• Title/Summary/Keyword: 부피팽창계수

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Physical Properties of Permeable Concrete Using Slag as an Aggregate (슬래그 골재를 사용한 투수성 콘크리트의 물리적 성질)

  • 최재진;박원태
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.4 no.4
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    • pp.404-408
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    • 2003
  • This paper discusses the physical properties of permeable high quality concrete using blast furnace slag or steel slag as a part of aggregate. In the case of steel slag, aging treatment was adopted to prevent the volume expansion. With high range water reducing agent, the concrete using slag aggregate showed compressive strength up to 24MPa at the age of 28 days and the water permeability of the concrete was over the level of 0.1 m/s in this experiment. Also, there was no expansion problem in the concrete substituted with aged slag as a part of aggregate.

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Evaluation of Performance of Expansive Material for Restoration of Underground Cavity and Stress Release Zone (지하공동 및 이완영역 복구를 위한 팽창성 재료의 성능 평가)

  • Lee, Kicheol;Choi, Byeong-Hyun;Bak, Jongho;Kim, Dongwook
    • Journal of the Korean Geosynthetics Society
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    • v.17 no.4
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    • pp.141-155
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    • 2018
  • Recently, the number of ground subsidence resulting from underground cavity has been increased. Accordingly, the importance of restoration of stress release zone around the underground cavity has been emphasized. The stress release zone is composed of low density soils having extremely low stiffness and degree of compaction, which can lead to additional cavity expansion and collapse of overlying ground. Therefore, in this study, the suitability of restoration method of underground cavity using expansive material for reinforcement of stress release zone around the cavity is verified. The basic physical properties and expansion characteristics of the expansive material were examined. The experiment equipment capable simulating of stress release zone was developed and is used to investigate the effect of expanding material on stress release zone. The stress release zone was simulated using the spring in numerical analysis. The factors of the volume ratio of the underground cavity to the expansion material, the degree of stress relaxation, and the shape of the cavity were varied in numerical simulations, and the behavior of stress release zone was analyzed based on the numerical analysis results. Analysis variables are factors that affect each other. Also, filling of underground cavity and capacity of restoration of stress release zone were confirmed when the expansive material was inserted into underground cavity.

Cu-In 합금 콜로이드 전구체로부터 형성된 CuIn (Se,S)$_2$ 박막의 미세구조에 미치는 황화/셀렌화의 영향

  • Mun, Byeong-Min;Go, Min-Jae;Lee, Do-Gwon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.428-428
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    • 2012
  • CIGS 또는 CIS 태양전지는 높은 흡광계수와 조절가능한 밴드갭 특성으로 인해 높은 광전변환효율을 나타내므로 실리콘 태양전지를 대체할 차세대 태양전지로 주목받고 있다. 그러나 태양전지의 저가화를 위해서는 기존의 동시증발법 또는 스퍼터링을 대신할 수 있는 비진공 방식의 박막제조방법이 요구된다. 다양한 비진공 코팅방법 중에서 용액 또는 콜로이드 전구체를 프린팅하는 방법은 batch 조성이 박막의 조성으로 전사되므로, 전착법에 비해 조성 조절이 용이하다는 장점이 있다. 한편, 콜로이드 공정에 속하는 Cu-In 합금 나노 분말법은 셀렌화 또는 황화 과정 중에 부피가 팽창하는 장점을 활용 가능한 반면, 전구체 박막의 충진밀도가 낮을 경우 열처리를 통한 치밀화에 한계가 생길 수 있는 단점이 있다. 본 연구에서는 합성한 Cu-In합금 분말을 이용하여 전구체 박막을 형성한 후 반응기구가 다른 황 및 셀레늄 분위기에서의 열처리를 통해 소결된 박막의 결정상, 미세구조 및 표면 형상의 차이를 비교하였다.

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Characteristics of $\textrm{Al}_2\textrm{O}_3$-CaO Refractory Prepared from Oyster Shells (굴패각으로부터 제조된 $\textrm{Al}_2\textrm{O}_3$-CaO내화물의 특성)

  • Ryu, Su-Chak;Park, Hong-Chae
    • Korean Journal of Materials Research
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    • v.8 no.1
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    • pp.23-26
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    • 1998
  • 알루미나와 하소된 귤껍질의 소결반응에 의해 A $I_{2}$ $O_{3}$-CaO내화물이 제조되었다. 치밀화과정에서의 CaO의 영향과 A $I_{2}$ $O_{3}$-CaO 소결체의 특성을 고찰하였다. 소결체의 미세구조와 EDS 결과로 A $I_{2}$ $O_{3}$-CaO화합물을 확인하였다. 145$0^{\circ}C$에서 열처리한 소결체는 2.87/㎤의 부피비중과 12.03%의 겉보기 기공율을 가지며 압축강도는 312kg/$\textrm{cm}^2$이였다. 140$0^{\circ}C$에서 서결체의 열팽창 계수는 6.55Kx10$_{-6}$ $K_{-1}$이였다.

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Analysis of Stresses Along the Underfill/chip Interface (언더필/칩 계면의 응력 해석)

  • Park, Ji-Eun;Iwona Jasiuk;Lee, Ho-Young
    • Journal of the Microelectronics and Packaging Society
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    • v.9 no.4
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    • pp.35-45
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    • 2002
  • The stresses of the underfill/chip interface due to thermal loading was studied using the finite element method. At first, the effective properties of underfill for several volume fractions of silica particles were calculated by Mori-Tanaka method for three different material sets, and the parameters of singularity for the bimaterial edge and the bimaterial wedge were calculated. Consequently, the stresses at the underfill/chip interface with volume fraction of silica particles were investigated. Five different geometric models of flip-chip assembly involving two kinds of bimaterial strips and three kinds of three-layer models were considered under the assumption that the underfill is homogeneous. It was assumed that all components of the flip-chip assembly were linear elastic and isotropic, and their properties were temperature independent. The analysis was conducted in the context of the uncoupled plane thermo-elasticity under a plane strain assumption.

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Variation of the Physical-microstructural Properties of Sandstone and Shale Caused by CO2 Reaction in High Pressure Condition (고압 이산화탄소 반응에 의한 사암과 셰일의 물리적-미세구조적 변화)

  • Park, Jihwan;Son, Jin;Park, Hyeong-Dong
    • Tunnel and Underground Space
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    • v.26 no.4
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    • pp.293-303
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    • 2016
  • Underground $CO_2$ storage technology is one of the most effective methods to reduce atmospheric $CO_2$. In this study, $CO_2$ storage condition was simulated in the laboratory. Sandstone and shale specimens were saturated in 1M NaCl and were reacted at $45^{\circ}C$, 10 atm for 4 weeks. The physical and microstructural properties of rock specimens were measured. Variations on physical properties of shale specimens were bigger than those of sandstone specimens, such as volume, density, elastic wave velocity, Poisson's ratio and Young's modulus. Microstructure were analyzed using X-ray computed tomography. Total number of pores were decreased, and average volume, average area and average equivalent diameter of each pore were changed after $CO_2$ reaction. Swelling and leakage of clay mineral caused by $CO_2$-mineral reaction were the reason of changes. The results of this study can be applied to predict the physical and microstructural changes in underground $CO_2$ storage condition.

Study on Deformation of Miniature Metal Bellows in Cryocooler Following Temperature Change of Internal Gas (내부 기체의 온도 변화에 따른 극저온 냉각기용 소형 금속 벨로우즈의 변형에 관한 연구)

  • Lee, Seung Ha;Lee, Tae Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.4
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    • pp.429-435
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    • 2015
  • A bellows is an important temperature control component in a Joule-Thomson micro-cryocooler. It is designed using a very thin shell, and the inside of the bellows is filled with nitrogen gas. The bellows is made of a nickel-cobalt alloy that maintains its strength and elastic properties in a wide range of temperatures from cryogenic to $300^{\circ}C$. The pressure of the gas and the volume within the bellows vary according to the temperature of the gas. As a result, the bellows contracts or expands in the axial direction like a spring. To explore this phenomenon, the deformation of the bellows and its internal volume must be calculated iteratively under a modified pressure until the state equation of the gas is satisfied at a given temperature. In this paper, the modified Benedict-Webb-Rubin state equation is adopted to describe the temperature-volume-pressure relations of the gas. Experiments were performed to validate the proposed method. The results of a numerical analysis and the experiments showed good agreement.

Determination of Shear Strength Modification Factors in Drilled Shaft (현장타설말뚝의 전단강도 조정계수 결정법)

  • Kim, Myung-Hak;Michael W. O'Neill
    • Proceedings of the Korean Geotechical Society Conference
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    • 1999.03a
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    • pp.193-200
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    • 1999
  • An experimental study is described in which a 305-mm-diameter instrumented drilled shaft was installed in a moderately expansive clay soil during the dry season and monitored over a period of about 18 months. The purpose of the study was In investigate the effects of seasonal moisture changes in the soil on the shear stresses imposed on the sides of the drilled shaft and movements of the shaft head. The soil in the vicinity of the test shaft was instrumented to measure suction and ground surface movement and the relation between suction, total stress and shear strength of the soil at the test site was determined through laboratory triaxial compression testing. Daily rainfall and temperatures were also monitored at the test site, the National Geotechnical Experimentation Site at the University of Houston, where control on surface grading and vegetation existed. Over the course of the study induced unit side shear values of up to 54 kPa were measured in the test shaft. A simple computational model was developed that related observed suction changes to unit side shear induced by the expansion of the soil through the use of the laboratory suction-total stress-shear strength relation.

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$La_{0.7}Ca_{0.3}Cr_{0.9}Co_{0.1}O_3$에 소결 조제 첨가에 따른 물리적 특성 변화

  • Seol, Gwang-Hui;Choe, Byeong-Hyeon;Ji, Mi-Jeong;Gwon, Yong-Jin;Lee, Seo-Hwan;Nam, San
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.96.1-96.1
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    • 2012
  • SOFC는 다른 연료전지보다 상대적으로 높은 구동 온도를 가지며 그로인해 높은 에너지 효율을 가진다. 먼저 금속연결제의 경우 높은 고온에서 산화 반응이 쉽게 일어나기 때문에 이로 인하여 연결재의 주요 특성인 전기전도도의 감소와 부피변화로 인한 크랙등이 유발되어 연결재의 주요 기능인 전기적인 연결 뿐만 아니라, 물리적으로 양극과 음극의 차폐 또한 어려워져 장기 구동에 있어서 주요 결함의 원인이되고 있다. 이로 인하여 많은 세라믹 연결재의 개발이 진행되어왔고, 이중에서 perovskite-structure를 가지는 LCO계의 연결재에 대한 연구가 활발히 진행되고 있다. $LaCrO_3$는 열팽창 계수가 주요 구성소재들과 유사하다는 장점과 도핑과 친환으로 인하여 특성제어가 용이하다는 이유 때문에 주로 사용되고 있다. 그러나 $LaCrO_3$는 낮은 전기전도도와 높은 소결온도에서 Cr휘발되는 단점이 있다. 이를 해결하기 위해서 A에 희토류와 B-site에 전위금속을 치환하여 소결 온도를 낮춘 연구들이 진행 되었다. 본 연구에서는 이런 결과 중 $La_{0.7}Ca_{0.3}Cr_{0.9}Co_{0.1}O_3$조성에 소결조제를 첨가하여 그에 따른 특성변화를 관찰하였다.

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The Enhanced Electrochemical Performance of Lithium Metal Batteries through the Piezoelectric Protective Layer (압전 특성의 보호층을 통한 리튬 금속 전지의 전기화학적 특성 개선)

  • Dae Ung Park;Weon Ho Shin;Hiesang Sohn
    • Membrane Journal
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    • v.33 no.1
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    • pp.13-22
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    • 2023
  • Despite high capacity of lithium metal anode, its uncontrollable dendrite growth results in the poor electrochemical (EC) performance (low Coulomb efficiency and limited cycle stability) and unsafe operation. In this study, we demonstrated a lithium metal anode protected with BaTiO3/PVDF based piezoelectric layer to enhance its EC performance by utilizing the locally polarized lithium metal after volume expansions. As-formed lithium metal electrode deposited with BTO@PVDF layer exhibited an enhanced Coulombic efficiency (> 98% for 100 cycles) and facilitated lithium ion diffusions (lithium diffusion coefficient: DLi+), revealing the effectiveness of piezoelectric layer deposited lithium metal electrode approach.