• Ceramist
• /
• 제1권1호
• /
• pp.28-36
• /
• 1998

세라믹 분발의 분산안정성은 입자의 입경 및 형상, 배열형태, 그리고 분산기구에 따라 크게 달라진다. 대체로 입경이 콜로이드 범위내에 존재하면 일반적인 정전반발력이나 입체반발력에 의하여 분산이 가능하지만, 콜로이드 범위를 넘는 조대한 입경을 가지는 분말에서는 진정한 분산안정성을 얻는 것은 불가능하다. 비록 콜로이드 범위에 속히는 입경을 가지더라도 Hamaker 상수가 매우 높거나 기하이방성을 가진 입자가 우선배향성을 가지는 경우에도 마찬가지의 결과를 보여 준다. 진정한 의미의 분산안정성을 얻을 수 없는 경우 입자 간 포텐셜 에너지의 절대값이 최소가 되도록 함과 더불어 고분자 흡착층이나 전기이중층의 두께를 조정하여 입지간 평형거리를 조정하여 후속공정에서의 균일성을 유지하는 것이 기능하다. 이와 같은 제한응집은 진정한 의미의 분산안정성을 얻을 수 없는 분말을 구성분말로 하는 단미는 물론 복합재료에서도 활용이 가능하다. 나노 크기의 입경을 가지는 분말에서는 반데르발스 인력은 상대적으로 작지만, 정전반발력도 동시에 작아지기 때문에 에너지 장벽의 높이가 충분하지 않은 경향을 보인다. 따라서, 나노 분말의 분산안정성은 흡착층의 두께가 크지 않는 저분자량의 고분자를 흡착시켜 입체반발력을 부여하는 것이 바람직하다.

• Applied Chemistry for Engineering
• /
• 제24권6호
• /
• pp.656-662
• /
• 2013

The iron oxide ($Fe_3O_4$) particles in the coolant of the secondary system of a nuclear power plant reduce the heat transfer performance or induce corrosion on the surface of the heat transfer tube. To prevent these problems, we conducted a study to improve the dispersion stability of iron oxide using polymeric dispersant injection in simulated secondary system water. The three kinds of anionic polymers containing carboxyl groups were selected. The dispersion characteristics of the iron oxide particles with the polymeric dispersants were evaluated by performing a settling test and measuring the transmission, the zeta potential, and the hydrodynamic particle size of the colloid solutions. Polymeric dispersants had a significant impact on the iron oxide dispersion stability in an aqueous solution. While the dispersant injection tended to improve the dispersion stability, the dispersion stability of iron oxide did not increase linearly with an increase in the dispersant concentration. This non-linearity is due to the agglomerations between the iron oxide particles above a critical dispersant concentration. The effect of the dispersant on the dispersion stability improvement was significant when the dispersant concentration ratio (ppm, dispersant/magnetite) was in the range of 0.1 to 0.01. This suggests that the optimization of dispersant concentration is required to maximize the iron oxide removal effect with the dispersant injection considering the applied environments, the iron oxide concentration and the concentration ratio of dispersant to iron oxide.

• Journal of the Korean Ceramic Society
• /
• 제38권4호
• /
• pp.343-350
• /
• 2001

본 연구에서는 탄산화법으로 침강성 CaCO$_3$분말을 제조하고 제조된 CaCO$_3$현탁액의 분산안정성을 연구하였다. CaCO$_3$현탁액의 pH 변화와 고분자전해질 PMAA와 PAA의 첨가에 따른 입자크기, 유동학적 특성(점도), zeta potential 및 현탁액의 침강속도 등을 측정하였다. 탄산화법에 의해 약 0.1$\mu\textrm{m}$ 크기와 비표면적이 23.57$m^2$/g인 단분단 calcite형 CaCO$_3$분말을 제조하였다. pH가 11인 CaCO$_3$현탁액에 0.01 wt% PMAA가 첨가된 경우에 우수한 분산안정성을 나타내었는데 이는 CaCO$_3$입자표면에 PMAA의 흡착에 의한 electrosteric 안정화기구와 CaCO$_3$입자들 사이의 정전기적 반발력에 의한 것으로 판단된다. PMAA와 PAA 첨가량 변화에 따른 pH 6, 9, 11의 CaCO$_3$현탁액의 침전높이를 측정한 결과 PMAA와 PAA의 농도가 0.15 wt% 부근에서 분산안정성을 보였는데 이는 CaCO$_3$입자들 사이간의 분산제에 의한 뚜렷한 경계를 갖는 흡착층이 형성되었기 때문으로 생각되며 따라서 CaCO$_3$현탁액의 최적 분산안정성을 위해서는 적절한 pH 조절과 PMAA 및 PAA의 첨가가 필요함을 알 수 있다.

• Applied Chemistry for Engineering
• /
• 제8권2호
• /
• pp.252-261
• /
• 1997

The effect of solvent on the dispersion stability of $CaCO_3$ pigment in various solvents and resin solutions has been studied using Dynometer. Dispersion stability can be estimated in a relatively short time by means of Dynometer and the solubility parameter, ${\delta}$, of $CaCO_3$ determined from dispersion stability was 11.62(${\delta}_d=8.04$, ${\delta}_p=5.05$, ${\delta}_h=6.70$). The solvent showing weaker interaction with pigment increased the adsorption of resin on to the pigment, resulting in higher dispersion stability in resin solution. It was found that the rheological properties and dispersion stability of pigmented resin solution were depending strongly on the solvent added in small amount in the formulation.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 한국추진공학회 2009년도 춘계학술대회 논문집
• /
• pp.163-166
• /
• 2009

For the preparation of Aluminum-slurry fuel, the effects of process parameters on the aluminum dispersion stability in the liquid fuel have been investigated. The dispersion stability of aluminum-slurry fuels could be monitored by measurements through Turbiscan using the scattering of the Laser. Through the application of various additives, TPAB (Tetrapropyl ammonium bromide) showed more reasonable performance than others.

• Journal of Digital Contents Society
• /
• 제16권2호
• /
• pp.299-306
• /
• 2015

In this paper, we research to secure stability of data storing/searching on NoSQL implemented on Distributed File System. When implementing NoSQL on Distributed File System, we faced that random write on Distributed File System is almost impossible. To solve this problem, a concept of Intermediate-File was employed, and then it has been achieved that our system resist any failure circumstance. Additionally, since we discovered its performance cannot be as fast as general File System, by redefining the file block unit for our NoSQL system, we have prevented a slowdown in system performance. As a result, we are able to develop highly scalable NoSQL as Distributed File System, which fulfills basic conditions of transaction: Atomicity, Consistency, Isolation, and Performance.

• Applied Chemistry for Engineering
• /
• 제22권2호
• /
• pp.133-137
• /
• 2011

In this study, illite was size-reduced using a wet-ball-milling treatment to improve its dispersion. Changes in illite particle size, size distribution, and dispersion characteristics after varying the treatment period were investigated. And the dispersion and dispersion stability of illite solution after 2 h wet ball milling treatment with different pH conditions were also evaluated. The illite particle size significantly decreased as the treatment time increased and the size reduction effect of wet ball milling deteriorated above 2 h treatment time. In addition, illite particle size was more evenly distributed as the treatment time increased. X-ray diffraction (XRD) analysis showed that no crystal structural changes of illite were induced, but the characteristic peak of illite the weaker due to the size reduction and exfoliation, as the treatment time increased. Zeta potential analysis showed that the illite dispersion improved, as the treatment time increased. The illite wet-ball-mill treated at pH 2 had the lowest dispersion stability. Illite dispersion and dispersion stability increased as pH increased, due to the increase in surface ionization. Hence, the results showed that as the treatment time increased, the illite particle size decreased, and dispersion and dispersion stability improved due to the increase in surface energy and repulsion force between particles.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
• /
• pp.46-46
• /
• 2008

스텔스 기능을 가진 군사용 항공기는 레이다 망의 추적을 피하기 위해 일반 냉각수 대신에 절연유를 냉각매체로 사용한다. 그러나 절연유는 물에 비하여 열전달특성이 매우 낮기 때문에 항공기 전기전자 기기/부품 발열부를 효과적으로 냉각시키지 못하는 한계성을 가지고 있다. 따라서 본 연구에서는 나노유체(Nanofluid) 개념을 이용하여 절연유에 알루미나 및 질화알루미늄 나노분말을 미랑 분산시킨 나노절연유를 제조하고 이것의 열전달특성을 순수 절연유의 그것과 비교 평가함으로써, 냉각특성이 크게 개선된 새로운 냉매로서의 적용 가능성을 확인하고자 하였다. 다만 나노절연유를 제조함에 있어서 가장 큰 장애물은 오일에 대한 분산성 확보에 있기 때문에, 비드밀 및 초음파를 이용한 나노분말 응집체의 습식분산 및 분산제를 이용한 친유성 표면개질을 동시에 수행함으로써 장시간 안정된 분산성을 확보하도록 노력하였다. 나노유체의 열전도도 및 대류열전달계수는 비정상열선법을 이용하여 측정하였으며, 유체 속의 분말 분산 상태는 원심력을 이용한 분산안정성 평가장치 및 cryo FE-SEM을 이용하여 확인하였다. 또한 분말 형상이 대류열전달에 미치는 영향을 조사하기 위하여 알루미나 나노분말은 구상과 침상의 분말을 모두 사용하였고, 질화알루미늄 외에 다이아몬드 나노절연유도 함께 제조, 평가함으로써 냉각 및 절연특성, 그리고 물리화학적 안정성이 우수하고 실적용 가능성이 가장 높은 재료를 도출하고자 하였다.

• Applied Chemistry for Engineering
• /
• 제8권5호
• /
• pp.830-836
• /
• 1997

The surface modification of iron oxide particle produced from steel-pickled acid by sodium-contained materials was studied. The molar ratio of $SiO_2$ to $Na_2O$ of sodium silicate was 1, 2, 3.5, respectively. The dispersion stability of iron oxide suspension as functions of amount of silica and pH was evaluated by surface charge and sedimentation velocity of iron oxide particle. Then the amount of sodium silicate was determined to provide a dispersion stability of iron oxide particle above pH 7. Finally, the surface modification of iron oxide particle with sodium silicate as silica-contained materials was done by wet ball milling. In the results of study, the dispersion stability of silica modified iron oxide particle was largely depended on amount of silica and pH together. The untreated iron oxide was unstable at pH 8, i.e. isoelectric point, but, the surface modified iron oxide particle with 0.8wt% silica was stable above pH 5. The dispersion stability was enhanced with 0.2wt% of anionic polyelectrolyte.

• Journal of the Institute of Electronics Engineers of Korea SC
• /
• 제44권2호
• /
• pp.1-9
• /
• 2007

In this paper, new results for perturbation bounds for unified decentralized systems by a unified approach using $\delta$ (defined as a shift operator at unified approach) are presented. Robust stability analysis of unified decentralized system is investigated by new robust stability bound under system uncertainties. New unified stability bounds are developed based on the unified Lyapunov matrix equation. It is shown that the system maintains its stability when new unified bounds are applied. Numerical example is presented to illustrate the proposed analysis.