• Title/Summary/Keyword: 방출스펙트럼

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다양한 기체를 사용한 대기압 플라즈마 젯에 대한 세포 내 활성 산소종의 영향 연구

  • Jo, Hye-Min;Kim, Seon-Ja;Jeong, Tae-Hun;Im, Seon-Hui
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.542-542
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    • 2013
  • 저온 플라즈마를 발생시키는 대기압 마이크로-플라즈마 젯(Micro-plasma jet)을 이용하여 플라즈마와 세포와의 상호작용에 대한 연구를 진행하였다. 세포의 대사과정에서 생성되는 활성산소 종(Reactive Oxygen Species, ROS)은 세포에 산화 스트레스를 유발시킨다. 이러한 스트레스는 세포 예정사(programmed cell death)의 원인이 된다. 플라즈마 형성 기체로 헬륨, 아르곤, 질소를 사용하여 각각의 기체에 따른 세포의 형태 변화 및 세포 내 활성 산소 종의 영향을 분석하였다. 실험에 사용된 세포는 인체의 폐암 세포[Human lung cancer cell, A549]이며 플라즈마 처리 후 Intracellular ROS assay를 통하여 플라즈마에서 발생되는 활성 산소 종(Reactive Oxygen Species, ROS)이 세포 내에 들어가 활성 산소 종을 증가시키는 것을 확인하였다. 이때, 플라즈마에서 발생되는 활성 산소 종(Reactive Oxygen Species, ROS)들은 광 방출 스펙트럼(Optical Emission Spectroscopy)로 분석하였고, 기체별로 비교하여 보았다. 또한, 이 때 발생되는 플라즈마의 전류-전압 특성에 따른 optical intensity를 비교하였다.

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A Study on the Spectrum Analyzing of Internal Leak in Valve for Power Plant Using Acoustic Emission Method (음향방출법에 의한 발전용 밸브내부 누설의 스펙트럼분석 연구)

  • Lee, Sang-Guk;Lee, Sun-Ki;Lee, Jun-Shin;Sohn, Seok-Man
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.694-699
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    • 2004
  • The purpose of this study is to estimate the availability of acoustic emission method to the internal leak of the valves at nuclear power plants. The acoustic emission method was applied to the valves at the site, and the background noise was measured for the abnormal plant condition. From the comparison of the background noise data with the experimental results as to relation between leak flow and acoustic signal, the minimum leak flow rates that can be detected by acoustic signal was suggested. When the background levels are higher than the acoustic signal, the method described below was considered that the analysis the remainder among the background noise frequency spectrum and the acoustic signal spectrum become a very useful leak detection method. A few experimental examples of the spectrum analysis that varied the background noise characteristic were given.

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Emission Spectroscopy of Unstable Molecules using a Fourier Transform Spectrometer (Fourier Transform 분광기를 이용한 불안정한 분자의 방출분광학)

  • Sang Kuk Lee;Un Sik Kim
    • Journal of the Korean Chemical Society
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    • v.37 no.4
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    • pp.371-377
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    • 1993
  • Fourier Transform UV/VIS spectrometer has been modified for emission spectroscopy with the technique of supersonic expansion, in which the unstable molecular radical $CH_3S$ has been generated in a jet by a high voltage DC discharge. The fluorescence spectra of the supersonically cooled radical have been recorded on a Fourier Transform UV/VIS spectrometer. The ratio of signal to noise of the spectra has been improved substantially. Also the rotational structure has been clearly resolved for $CH_3S$ molecular radical.

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Characteristics of Low-power Microwave Induced Plasma Emission Spectrum and Detection of $CO_2$ (저출력 마이크로파 유도 플라스마 방출스펙트럼의 특성과 $CO_2$ 분석)

  • Noh, Seung Man;Park, Chang Joon;Kim, Young Sang
    • Journal of the Korean Chemical Society
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    • v.40 no.4
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    • pp.235-242
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    • 1996
  • A surfatron-type microwave induced plasma (MIP) cavity has been constructed, which can be easily interfaced with a gas chromatograph. Various plasma gases such as He, Ar and N2 were used to generate the MIP and small amounts of CO2 gases were injected through the MIP to obtain characteristic spectrum of each plasma gas and to study feasibility of the MIP as a soft ionization source. Since He and Ar plasmas have high metastable state energy, it was not possible to detect sample gas in molecular state. With N2 plasma, however, a strong emission of molecular ions could be detected owing to its low metastable state energy.

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Preparation and characterization of CdS nanoparticle on the surface of silica nanoparticles (실리카 나노입자 표면에 CdS 나노입자의 제조 및 평가)

  • Kang, Yun-Ok;Choi, Seong-Ho;Gopalan, A.;Lee, Kwang-Pill
    • Analytical Science and Technology
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    • v.20 no.5
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    • pp.413-418
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    • 2007
  • Poly(vinylpyrrolidone) stabilized cadmium sulfide (CdS) nanoparticles were loaded onto the surface of silica ($SiO_2$) nanoparticles by using ${\gamma}$-irradiation. TEM micrograph reveals the presence of ~20nm sized CdS nanoparticles on the surface of $SiO_2$ nanoparticles. XRD patterns confirm the crystalline. PL spectra of the simple PVP-stabilized CdS nanoparticle and $SiO_2$@CdS composite confirm the differences in the emission characteristics between them. Two prominent emission peaks were noted around 550 nm and 600 nm for PVP-stabilized CdS nanoparticles). The emission peaks noted for the PVP-stabilized CdS nanoparticles were found to be blue shifted for $SiO_2$@CdS composites. Besides, an additional emission peak around 450 nm was noticed for the $SiO_2$@CdS composite. The presence of CdS nanoparticles influence the emission characteristics and induce quantum confinement effect.

비열평형 대기의 원자스펙트럼

  • Kim, Gap-Seong
    • Publications of The Korean Astronomical Society
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    • v.5 no.1
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    • pp.40-64
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    • 1990
  • 복사전달식, 통계평형식 및 전하 입자 보존식을 동시에 만족시키는 비열평형상태의 대기에 대하여 그 방출원자스펙트럼을 수치계산하였다. 등온, 중압의 비열평형 태양홍염을 대상모델로 선정하였는데 여기에 적응한 제한조건중 복사전달에 관련된 편미분방정식은 3점 근사 차분법에 의해 정리하였고 홍염중심에 대칭성을 가정하여 경제조건을 부여하였으며 대기의 물리상태에 관련된 비선형 연립방정식의 해는 완전선형화 기법을 통한 퓨트리에 소거법을 이용해 구하였다.

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A Study on the Luminescence Properties of LiGd9(SiO4)6O2:Ce3+ (LiGd9(SiO4)6O2:Ce3+ 형광 특성 연구)

  • Jin, Seongjin
    • Journal of the Korean Society of Radiology
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    • v.9 no.3
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    • pp.169-174
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    • 2015
  • $LiGd_9(SiO_4)_6O_2:Ce^{3+}$ phosphors were synthesized by solid-state reaction method. The structural characteristic was investigated by X-ray powder diffraction analysis. The emission and excitation spectra of the $Ce^{3+}$ ions doped $LiGd_9(SiO_4)_6O_2$ phosphors were obtained under the UV excitation. The emission spectra of $LiGd_9(SiO_4)_6O_2:Ce^{3+}$ shows the band at 410 nm corresponding to the $^2F_{5/2}$ and $^2F_{7/2}$ states of $Ce^{3+}$. The red shift of $Ce^{3+}$ emission is found as the $Ce^{3+}$ concentration increases, which could be explained by the change in crystal-field symmetry and strength with increasing $Ce^{3+}$ concentration. Fluorescence decay time of $Ce^{3+}$ was about 20 ns. When the concentration of $Ce^{3+}$ increases life time was slightly reduced.

Y2MoO6:RE3+(RE=Eu, Sm) 형광체 분말의 제조 및 특성

  • Lee, Jin-Hong;Jo, Sin-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.164-164
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    • 2015
  • 최근에 고효율의 적색 발광체를 개발하고자 무기물 모체에 다양한 활성제 이온을 주입하는 연구가 상당한 관심을 끌고 있다. 본 연구에서는 발광 효율이 높은 적색 형광체 분말을 제조하고자 두 종류의 활성제 이온 $Eu^{3+}$$Sm^{3+}$가 도핑된 $Y_2MoO_6$형광체 분말을 고체상태 반응법을 사용하여 전기로에서 $400^{\circ}C$에서 하소와 $1100^{\circ}C$에서 소결공정을 통하여 제조하였다. 활성제 이온의 몰 비에 따른 적색 형광체의 결정 구조, 발광과 흡광 스펙트럼을 조사하였다. 파장 299 nm로 여기 시킨 $Y_2MoO_6:Eu^{3+}$ 경우, 발광 세기가 가장 강한 611 nm의 주 피크를 방출하는 적색 스펙트럼이 관측되었으며, 함량이 0.01 mol에 0.2 mol로 증가함에 따라 611 nm의 주 적색 발광 스펙트럼의 세기가 증가하는 경향을 나타내었다. 파장 611 nm로 제어한 흡광 스펙트럼은 299 nm에 피크를 갖는 전하전달밴드 (CTB) 이었다 [그림 참조].

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THE CHROMOSPHERIC ACTIVITY ON V711 TAU (V711 TAU의 채층활동)

  • V771TAU의채층활동
    • Journal of Astronomy and Space Sciences
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    • v.14 no.1
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    • pp.59-66
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    • 1997
  • The relationship between Mg II emission line and light variation of V711 Tau has been derived to investigate the chromospheric activity on V711 Tau. First, a shape of an optical light curve was compared with that of ultraviolet constructed from the IUE low resolution spectra. Second, the intensities of Mg II k emission lines have been reduced from IUE high resolution spectra. The intensity of Mg II k line was compared with brightness of the UV light curve at given phase. The Mg II line intensity is maximum at the phase $O.^{P}4$ where the light is minimum. The evidence of chromosperic activity is indicated by the intensity variation of the MgII emission line with orbital phase for V711 Tau.

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Luminescence Properties of Europium-doped NaSr(PO3)3 Phosphor (Europium이 첨가된 NaSr(PO3)3형광체의 형광특성)

  • Yoon, Changyong;Park, Cheolwoo
    • Journal of the Korean Society of Radiology
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    • v.13 no.4
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    • pp.645-652
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    • 2019
  • Phosphor with phosphorus doped with rare earth ions was investigated by searching Sr and Eu phosphors suitable for substitution of Eu ions with similar ionic radius to polyphosphate host. The $NaSr(PO_3)_3$ phosphor was synthesized by the solid state method and the $NaSr(PO_3)_3:Eu^{2+}$ phosphor was prepared by the carbon thermal reduction method. Both of the phosphors were identified by X - ray diffraction. The excitation and emission spectra of $NaSr(PO_3)_3:Eu^{3+}$ increased fluorescence intensity and intensity quenching with increasing $Eu^{3+}$ concentration. The higher the $Eu^{3+}$ concentration in the emission spectrum, the higher the local symmetry of $Eu^{3+}$ environment. The mechanism of concentration quenching, in which fluorescence decreases due to the energy transfer between $Eu^{2+}$ ions with the closest critical distance between $Eu^{2+}$ ions with increasing $Eu^{2+}$ ion concentration, was confirmed in the emission spectrum of $NaSr(PO_3)_3:Eu^{2+}$ concentration. It is possible to change the fluorescent region through the post-processing of single rare earth ion added phosphors, and it is possible to change the fluorescence by applying the energy transfer and concentration quenching mechanism according to the local symmetry of $Eu^{3+}$ will be used for high phosphor development.