• Title/Summary/Keyword: 복합 폴리프로필렌

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Half-dome Thermo-forming Tests of Thermoplastic Glass Fiber/PP Composites and FEM Simulations Based on Non-orthogonal Constitutive Models (열가소성 유리섬유/PP 복합재의 반구돔 열성형 평가 및 비직교 구성방정식을 이용한 FEM 수치해석)

  • Lee, Wonoh
    • Composites Research
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    • v.29 no.5
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    • pp.236-242
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    • 2016
  • In this work, tensile and in-plane shear tests for thermoplastic glass fiber/polypropylene composites were performed at a thermo-forming temperature and their properties were characterized and mathematically expressed by using the non-orthogonal constitutive model. As for the thermo-forming test, half-dome experiments were carried out by varying the usage of a releasing agent and the weight of holders. As results, the optimum final shape having well-aligned symmetry and no wrinkle formation was obtained when the releasing agent was used, and it was found that the careful control of a holding force is crucial to manufacture the healthy product. Furthermore, FEM simulations based on the non-orthogonal model showed similar final shapes and tendency of wrinkle formation with experimental results, and confirmed that wrinkles increase with less holding force and higher punch force is required under high frictional condition.

Mechanical Properties of Wood-Fiber Thermoplastic Composites (목섬유(木纖維)와 열가소성(熱可塑性) 플라스틱 복합재료(複合材料)의 기계적(機械的) 성질(性質))

  • Park, Byung-Dae;Lim, Kie-Pyo;Kim, Yoon-Soo
    • Journal of the Korean Wood Science and Technology
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    • v.22 no.2
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    • pp.46-53
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    • 1994
  • This study was conducted to investigate a feasibility of manufacturing wood fiber thermoplastic composites and to evaluate their mechanical properties. Wood fiber as a potential reinforcing filler was compounded with two thermoplastics (polypropylene and high density polyethylene) in high intensity thermokinetic plastic mixer aided with a wetting agent. It was found that wood fiber thermoplastic composites could be manufactured by injection molding process. The tensile and flexural strength of injection molded specimens were improved greatly with increasing wood fiber concentration. Tensile and flexural modulus increased proportionately with wood fiber concentration. Wood fiber provided reinforcement with thermoplastics in terms of strength and modulus. However, the percent elongation at break and energy to break were reduced with increasing wood fiber loadings. Impact strength also showed similar trend.

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Preparation of Alumina Sol Coated BOPP Composites and Their Gas Permeation Characteristics (Alumina Sol을 코팅한 BOPP 복합체의 제조 및 기체 투과 특성)

  • Hong, Seong-Uk;Oh, Jae-Won;Ko, Young-Deok;Song, Ki-Chang
    • Membrane Journal
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    • v.19 no.1
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    • pp.19-24
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    • 2009
  • Sol-gel process is relatively simple, easy to use, cheap to install, and results in thin coating layers with superior physical and gas barrier properties. Films coated by the sol-gel process can be used as insulating films or packaging films for foods, chemicals, drugs, and beverages, etc. In this study, alumina sol was synthesized from aluminum isopropoxide and silane coupling agent was added to make coating solutions. In addition, biaxially oriented polypropylene (BOPP) was coated using several alumina sol solutions and their oxygen permeabilities were measured. The experimental results indicate that in the best case, the oxygen permeability of coated film was reduced by 85% compared to that of pure BOPP.

Formability for AA5182 sheet and AA5182/PP/AA5182 sandwich sheet (AA5182판재와 AA5182/PP/AA5182 샌드위치 판재의 성형성 평가)

  • 김대용;김기주;정관수;신광선;유동진
    • Composites Research
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    • v.13 no.2
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    • pp.81-90
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    • 2000
  • For automotive applications, a sandwich sheet which was made of a 5182 aluminum alloy (AA5182) sheet and a polypropylene (PP) sheet, AA5182/PP/AA5182, has been developed. In order to evaluate its formability, the forming limit diagrams (FLD) of the 5182 aluminum alloy sheet with 0.2mm thickness and the sandwich sheet with 1.2mm thickness have been obtained based on the modified Marciniak-Kuczynski (M-K) theory. To account for the anisotropy of the sheet, Hill's 1948 yield function has been applied. The FLD of the sandwich sheet was predicted to be better than that of the AA5182 sheet, which was well confirmed by experiments.

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방출조절용 항균성 포장재의 개발 및 미생물 생육억제와 물질전달 모델링

  • Han, Jeong-Hun
    • Bulletin of Food Technology
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    • v.9 no.2
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    • pp.111-127
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    • 1996
  • Potassium Sorbate의 향균능력측정결과 효모(Saccharomyces cerevisiae)의 성장에 대하여 uncompetitive 기작으로 작용하였다. 열처리 실험의 결과 Potassium Sorbate는 가열온도에 대하여 Arrhenius, 또한 가열시간에 대하여 1차반응식관계로 향균능력을 잃었으며 따라서 보존제로 Potassium Sorbate를 식품에 첨가후 포장, 가열살균하는 일반 식품가공공정상에서 가열살균공정이 첨가 보존제의 잔류향균능력을 잃게 하는 것으로 나타났다. 플라스틱 film과 치즈안에서 Potassium Sorbate의 확산계수 및 확산에 의한 물질전달 현상을 수학적모델과 컴퓨터 simulation 그리고 실험에 의해 구하였다. 저밀도폴리에틸렌(LDPE)이 범용플라스틱중에서 가장 작은 확산계수를 가져 빠른 물질전달이 요구되는 film층 또는 약물저장층으로 적합한것으로 나타났다. 그외 고밀도 폴리에틸렌(HDPE)과 폴리프로필렌(PP), 폴리에스터(PET)는 느린 물질전달이 요구되는층 또는 복합다층 film에서 물질전달에 단방향성을 주는 고차단층으로 적합한것으로 나타났다. Potassium Sorbate분말과 LDPE resin분말을 섞은후 단일스크루 익스트루더로 항균성 포장 film을 제조한 결과 LDPE film의 tensile strength과 elongation, elastic modulus는 Potassium Sorbate를 3% 이상 포함할때까지 변화하지 않았다. 그러나 film의 투명도는 급격히 낮아졌다. 향균성LDPE film은 효모가 접종된 한천배지상에서 항균물질인 Potassium Sorbate를 배지위로 서서히 방출시켜 효모의 성장속도(growth rate)를 저하시키고 초기성장지체기(lag period)를 연장시킨다. 따라서 식품포장재로 적용시에 미생물의 오염을 막고 식품저장기간을 연장할것이라 여겨진다.

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Basic Characteristics of High Performance Concrete Mixing Organic Fiber (유기섬유 복합 혼입 고성능 콘크리트의 기초적 특성)

  • Park, Byung-Kwan;You, Ji-Young;Lee, Joung-Ah;Jin, Cheng-Ri;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.05a
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    • pp.87-91
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    • 2008
  • The study examined fire resistance of concrete followed by change of mixed rate in PP and NY composite fiber and the results were as follows. In the event of fluidity in concrete not set, plane satisfied 600±100, its target slump flow, and fluidity was reduced as organic fiber's mixed rate was increased. Air amount satisfied 3.0±1.0, its target air amount, and didn't have distinct differences in reduction and increase according to organic fiber's kind and change of its mixed rate. However, it had a tendency that fluidity was reduced as the mixed rate was increased. In characteristics of hardening concrete, the 28th day compressive strength followed by organic fiber's kind and change of its mixed rate didn't have a lot of differences and satisfied high strength scope as about 70MPa. In spalling characteristics after fire resistance test, spalling was happened in non-mixture, plane combination, and P1N0. In other combinations, spalling resistance was happened. The relic compressive strength rate was 56%, the best condition, in P3N1(PP0.03%, NY0.01% compositeness) mixing PP fiber with NY fiber at once.

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Spalling Properties of 80MPa High Strength Concrete with Fiber (복합섬유(PP,NY)를 혼입한 설계강도 80MPa 3성분계 고강도콘크리트의 폭렬특성)

  • Kim, Seong-Deok;Lee, Bum-Sik;Bae, kee-Sun;Kim, Sang-yun;Park, Su-Hee
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.11a
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    • pp.51-54
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    • 2009
  • In this study, the fire resistance test was carried out with a parameter such as fiber(PP+NY) mixed ratio on high strength concrete with 80MPa, and the spalling resistance property was evaluated. Concrete material test was carried out with a parameter such as fiber(PP+NY) mixed ratio(0%, 0.05%, 0.1%, 0.2%) of high strength concrete with 80MPa. Although the flowability and the strength capacity were delicately decreased with a increase of fiber mixed ratio, they satisfied the target limits. As the spalling resistance property after the fire resistance test of 3 hours, the spalling was partly shown on the high strength concrete with fiber(PP+NY) mixed ratio of 0% but, wasn't shown on the high strength concrete with fiber(PP+NY) mixed ratio of 0.05% ~ 0.2%.

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Manufacturing and Characterization of Red algae fiber/Polypropylene Biocomposites (홍조류섬유보강 폴리프로필렌 바이오복합재료의 제조 및 특성 분석)

  • Lee, Min-Woo;Seo, Yung-Bum;Han, Seong-Ok
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2008.04a
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    • pp.178-182
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    • 2008
  • The bleached red algae fiber(BRAF) showed very similar crystallinity to the cellulose, furthermore, it has higher thermal decomposition temperature than that of the microcrystalline cellulose(MCC). Polypropylene biocomposites reinforced with BRAF have been fabricated with various BRAF contents by compression molding method and their mechanical and thermomechanical properties have been studied. The mechanical strength as tensile, impact and flexural modulus of BRAF/PP biocomposites were gradually improved with increasing the BRAF content, and thermal property which against the thermal expansion was markdly improved, especially. These results are compared with chopped non-woody fibers as Henequen or Kenaf, BRAF was more effective for fabrication of biocomposites reinforced small-sized fibers. The red algae fiber reinforced biocomposites has the applicability such as electronics, biodegradable products and small-structure composites.

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A Study on the Prediction of Warpage During the Compression Molding of Glass Fiber-polypropylene Composites (유리섬유-폴리프로필렌 복합재료의 압축 공정 중 뒤틀림 예측에 관한 연구)

  • Gyuhyeong Kim;Donghyuk Cho;Juwon Lee;Sangdeok Kim;Cheolmin Shin;Jeong Whan Yoon
    • Transactions of Materials Processing
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    • v.32 no.6
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    • pp.367-375
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    • 2023
  • Composite materials, known for their excellent mechanical properties and lightweight characteristics, are applied in various engineering fields. Recently, efforts have been made to develop an automotive battery protection panel using a plain-woven composite composed of glass fiber and polypropylene to reduce the weight of automobiles. However, excessive warpage occurs during the GF/PP compression molding process, which makes car assembly challenging. This study aims to develop a model that predicts the warpage during the compression molding process. Obtaining out-of-plane properties such as elastic or shear modulus, essential for predicting warpages, is tricky. Existing mechanical methods also have limitations in calculating these properties for woven composite materials. To address this issue, finite element analysis is conducted using representative volume elements (RVE) for woven composite materials. A warpage prediction model is developed based on the estimated physical properties of GF/PP composite materials obtained through representative volume elements. This model is expected to be used for reducing warpages in the compression molding process.

Rheological Properties and Foaming Behaviors of Modified PP/Nano-filler Composites (개질 폴리프로필렌/나노필러 복합체의 유변학적 특성 및 발포거동)

  • Yoon, Kyung Hwa;Lee, Jong Won;Kim, Youn Cheol
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.494-499
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    • 2013
  • Modified polypropylene (m-PP) was fabricated by furfuryl sulphide (FS) as branching agent and m-PP/nano-filler composites were prepared with silicate and multi-walled carbon nanotube (MWCNT), using a twin screw extruder. The chemical structures and thermal properties of the m-PP were investigated by FTIR and DSC. The chemical structure of the m-PP was confirmed by the existence of =C-H stretching peak of the branching agent at 3100 $cm^{-1}$. There was no district change in melting temperature in case of m-PP, but a certain increase in crystallization temperature was notified and the increase was in the range of $10-20^{\circ}C$. The rheological properties, filler dispersion and foaming behaviors of the m-PP/nano-filler composites were investigated by dynamic rheometer, X-ray diffractometer (XRD) and scanning/transmission electron microscope (SEM/TEM). m-PP/nano-filler composites showed a high complex viscosity at a low frequency, an increase in melt elasticity, and a high shear thinning effect. Compared to pure PP, m-PP and m-PP/nano-filler composites were sufficient to enhance the foaming behavior.