• Clean Technology
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• v.11 no.3
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• pp.141-146
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• 2005

The composite membranes were made by grafting using supercritical carbon dioxide (scCO2) impregnation and polymerization procedures. The membranes were synthesized by changing amount of monomer. The polypropylene grafted polystyrene sulfonic acid (PP-g-pssa) membranes were characterized with various methods. The morphology and structure of PP-g-pssa membranes were analyzed with scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS). As amount of monomer was increased, ion conductivity, cell performance was increased and methanol permeability was decreased. However PP-g-pssa membranes with 1.5g monomer and over had similar values of methanol permeability, ion conductivity and cell performance.

• Journal of the Korean Society for Precision Engineering
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• v.13 no.8
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• pp.88-95
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• 1996

유리섬유가 강화된 열가소성 복합재료 판재의 성형성에 대한 이해를 돕기 위해 이론적 고찰과 실험적 고찰이 행해졌다. 성형시험에서 사용된 형상은 임의의 방향으로 위치한 유리섬유를 중량비로 30% 함유한 폴리프로필렌 재료가 사용되었고, 시험된 형상은 판재의 굽힘성이나 인장성을 측정하는데 널리 사용되는 스위프트컵(Swift flat-bottomed cup)모양이다. 성형시험과 재료시험은 플리프로필렌 Matrix의 유리성 천이온도(Glass transition temperature)와 용융온도 사이에서 행해졌다. 본 연구의 이론과 고찰을 위해서 재료의 평면 방향으로는 동질성을 그리고 그 직각 방향으로는 이질성을 가진 연속체 물질로 가정하여 유도하였다. 이러한 이론적 결과는 실험 결과와 비교되어졌고,이를 통해 시험된 재료의 최적의 성형조건을 제시하였다.

• Polymer(Korea)
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• v.30 no.4
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• pp.318-325
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• 2006

Polypropylene-clay nanocomposites were studied by the modification of clay with amino silanes to introduce covalent bonds in nanocomposites, and prepared by melt-compounding with polypropylene, clay modified with amino silanes and maleic anhydride grafted polypropylene. The . .structure and surface properties of modified clay were determined by x-ray diffraction, infrared spectrum, and solid-state $^{29}Si$ nuclear magnetic resonance spectrum. The modification of clay with aminosilanes led to the increase of the silicate interlayers to about $19.8{\AA}$, the weakening effects of hydroxy group at $3650cm^{-1}$ and the signal of amine groups at -69 ppm proved that the modification had taken place.

• Composites Research
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• v.33 no.6
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• pp.346-352
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• 2020

In mobility industries, the use of thermoplastic composites increased dynamically. In this study, the mechanical and impregnation properties of continuous glass fiber (GF)/polypropylene (PP) composite were evaluated with different GF contents. The GF/PP commingled fiber was manufactured with different GF contents and continuous GF/PP composite was manufactured using continuous compression molding process. Tensile, flexural, and impact test of specimens were evaluated with different GF contents. The fracture behavior of specimens was proved using field emission-scanning electron microscope images of fracture area and impregnation property was evaluated using dynamic mechanical analyzer and interlaminar shear strength. Finally, the GF/PP composite was the optimized mechanical and impregnation properties using 50 wt.% GF/PP commingled fiber.

• Resources Recycling
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• v.22 no.2
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• pp.18-21
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• 2013

In this study, surface modification of wood powder by atmospheric pressure plasma treatment was investigated. The composites were manufactured using wood powder and polypropylene(wood powder : PP = 55 wt% : 45 wt%). Atmospheric pressure plasma was treated as condition of 3KV, $17{\pm}1$KHz, 2 g/min. Helium was used as carrier gas and monomer such as hexamethyl-disiloxane(HMDSO) was used to modify surface property by plasma polymerization. The tensile strength of untreated waste wood powder(W3) and homogeneous wood powder(H3) were about 18.5 MPa, 21.5 MPa while the tensile strength of plasma treated waste wood powder(PW3) and homogeneous wood powder(PH3) were about 21.2 MPa, 23.4 MPa, respectively. And tensile strength of W3 and H3 were improved by 14.6% and 8.8%, respectively. From the results for mechanical property, morphological analysis, we obtained improved interfacial bonding of polypropylene and wood powder modified by plasma treatment.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2011.06a
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• pp.1013-1014
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• 2011

• Journal of the Korean Geosynthetics Society
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• v.2 no.3
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• pp.25-38
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• 2003

Geotextile composites to improve the resistance to the application environment were manufactured of recycled polyester geotextile with carbon black as ultraviolet stabilizer and polypropylene geotextile by needle-punching method. Mechanical properties, ultraviolet resistance and chemical stability were evaluated. Retention ratio of tensile properties of polypropylene geotextiles were decreased about 50% with the exposed condition by ultraviolet but those of geotextile composites showed the slightly decrease. Geotextile composites which have larger weights of recycled polyester geotextile were more stable against ultraviolet. For chemical stability, the changes of tensile strength values of geotextile composites were in the range of -20~+10% at the various chemical conditions.

• Composites Research
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• v.27 no.4
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• pp.130-134
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• 2014

The purpose of this paper is to build DB in order to Propose new constitutive equations by redefining constitutive equations for Polyurethane presented by Jeong et al. [12] based on Quasi-static test and Impact test DB of Expanded polypropylene using cylindrical specimens with 4 different densities presentsd by Kim et al. [7] for EPP foam and combining the impulse-momentum theory.

• Composites Research
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• v.18 no.1
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• pp.23-29
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• 2005

In this work, the effect of ozone treatment of montmorillonite (MMT) on the surface characteristics of montmorillonite and the thermal stability of MMT/polypropylene (PP) nanocomposites was investigated. The surface properties of MMT were determined by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), and X-ray photoelectron spectroscopy (XPS). Also, the thermal stability of nanocomposites was investigated in thermogravimetric analysis (TGA). As a result, it was found that the silicate interlayers of the organically modified MMT (D-MMT) were increased by about 11${\AA}$, as compared with the MMT. Also, FT-IR showed that a new peaks at $2800\~2900\;cm^{-1}$ appeared due to the $CH_2$ mode in the D-MMT The ozone treatment of the MMT led to an increase of SiO or $SiO_2$ groups on MMT surfaces, resulting in increasing the oxygen-containing functional groups on MMT. The ozonized MMT had higher thermal stability than that of untreated nanocomposites. This was due to the improvement of interfacial bonding strengths, resulting from the acid-base interfacial interactions between PP and MMT.

• Composites Research
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• v.26 no.1
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• pp.1-6
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• 2013

CNT-polypropylene (PP) composites were compounded by solvent dispersion method with uniform dispersion by using twin screw extruder. Damage sensing effects based on conductive carbon nanotubes (CNT) were evaluated to monitor the internal damage of CNT-PP composites using electrical resistance measurement. Mechanical and interfacial properties of CNT-PP composites were investigated and compared with neat PP. The mechanical properties of PP matrix were improved after adding CNT, because of the reinforcing effect of CNT fillers. In order to monitor the internal damage of CNT-PP composite, the change in electrical resistance of the composites was measured under fatigue loading and bending tests. CNT fillers exhibited good sensing under electrical resistance measurements. It is shown that CNT-PP composites with low CNT contents allow identifying critical cyclic loading, which are found to be accompanied with the internal failure.