• Proceedings of the KSME Conference
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• 2005.11a
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• pp.66.1-66.1
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• 2005

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.2961-2966
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• 2007

When the pressure at the weak spot established at a certain part of a high pressure vessel or piping system exceeds a design pressure, this weak spot is burst, and the pressurized gas emitted through the weak spot will cause a compression wave system. In this connection, in the present study, an experimental study by using a conventional shock tube facility is performed to estimate the effects of the material of diaphragm, curvature radius and thickness of materials on the valve opening time in diaphragm. Pressure sensor having 500kHz in natural frequency is installed at 35mm downstream of the rupture diaphragm to measure the static pressure history of propagating and being accumulated compression wave. 4 kinds of materials are used as diaphragm that is aluminium, copper, stainless steel and zinc. The diaphragm radii of curvature R are ${\infty}$, 120mm and 60, respectively. And the depth for $90^{\circ}$ groove is 0.04mm. It is found that the smaller the tensile strength and elongation of the rupture diaphragm is, the smaller the radius of curvature of the rupture diaphragm is, and for the same conditions the thinner the thickness of the rupture diaphragm is, the shorter the valve opening time becomes. Also, the tensile strength, elongation and the radius of curvature of the rupture diaphragm for the same conditions are smaller, the maximum pressure rise caused by the coalescences of the compression wave is smaller. Finally the pressure ratio is higher, the valve opening time is shortened and gradient of pressure increment is more steepen.

• Korean Chemical Engineering Research
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• v.50 no.3
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• pp.492-498
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• 2012

In this study, hydrodynamics such as solid circulation rate and voidage in the desulfurizer and the reaction characteristics of Zn-based solid sorbents were investigated using lab-scale high pressure and high temperature desulfurization process. The continuous HGD (Hot Gas Desulfurization) process consist of a fast fluidized bed type desulfurizer (6.2 m tall pipe of 0.015 m i.d), a bubbling fluidized bed type regenerator (1.6 m tall bed of 0.053 m i.d), a loop-seal and the pressure control valves. The solid circulation rate was measured by varying the slide-gate opening positions, the gas velocities and temperatures of the desulfurizer and the voidage in the desulfurizer was derived by the same way. At the same gas velocities and the same opening positions of the slide gate, the solid circulation rate, which was similar at the temperature of $300^{\circ}C$ and $550^{\circ}C$, was low at those temperatures compared with a room temperature. The voidage in the desulfurizer showed a fast fluidized bed type when the opening positions of the slide gate were 10~20% while that showed a turbulent fluidized bed type when those of slide gate were 30~40%. The reaction characteristics of Zn-based solid sorbent were investigated by different desulfurization temperatures at 20 atm in the continuous operation. The $H_2S$ removal efficiency tended to decrease below the desulfurization temperature of $450^{\circ}C$. Thus, the 10 hour continuous operation has been performed at the desulfurization temperature of $500^{\circ}C$ in order to maintain the high $H_2S$ removal efficiency. During 10 hour continuous operation, the $H_2S$ removal efficiency was above 99.99% because the $H_2S$ concentration after desulfurization was not detected at the inlet $H_2S$ concentration of 5,000 ppmv condition using UV analyzers (Radas2) and the detector tube (GASTEC) which lower detection limit is 1 ppmv.