• Journal of the Korean Chemical Society
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• v.41 no.10
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• pp.524-534
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• 1997

Analysis of additives in cured rubber is often a difficult task for analytical chemists because of a wide variety of complex components. Conventional analyses of additives and rubbers have been done in multistep, off-line processes with large sample size and extensive sample preparations. The coumarone-indene resin, resorcinol-formaldehyde resin, and prevulcanization inhibitor have been characterized by their pyrolysis pathways and mass spectra of characteristic pyrolyzates. Pyrolysis Gas Chromatography/Mass Spectrometry (Py-GC/MS) was used in the identification of additives without any sample pretreatment. This result shows that several organic additives in cured rubber can be directly analyzed.

• Korean Journal of Food Science and Technology
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• v.31 no.6
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• pp.1563-1569
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• 1999

For the encapsulation of flavor compounds, maltodextrin (MD), gum arabic (GA) alkenylsuccinated modified starch (MS) and gellan gum were chosen for wall materials and their combination was optimized. Five fruit flavor compounds having boiling point of $90{\sim}200^{\circ}C$ were selected as core materials and their mixture was incorporated with rapeseed oil (flavor mixture to oil = 1 : 4). Flavor compound mixture to wall material ratio of 1 : 4 was selected, and the amount of maltodextrin was fixed to 30% of the wall material mixture. Gellan gum was selected as an additional wall material to increase emulsion stability. The optimum combination ratio of the wall material mixture for maximal total oil retention and minimal surface oil content is : 30.0% MD ; 26.4% GA ; 39.6% MS ; 4% gellan gum.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.3
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• pp.66-74
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• 2016

The aim of this research work is to investigate the mix proportion of multi-component cement incorporating ground granulated blast furnace(GGBFS), fly ash(FA) and silica fume(SF) as an addition to cement in ternary and quaternary combinations. The water-binder ratio was 0.45. In this study, 50% and 60% replacement ratios of mineral admixture to OPC was used, while series of combination of 20~40% GGBFS, 5~35% FA and 0~15% SF binder were used for fundamental characteristics tests. This study concern the GGBFS/FA ratio and SF contents of multi-component cement including the compressive strength, water absorptions, ultrasonic pulse velocity(UPV), drying shrinkage and X-ray diffraction(XRD) analysises. The results show that the addition of SF can reduce the water absorption and increase the compressive strength, UPV and drying shrinkage. These developments in the compressive strength, UPV and water absorption can be attributed to the fact that increase in the SF content tends basically to consume the calcium hydroxide crystals released from the hydration process leading to the formation of further CSH(calcium silicate hydrate). The strength, water absorption and UPV increases with an increase in GGBFS/FA ratios for a each SF contents. The relationship between GGBFS/FA ratios and compressive strength, water absorption, UPV is close to linear. It was found that the GGBFS/FA ratio and SF contents is the key factor governing the fundamental properties of multi-component cement.

• Journal of the Korean Recycled Construction Resources Institute
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• v.3 no.3
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• pp.268-276
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• 2015

In this study, $CO_2$ reduction type quaternary component high fluidity concrete was produced with more than 80% reduction in cement quantity to increase the use of industrial byproducts and enhance construction performance, thereby reducing $CO_2$ emissions. Furthermore, the quality properties, and $CO_2$ reduction performance of this concrete were evaluated. As a result of the quality evaluation of quaternary component blended high fluidity concrete with $CO_2$ reduction, the target performance could be achieved with a 80% or more reduction of cement quantity by mixing a large amount of industrial byproducts. The required performance level was obtained even though the flow, dynamic, and durability characteristics decreased a little compared to conventional mix. In addition, to analyze the $CO_2$ reduction performance of quaternary component blended high fluidity concrete with $CO_2$ reduction, the life cycle assessment (LCA) of the concrete was performed and the results showed that compared to the conventional mix, the carbon emissions decreased by 62.2% and the manufacturing cost by 24.5%.

• Journal of Conservation Science
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• v.17 s.17
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• pp.33-38
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• 2005

One piece of Haedong-Tongue(해동통보) minted at 1,102 A.D. was excavated from No.20 wooden coffin, Sinbong-dong, Cheongju. It was analyzed by micro-XRF and ICP and determined the concentrations of ten elements such as Cu, Pb, Sn, Zn, Fe, Mn, Sb, Co, As, Ag and Ni. The measurement of lead isotope ratios was also carried out in order to predict the provenance of raw materials used for minting of Haedong-Tongbo. It was found that Haedong-Tongbo was minted with three compositions of $Cu\;75.5\%,\;Pb\;13.3\%\;and\;Sn\;6.0\%$, which were different from the typical composition of Chosen-Tongbo and Sangpyung-Tongbo used in Chosen dynasty. Lead isotope ratios of Haedong-Tongbo showed that the provenance of lead used for minting of it suggested the possibility to be originated from Southern part of Korea.

• Korean Journal of Food Science and Technology
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• v.25 no.5
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• pp.475-480
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• 1993

This study was carried out to estimate the bind values of raw meats which are used as an input constaint in the least-cost formulation of an emulsion-type sausage. The least-cost formulation will be useful for Korean meat processore to produce more effectively as meat-grade system is put in force. The analysis results in compositions, functionalities, and pigment contents of raw meats were various according to the difference of species and their parts. The cohesiveness was correlated positively with moisture or protein content and negatively with fat content. Consequently two multiple regression equations for bind value could be derived from the compositions of raw meats. The equations then may be useful for predicting the bind value of a raw meat which presently has not been analysed.

• Microbiology and Biotechnology Letters
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• v.1 no.2
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• pp.79-87
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• 1973

The superior materials for substitution of bean and red pepper paste were selected through the examination of chemical compositions and the function. The following results were obtained. (1) The enzyme activities were higher in the process of koji manufacturing for brewing bean paste and red pepper paste in barley koji and in corn powder koji, but those of wheat koji were inferior (2) Corn powder was proved as the most excellent substitute, because its components and functioning were the best. (3) In the production of the paste the use of corn powder and bean with equal amount was proved as good as those product of the traditional way of the brewing. (4) By using the corn powder, the production cost can be cut down to 25％ in the production of bean paste, and to 23％ in the production of red pepper paste, comparing with those of traditional brewing products

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.24 no.1
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• pp.27-32
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• 2014

This study analyzed the fundamental characteristics of concrete according to a ternary system mixing in order to reduce hydration heat of mass concrete and to improve early age strength. The results are as follows. The fluidity of unconsolidated concrete satisfied the target scope regardless of the binder conditions. When the replacement ratio between FA and BS increased, the slump of low heat-A mix and low heat-B mix increased, and air content was not affected by the change of binders. As for setting time, low heat cement mix had the fastest regardless of W/B, and high early strength low heat mix achieved 6 hours' reduction compared with low heat-B mix at initial set, and 12 hours' reduction at the final set respectively. As for the simple hydration heat, the low mix peak temperature was the highest and low heat-B mix had the lowest temperature. And high early strength low heat mix was similar with that of low heat-B. The compressive strength of hardened concrete had similar strength scope in all mixes except for low heat-B mix at early ages, and had unexceptionally similar one without huge differences at long-term ages.

• Korean Journal of Construction Engineering and Management
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• v.20 no.1
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• pp.133-140
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• 2019

The concrete mix should be designed and produced to reflect the specific site conditions during concrete placement. That is, the concrete mix design should be planned considering temperatures, work environments, pouring methods, etc. The objective of this research is to understand the external factors of curing temperature and delay time that influence concrete strengths during pouring work, and provide concrete mix design that can be most robust to the effects of external factors. The Taguchi's robust method is used in preparing the concrete mix design to achieve the research objective. In a case study, an indoor concrete test was performed to find the optimal combination of concrete mixes with external factors of curing temperature and delay time. Concrete test cylinders were made to test concrete strengths given different external factors. The study results showed that the optimal performance of concrete strength can be achieved by applying the robust method when preparing a concrete mix design.

• Elastomers and Composites
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• v.14 no.3
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• pp.161-168
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• 1979

이 논문(論文)의 목적(目的)은 열적안정성(熱的安定性) 및 내노화성면(耐老化性面)에 있어서 디엔제3성분단위체(第三成分單位體)(diene termonomer)의 각각(各各)의 종류(種類)가 EPDM의 중합체(重合體)의 성질(性質)에 미치는 효과(效果)를 구명(究明)하는데 있다. 제3성분단위체(第三成分單位體) 5종(種)으로 각각(各各) 다음과 같다. 즉, ethylidene norbonene(ENB), butadiene(BD), dicyclopentadiene(DCPD), methyltetrahydroindene (MTHI) 및 1,4-hexadiene(HD)이다. 이들을 써서 만든 각각(各各)의 EPDM은 동(同)몰의 불포화도(不飽和度)로 만들어졌다. 또한 가황계(加黃系)는 동일(同一)한 황/촉진제계(黃/促進劑系)를 사용(使用)하였다. ENB-EPDM이 순(純)고무배합체(配合體) 및 충전제함유배합체(充塡劑含有配合體)의 가황(加黃)에 있어서 모두 함께 가장 빠른 가황속도(加黃速度)를 보였다. HD-EPDM은 순(純)고무배합체(配合體)에서 가황속도(加黃速度)가 가장느렸으나 충전제함유배합물(充塡劑含有配合物)에서는 DCPD-EPDM보다는 발랐다. BD-EPDM을 제외(除外)한 이들 중합체(重合禮)는 거의 같은 초기가교밀도(初期架橋密度)를 갖는다. 가교밀도(架橋密度) 및 가교형(架橋型)을 분석(分析)하여 보면 BD-EPDM 쇄(鎖)에서 부타디엔 단위(單位)는 블럭을 이루고 있다. 또한 HD-EPDM은 순(純)고무가황체(加黃體) 및 충전제배합가황체(充塡劑配合加黃體)에 있어서 원가교결합(原架橋結合)의 50%가 monosulfide의 구조(構造)를 가지고있다. 이외(外)의 4종(四種)의 EPDM 폴리머는 보다 낮은 monosulfide구조를 가진다. $177^{\circ}C(350^{\circ}F)$의 노화온도(老化溫度)에서 ENB 및 HD폴리머는 약(約) 65% monosulfide 가교(架橋) 및 거의 동일(同一)한 파괴에너지값$(E_b)$을 가진다. 그러나 1,4HD의 원가교(原架橋)의 monosulfide 구조함량(含量)이 보다 높다고 해서 그의 내노화성(耐老化性)이 다른 폴리머보다 더 좋다고는 생각되지 않는다. DCPD는 $177^{\circ}C(350^{\circ}F)$의 노화온도(老化溫度)에서 똑같은 monosulfide가교(架橋)를 가지나 노화온도(老化溫度)가 $259^{\circ}C(500^{\circ}F)$로 높아짐에 따라 monosulfide 함량(含量)도 증가(增加)한다. $550^{\circ}F(287.7^{\circ}C)$의 노화온도(老化溫度)에서는 EPDM폴리머의 모든 가교(架橋)가 monosulfide구조가 되나 전가교밀도(全架橋密度) 및 $E_b$ (신장률(伸長率), 절단시(切斷時)의)는 대단(大端)히 낮은 것으로 나타나는데 이것은 산화(酸化)에 의한 노화(劣化)에 기인(基因)되는 것으로 보인다. 질소기류(窒素氣流)속에서의 TGA의 분석결과(分析結果)를 보면 EPDM 가황체(加黃體)는 $800\sim935^{\circ}F(427\sim502^{\circ}C)$의 온도범위(溫度範圍)에서 분해(分解)되며 공기중(空氣中)에서는 $750\sim935^{\circ}F$ 범위(範圍)에서 분해(分解)한다.