• Title/Summary/Keyword: 변질작용

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Element Dispersion and Wallrock Alteration of TA26 Seamount, Tonga Arc (통가열도 TA26 해저산의 모암변질과 원소분산)

  • Yoo, Bong-Chul;Choi, Hun-Soo;Koh, Sang-Mo
    • Economic and Environmental Geology
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    • v.44 no.5
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    • pp.359-372
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    • 2011
  • TA26 seamount, which is located at south part of Tonga arc, occurs widely hydrothermal plume and is area that sampled hostrock, hydrothermal ore and hydrothermal alteration rock for this study. Hostrocks are basalt and basaltic andesite. Altered rocks by hydrothermal solution consists of plagioclase, pyroxene, pyrite, ilmenite, amorphous silica, barite, smectite, iron sulfates, Fe-Si sulfates and Fe silicates. Gains and losses of major, trace and rare earth elements during wallrock alteration suggest that $K_2O$(+0.04~+0.45 g), $SiO_2$(-6.52~+10.56 g), $H_2O$(-0.03~+6.04 g), $SO_4$(-0.46~+17.54 g), S(-0.46~+13.45 g), total S(-0.51~+16.93 g), Ba(-7.60~+185078.62 g), Sr(-36.18~+3033.08 g), Ag(+54.83 g), Au(+1467.49 g), As(-5.80~+1030.80 g), Cd(+249.78 g), Cu(-100.57~+1357.85 g), Pb(+4.91~+532.65 g), Sb(-0.32~+66.59 g), V(-113.58~+102.94 g) and Zn(-49.56~+14989.92 g) elements are enriched from hydrothermal solution. Therefore, gained(enriched) elements(($K_2O$, $H_2O$, $SO_4$, S, total S, Ba, Sr, Ag, Au, As, Cd, Cu, Pb, Sb, V, Zn) represent a potentially tools for exploration of sea-floor hydrothermal deposits from the Tonga arc.

Text integration processing based on connectives in Aphasics (실어증 환자의 접속사 정보처리에 관한 연구)

  • Kim, Soo-Jeong;Moon, Young-Sun;Kim, Mi-Ra;Kim, Yoo-Jeong;Nam, Ki-Chun
    • Annual Conference on Human and Language Technology
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    • 1999.10e
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    • pp.441-446
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    • 1999
  • 본 연구는 접속사를 통한 텍스트 통합 과정이 논리적 추론 종류에 따라 다른 정보처리 과정 혹은 다른 종류의 단원적 구조(modular structure in language processing)에 의해 처리되는지를 조사하기 위해 실시되었다. 또한, 접속사를 통한 추론 과정이 실어증의 증상 종류에 따라 다른 종류의 언어정보처리 손상이 있는지를 평가하기 위해 실시되었다. 실험에 참가한 환자는 이해성 실어증환자(Wernicke aphasic), 전반성 실어증 환자(Global aphasic), 표현성 실어증 환자(Broca aphasic) 등이었다. en 종류의 과제를 이용하였다. 한 과제는 앞 뒤 문장을 논리적 관계성을 표현하는 접속사를 채워 넣는 과제였고 다른 과제는 접속사가 포함된 텍스트가 옳은지를 판단하는 정오 판단 과제였다. 실험재료 문장에 사용된 접속사는 추가적인 정보를 제공하는 '그리고'와 대등 관계를 나타내는 '그러나' 및 인과 관계를 표현하는 '그래서' 였다. 이 세 종류의 접속사는 각기 다른 논리적 관계성을 나타낸다. 실험 결과는 실어증 환자가 전반적으로 채워 넣기 과제에서 보다는 정오 판단 과제에서 더 많은 실수를 보였으며, 표현성 실어증 환자보다는 이해성 실어증 환자가 더 많은 오류를 보였다. 또한, 세 종류의 접속사 중에 '그리고'가 표함된 텍스트에서 더 많은 실수를 보였다. 이 연구에서 나타난 흥미 있는 결과는 표현성 실어증 환자는 '그러나' 접속사가 포함된 텍스트에서의 수행이 '그래서'가 포함된 경우에서보다 좋은 반면에 전반성 실어증 환자는 '그래서'를 포함하는 텍스트에서의 수행이 '그러나'를 포함하는 텍스트에서의 수행이 더 우수해서 이중해리(double dissociation)가 나타난다는 사실이다. 이 결과는 선후 문장이 어떤 종류의 논리적 관계성을 지니는가에 따라 다른 종류의 정보처리가 진행된다는 것을 암시하는 결과이다.>$\textrm{cm}^2$.。C로 비교적 양호한 초전박막의 전기적 특성을 나타내었다.(Mg+Fe)비를 갖고 전자에 비해 Al이 풍부한 환경에서 생성되었으며, 따라서 활석과 연관되지 않은 녹니석은 생성시 광체와 인접한 화강아질 편마암에 의해 주로영향을 받았을 것으로 생각된다. 녹니석의 이러한 2가지 화학조성상의 경향은 녹니석과 공존하는 운모류나 각섬석류들의 화학분석결과와도 잘 일치한다. 이러한 결과는 이 지역의 활석 광상이 초염기성암 기원의 사문암이 열수변질작용을 받아 생성되었음을 명확하게 지시하며, 따라서 활석 광석내에 존재하는 녹니석은 활석의 근원 광물로서 녹니석편암 및 녹니석 편마암 매의 녹니석이 활석화되고 남은 잔존광물이 아니라, 주변암에 의해 성분상의 영향을 받은 열수와 사문암과의 변질교대작용에 의한 활석화과정 중에 주로 생성된 것으로 추정된다. 이러한 결과는 연구지역의 활석광상이 초염기성암의 사문암화 작용과 활석화 작용의 두 가지 변질작용에 의해 형성되어졌음을 알려준다.농도 증가 없이 폐 조직에 약 50배 정도의 고농도 cisplatin을 투여할 수 있었으며, 또한 분리 폐 관류 시 cisplatin에 의한 직접적 폐 독성은 발견되지 않았다이 낮았으나 통계학적 의의는 없었다[10.0%(4/40) : 8.2%(20/244), p>0.05]. 결론: 비디오흉강경술에서 재발을 낮추기 위해 수술시 폐야 전체를 관찰하여 존재하는 폐기포를 놓치지 않는 것이 중요하며, 폐기포를 확인하지 못한 경우와 이차성 자연기흉에 대해서는 흉막유착술에 더 세심한 주의가 필요하다는 것을 확인하였다. 비디오흉강경수술은 통증이 적고, 입원기간이 짧고, 사회로의 복귀가 빠르며, 고위험군에 적용할 수 있고, 무엇보다도 미용상의 이점이 크다는 면에서 자연기흉에 대해 유용한 치료방법임에는 틀림이 없으나 개흉술에 비해 재발율이 높고 비용이 비싸다는 문제가 제기되고 있는 만큼

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Reaction Path Modeling of Granitic Cultural Properties and Its Implication for Preservation (화강암질 석조문화재의 풍화반응경로 특성과 보존에 대한 제언)

  • Park Maeng-Eon;Sung Kyu-Youl
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.2
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    • pp.83-92
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    • 2005
  • Dissolution rate of minerals may differ from climates configuration, but weathering rate of feldspars is generally proved to be relatively higher The result of geochemical reaction modeling indicates the acid water of pH 4.5 excluding any other variables, was 2.3 times higher than that in ordinary rain of pH 5.7. This result proved that pH is very important factor in preservation of granite cultural properties. To prevent the weathering of stone cultural properties, weathering characteristics of stones should be studied first and constitution of dry environments, using water repellent or oil coating, isolating water which cause chemical weathering reaction like hydration and oxidization should be considered. Considering the long-term reactions between granite and rain, selection of materials, which can bring neutralization and non-oxidization conditions, are very important in using cleaning agents and biological controls.

Geochemical Aspects of Groundwater in Granite Area and the Origin of Fluoride with Emphasis on the Water-Rock Interaction (화강암지역 지하수 수질의 특징과 불소원인에 관한 물-암석반응 연구)

  • Choo, Chang-Oh;Kim, Jong-Tae;Chung, Il-Moon;Kim, Nam-Won;Jeong, Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.18 no.1
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    • pp.103-115
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    • 2008
  • The purposes of this study are to understand characteristic water-rock interaction mechanisms of groundwater in the granite area of Geochang and Hapcheon areas, Gyeongnam-do and to clarify the origin of fluoride. The possible water-rock interaction process and the source of fluorine were studied using water chemistry, rock chemistry, mineralogy by XRD, and microtexture analysis by backscattered electron image of the electron microprobe. No clear relationships between F and hardness was found. But the fluorine content increases to some extent with pH and well depth. Preferential alteration due to water-rock interaction took place along edges or cleavage, or margins of biotite. Because biotite is highly subject to alteration in granite aquifer, fluorine in groundwater is originated from the leaching of biotite.

Genesis of Clay Minerals in the Vicinity of Gwangpo Bay, Southern Coast of Korea (광포만 집수유역내에 분포하는 점토광물의 성인에 관한 연구)

  • PARK Maeng-Eon;SONG Yong-Sun;KIM Hee-Joon;KIM Dae-Choul;PAIK In-Sung;CHUNG Sang-Yong;SONG Shi-Tae
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.21 no.4
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    • pp.259-268
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    • 1988
  • Clay deposits in the vicinity of the Gwangpo Bay, southern coast of Korea, occur restrictively in anorthositic masses. Laumontite and meta-halloysite are the predominant clay minerals with iron oxides at the uppermost surface. Chlorite and halloysite occur in deeper zone. Beneath the main clay horizon, but not above, some anorthositic rocks are pervasively altered to quartz, sericite, chlorite, pyrite and montmorillonite along the hydrothermal channels. The hypotheses of hydrothermal and weathering origins of the clay minerals are tested by multi-component equilibrium calculations of the reactions of modified hydrothermal water and rain water with anorthositic rocks at $100^{\circ}C\;and\;25^{\circ}C$, respectively. The calculated mineralogy from the reaction with rain water resembles natural mineral assemblage except for abundance in laumontite. The result implies that the weathering process is the main machanism of the formation of clay deposits in the area.

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Supergene Alteration of Amphibole in Suryun Kaolin Deposits: Mineralogical and morphological Studies (수륜 고령토광산에서 산출되는 각섬석의 표성 변질작용: 광물학적 및 형태적 연구)

  • 김수진;아비드무타자칸;이동진
    • Journal of the Mineralogical Society of Korea
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    • v.2 no.1
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    • pp.37-46
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    • 1989
  • X-ray, optical and electron microscope studies exhibit that the amphiboles in anorthositic saprolite from kaolin deposits, located in Suryun-myeon, Seongju-gun, Kyungsangbuk-do, have altered under weathering conditions to smectite, mixed-layer mineral, vermiculite and goethite. In early supergene alteration stage when rock structure is still preserved, smectite occurs as initial weathering product of amphibole. Further weathering leads to the formation of mixed-layer mineral, vermiculite and goethite as indicated by XRD and SEM studies. Scanning electron microscopy studies of amphibole show that the dissolution of amphibole proceeds by selective etching at the surface along weaker zones producing distinct etch pattern, The calcic amphiboles according to electron microprobe analyses, show leaching of the most mobile elements (Mg, Ca and Fe) during alteration.

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Characteristics of the Copper Mineralization in Tsogttsetsii Area, Mongolia (몽골 촉트체치 지역의 동 광화작용 특성)

  • Davaasuren, Otgon-Erdene;Lee, Bum Han;Kim, In Joon;Ryoo, Chung-Ryul;Heo, Chul-Ho
    • Journal of the Mineralogical Society of Korea
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    • v.29 no.1
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    • pp.23-34
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    • 2016
  • Tsogttsetsii area, an intrusive complex associated with Cu porphyry mineralization, is located in the Gurvansaikhan island arc terrane of the Central Asian Orogenic belt, Southern Mongolia. We performed a reconnaissance survey in Tsogttsetsii area. Cu mineralization in Tsogttsetsii area is porphyry Cu type related with alkali granite intruded in Permian. Mineralogical and textural properties of the ores and associated minerals were analyzed using X-ray diffraction, thin section petrography, and Scanning electron microscopy-Energy dispersive spectroscopy (SEM-EDS). Ore minerals identified in polarizing microscope are magnetite, pyrite and bornite. Propylitic alteration zone occurs broadly in the area where malachite occurrences are shown to be spread intensively in alkali granite area. Quartz, sericite, chlorite and epidote were observed in the alteration zone samples. As results of XRD and SEM-EDS analysis, samples of copper oxides were composed mainly of malachite, cuprite and small amounts of quartz. Average and maximum Cu contents of samples collected from malachite occurrences area are 759 ppm and 6190 ppm, respectively. The characteristics of mineralization in Tsogttsetsii area is similar to Oyu Tolgoi Cu-Au (Mo) deposit and Tsagaan Suvarga Cu-Mo deposit which are 56 km south and 120 km northeast from Tsogttsetsii area, respectively. Characteristics of the study area, such as the geology, tectonic environment, lithology, mineralization, and alterations of the rocks within the survey area, resemble the characteristics of other porphyry deposits. Therefore further exploration including Induced Polarization (IP) survey for identifying subsurface orebody is required.

Assessment of Rocks and Alteration Information Extraction using ASTER data for Övörkhangaii Province, Mongolia (ASTER 영상자료를 활용한 몽골 오보르항가이(Övörkhangai) 일대 암상 빛 변질 정보추출의 활용가능성 평가)

  • Jeong, Yongsik;Yu, Jaehyung;Koh, Sang-Mo;Heo, Chul-Ho
    • Economic and Environmental Geology
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    • v.48 no.4
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    • pp.325-335
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    • 2015
  • This study examined the possibility to extract potential alteration zones and lithologic information based on ASTER band ratio techniques for mineralized area located in ${\ddot{O}}v{\ddot{o}}rkhangai$ province, Mongolia, and the effectiveness of remote sensing as a preliminary exploration tool for mineral exploration was tested. The results of ABRLO, PBRLO, and PrBRLO models indicated that the detection of argillic zone requires the verification of the samples to verify hydrothermal alteration minerals as clay minerals can formed by weathering process, whereas phyllic-propylitic zones were considerably related to the spatial distribution of the intrusive bodies, geological structures, and ore distribution. QI and MI results showed that QI is more useful for sedimentary rocks such as conglomerate and sandstone than meta-sedimentary like quartzite, and MI faced relatively uncertain in detection of felsic or mafic silicate rocks. QI and MI may require additional geologic information such as the characteristics of samples and geological survey data to improve extraction of lithologic information, and, if so, it is expected that remote sensing technique would contribute significantly as a preliminary geological survey method.

Study on Constituent Minerals and Illitization Characteristics of Yeongdong Illite Ore (영동 일라이트 광체의 구성광물 및 일라이트화 특성 연구)

  • EunJi Baek;Yu Na Lee;Byeongyong Yu;Dongbok Shin;Youngseuk Keehm;Sun Young Park;Hyun Na Kim
    • Korean Journal of Mineralogy and Petrology
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    • v.36 no.1
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    • pp.41-54
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    • 2023
  • Illite is a common mineral that forms readily from feldspar and mica via hydrothermal alteration and exhibits various characteristics depending on the degree of hydrothermal alteration. To ensure continued mining of high-quality illite ore, it is crucial to understand the illitization. Thus, this study collected ores from two illite ore deposit and their surrounding alteration zones in Yeongdong-gun, Chungcheongbuk-do, a significant source of illite in the Republic of Korea, to determine the constituent mineral contents and textural characteristics. Polarized light microscopy analyses revealed that the illite ore deposit were highly illitized with little remaining textural characteristics of the parent mica schist, and only some quartz was present. The ore zone contained illite, muscovite, quartz, and feldspar, with illitization primarily occurring around feldspar and quartz. X-ray diffraction analyses identified that the content of illite/muscovite was approximately 50-75 wt.%, with a maximum of 75 wt.%. Additionally, X-ray fluorescence analyses indicated a linear increase in K2O content with increasing illite content, showing the highest correlation among the major components analyzed. It is suggested that the illite in the Yeongdong area results from feldspar and quartz alteration by hydrothermal fluids along the fault, with illitization of feldspar occurring before that of quartz. The results of this study are expected to contribute to the development of high-quality illite ore deposit in Yeongdong, Chungcheongbuk-do.

Hydrothermal Alteration Related to Cretaceous Felsic Magmatism in the Seongsan Dickite Deposits, Korea; Estimation of Ore - Forming Temperature and aNa+/aK+ Ratio of the Hydrothermal Fluid (성산딕카이트광상에서의 백악기산성마그마티즘에 관련된 열수변질작용 ; 광상형성온도의 측정 및 열수용액의 aNa+/aK+)

  • Kim, In Joon
    • Economic and Environmental Geology
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    • v.25 no.3
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    • pp.259-273
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    • 1992
  • The Seongsan mine is one of the largest dickite deposits in the southwestern part of the Korean Peninsula. The main constithent minerals of the ore are dickite and quartz with accessory alunite, kaolinite and sericite. The geology around the Seongsan mine consists mainly of the late Cretaceous felsic volcanic rocks. In the studied area, these rocks make a synclinal structure with an axis of E-W direction plunging to the east. Most of the felsic volcanic rocks have undergone extensive hydrothermal alteration. The hydrothermally altered rocks can be classified into the following zones: Dickite, Dickite-Quartz, Quartz, Sericite, Albite and Chlorite zones, from the center to the margin of the alteration mass. Such zonal arrangement of altered rocks suggests that the country rocks, most of which are upper part of the rhyolite and welded tuff, were altered by strongly acid hydrothermal solutions. It is reasonable to consider that initial gas and solution containing $H_2S$ and other compounds were oxidized near the surface, and formed hydrothermal sulfuric acid solutions. The mineralogical and chemical changes of the altered rocks were investigated using various methods, and chemical composition of fifty-six samples of the altered rocks were obtained by wet chemical analysis and X.R.F. methods. On the basis of these analyses, it was found that some components such as $SiO_2$, $Al_2O_3$, $Fe_2O_3$, CaO, MgO, $K_2O$, $Na_2O$ and $TiO_2$ were mobilized considerably from the original rocks. The formation temperature of the deposits was estimated as higher than $200^{\circ}C$ from fluid inclusion study of samples taken from the Quartz zone. On the basis of the chemical composition data on rocks and minerals and estimated temperatures, the hydrothermal solutions responsible for the formation of the Seongsan dickite deposits were estimated to have the composition: $m_{K^+}=0.003$, $m_{Na^+}=0.097$, $m_{SiO_2(aq.)}=0.008$ and pH=5.0, here "m" represents the molality (mole/kg $H_2O$).

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