• Title/Summary/Keyword: 복합 폴리프로필렌

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Preparation of Polypropylene Grafted Polystyrene Sulfonic Acid Membranes for DMFCs in Supercritical CO2 (초임계 이산화탄소 함침을 이용한 연료전지용 폴리스타이렌/폴리프로필렌 복합막의 제조)

  • Byun, Jungyeon;Sauk, Junho;Synn, Wookyun;Kim, Hwayong
    • Clean Technology
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    • v.11 no.3
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    • pp.141-146
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    • 2005
  • The composite membranes were made by grafting using supercritical carbon dioxide (scCO2) impregnation and polymerization procedures. The membranes were synthesized by changing amount of monomer. The polypropylene grafted polystyrene sulfonic acid (PP-g-pssa) membranes were characterized with various methods. The morphology and structure of PP-g-pssa membranes were analyzed with scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS). As amount of monomer was increased, ion conductivity, cell performance was increased and methanol permeability was decreased. However PP-g-pssa membranes with 1.5g monomer and over had similar values of methanol permeability, ion conductivity and cell performance.

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Deep Drawing of Glass Fiber Reinforced Thermoplastic Composite (유리섬유 강화 열가소성 복합재료 판재의 소성가공)

  • 이중희
    • Journal of the Korean Society for Precision Engineering
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    • v.13 no.8
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    • pp.88-95
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    • 1996
  • 유리섬유가 강화된 열가소성 복합재료 판재의 성형성에 대한 이해를 돕기 위해 이론적 고찰과 실험적 고찰이 행해졌다. 성형시험에서 사용된 형상은 임의의 방향으로 위치한 유리섬유를 중량비로 30% 함유한 폴리프로필렌 재료가 사용되었고, 시험된 형상은 판재의 굽힘성이나 인장성을 측정하는데 널리 사용되는 스위프트컵(Swift flat-bottomed cup)모양이다. 성형시험과 재료시험은 플리프로필렌 Matrix의 유리성 천이온도(Glass transition temperature)와 용융온도 사이에서 행해졌다. 본 연구의 이론과 고찰을 위해서 재료의 평면 방향으로는 동질성을 그리고 그 직각 방향으로는 이질성을 가진 연속체 물질로 가정하여 유도하였다. 이러한 이론적 결과는 실험 결과와 비교되어졌고,이를 통해 시험된 재료의 최적의 성형조건을 제시하였다.

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Preparation of Polypropylene/Clay Nanocomposites Using Aminosilane Treated Clay (아미노실란 개질 클레이를 사용한 폴리프로필렌 클레이 나노복합재료)

  • Hong Chae-Hwan;Bae Jin-Woo;Lee Yong-Bum;Lee Choon-Soo;Jho Jae-Young;Nam Byeong-Uk
    • Polymer(Korea)
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    • v.30 no.4
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    • pp.318-325
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    • 2006
  • Polypropylene-clay nanocomposites were studied by the modification of clay with amino silanes to introduce covalent bonds in nanocomposites, and prepared by melt-compounding with polypropylene, clay modified with amino silanes and maleic anhydride grafted polypropylene. The . .structure and surface properties of modified clay were determined by x-ray diffraction, infrared spectrum, and solid-state $^{29}Si$ nuclear magnetic resonance spectrum. The modification of clay with aminosilanes led to the increase of the silicate interlayers to about $19.8{\AA}$, the weakening effects of hydroxy group at $3650cm^{-1}$ and the signal of amine groups at -69 ppm proved that the modification had taken place.

Evaluation of Impregnation and Mechanical Properties of Thermoplastic Composites with Different GF Content of GF/PP Commingled Fiber (유리섬유/폴리프로필렌 복합원사의 유리섬유 함량 변화에 따른 열가소성 복합재료의 함침 및 기계적 특성 평가)

  • Jang, Yeong-Jin;Kim, Neul-Sae-Rom;Kwon, Dong-Jun;Yang, Seong Baek;Yeum, Jeong Hyun
    • Composites Research
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    • v.33 no.6
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    • pp.346-352
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    • 2020
  • In mobility industries, the use of thermoplastic composites increased dynamically. In this study, the mechanical and impregnation properties of continuous glass fiber (GF)/polypropylene (PP) composite were evaluated with different GF contents. The GF/PP commingled fiber was manufactured with different GF contents and continuous GF/PP composite was manufactured using continuous compression molding process. Tensile, flexural, and impact test of specimens were evaluated with different GF contents. The fracture behavior of specimens was proved using field emission-scanning electron microscope images of fracture area and impregnation property was evaluated using dynamic mechanical analyzer and interlaminar shear strength. Finally, the GF/PP composite was the optimized mechanical and impregnation properties using 50 wt.% GF/PP commingled fiber.

A Study on Effect of Plasma Treatment for Waste Wood Application (폐목재(廢木材) 활용(活用)을 위한 플라즈마 처리(處理) 효과(效果)에 대한 연구(硏究))

  • Kim, MiMi;Lim, Joong Yeon
    • Resources Recycling
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    • v.22 no.2
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    • pp.18-21
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    • 2013
  • In this study, surface modification of wood powder by atmospheric pressure plasma treatment was investigated. The composites were manufactured using wood powder and polypropylene(wood powder : PP = 55 wt% : 45 wt%). Atmospheric pressure plasma was treated as condition of 3KV, $17{\pm}1$KHz, 2 g/min. Helium was used as carrier gas and monomer such as hexamethyl-disiloxane(HMDSO) was used to modify surface property by plasma polymerization. The tensile strength of untreated waste wood powder(W3) and homogeneous wood powder(H3) were about 18.5 MPa, 21.5 MPa while the tensile strength of plasma treated waste wood powder(PW3) and homogeneous wood powder(PH3) were about 21.2 MPa, 23.4 MPa, respectively. And tensile strength of W3 and H3 were improved by 14.6% and 8.8%, respectively. From the results for mechanical property, morphological analysis, we obtained improved interfacial bonding of polypropylene and wood powder modified by plasma treatment.

Strain Rate and Temperature Effects on TPO and PP for Enhanced Airbag Deployment Simulation (열가소성 올레핀과 폴리프로필렌 소재의 변형률 속도와 온도에 따른 기계적 특성을 고려한 에어백 전개 시뮬레이션의 정확도 향상)

  • Se-Min Lee;Gyu-Won Kim;Jae-Hyun Ahn;In-Soo Han;Hak-Sung Kim
    • Composites Research
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    • v.37 no.4
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    • pp.325-329
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    • 2024
  • To accurately predict airbag deployment during a collision, the mechanical properties of polymer materials at high strain rates according to temperature should be considered. In this study, the mechanical properties of TPO and polypropylene were measured at high strain rates via split-Hopkinson pressure bar tests under various environmental temperatures ranging from -35 to 85℃. Through this, tensile strength and failure strain were derived for each strain rate. As the polymer phase moves toward the high strain rate region, the β-transition becomes dominant, resulting in a non-linear increase in tensile strength in the Eyring plot. Additionally, an airbag module impact simulation was conducted to verify the effects of strain rate on airbag deployment using the LS-DYNA software. It was found that the TPO and polypropylene airbag deployment could be accurately predicted using the strain-rate-dependent mechanical behavior rather than quasi-static properties alone.

Assessment of Resistance to Application Environment of Geotextile Composites (복합형 지오텍스타일의 적용환경에 대한 저항성 평가)

  • Jeon, Han-Yong;Lyoo, Won-Seok;Ghim, Han-Do;Chung, Chin-Gyo;Cho, Bong-Gyun
    • Journal of the Korean Geosynthetics Society
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    • v.2 no.3
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    • pp.25-38
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    • 2003
  • Geotextile composites to improve the resistance to the application environment were manufactured of recycled polyester geotextile with carbon black as ultraviolet stabilizer and polypropylene geotextile by needle-punching method. Mechanical properties, ultraviolet resistance and chemical stability were evaluated. Retention ratio of tensile properties of polypropylene geotextiles were decreased about 50% with the exposed condition by ultraviolet but those of geotextile composites showed the slightly decrease. Geotextile composites which have larger weights of recycled polyester geotextile were more stable against ultraviolet. For chemical stability, the changes of tensile strength values of geotextile composites were in the range of -20~+10% at the various chemical conditions.

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Physical Property of Carbon Fiber Reinforced Thermoplastic Polymer based Composites by Repeating Processing of PP Composition (PP 복합 조성물의 반복 가공에 의한 열가소성 폴리머 탄소섬유 강화 복합재료의 물리적 특성 변화 연구)

  • Jin-Woo Lee;Jae-Young Lee;Seoung-Bo Shin;Jae-Hyung Park;Hyun-Ju Park;Kyung-Hun Oh;Jin-Hyuk Huh;Yun-Hae Kim;Ji-Eun Lee
    • Composites Research
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    • v.37 no.2
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    • pp.68-75
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    • 2024
  • Polypropylene (PP), a thermoplastic resin with excellent mechanical, thermal, chemical, and water resistance properties, has been attracting attention due to its economic efficiency and recyclability. However, repeated processing of thermoplastic resins can lead to property degradation, and the point at which quality degradation occurs varies depending on the processing conditions. In this study, we evaluated the performance changes of composite materials with repeated processing by blending PP resin with various additives and conducting extrusion and injection processes repeatedly. In addition, we evaluated the mechanical properties of composite materials to evaluate the effect of MFI value change during repeated processing on fiber impregnation in composite material processing.

A Constitutive Equation Including Strain Rate Effect for the Expanded Polypropylene (변형률 속도가 고려된 발포 폴리프로필렌의 구성방정식)

  • Kim, Han-Kook;Cheon, Seong S.
    • Composites Research
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    • v.27 no.4
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    • pp.130-134
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    • 2014
  • The purpose of this paper is to build DB in order to Propose new constitutive equations by redefining constitutive equations for Polyurethane presented by Jeong et al. [12] based on Quasi-static test and Impact test DB of Expanded polypropylene using cylindrical specimens with 4 different densities presentsd by Kim et al. [7] for EPP foam and combining the impulse-momentum theory.