• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2012.05a
• /
• pp.268-268
• /
• 2012

합금도금강판의 일시 방청과 기능성 부여 후처리는 크로메이트, 인산염처리 등과 같은 방법을 시행하는 것이 일반적이다. 그러나, 최근에는 아연합금도금 강판의 사용 및 보관 환경이 가혹해짐에 따라 보다 우수한 일시 방청성과 내식성이 요구되고 있다. 본 연구는 tetraethoxysilane (TEOS), methacryloxypropyltrimethoxysilane (MPTMS) 무기성분과 multifuncitional trimethylolpanetriacrylate(TMPTA) 그리고 1,6-Hexanediol diacrylate(HDODA) 등의 유기성분을 갖는 유무기 하이브리드 솔젤(sol-gel)1)을 제작하여 각 조건에 대하여 표면 관찰 및 염수분무시험을 통한 내식성 평가를 진행하였다.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2021.05a
• /
• pp.63-64
• /
• 2021

The corrosion inhibition properties of conifer cone (Pinus resinosa) extract were studied in synthetic concrete pore solutions (SCPS) with and without chloride environments by electrochemical methods. The electrochemical impedance spectroscopy (EIS) revealed that the conifer cone (CC) extract showed promising inhibition behavior by diminishing the corrosion rate of steel rebar both solutions i.e. with and without chloride. The extract of conifer cone hinders the corrosion reaction between steel rebar and aggressive ions. Further, it can be verified that the up to 1000mg.L-1 of CC extract can able to reduce the corrosion rate of steel rebar in chloride contaminated concrete.

• 전기산업
• /
• v.10 no.3
• /
• pp.89-98
• /
• 1999

• Magazine of the Korea Concrete Institute
• /
• v.27 no.1
• /
• pp.41-44
• /
• 2015

• 수도
• /
• v.25 no.1 s.88
• /
• pp.55-59
• /
• 1998

• Magazine of the Korea Concrete Institute
• /
• v.11 no.2
• /
• pp.251-259
• /
• 1999

Recently, large scale concrete structures exposed to severe environments are increasingly built in various locations, The corrosion may severely affect the durability and service life of such a concrete structure. It is, therefore, necessary to develop a method to enhance the corrosion resistance of a concrete, The purpose of this paper is, therefore, to investigate the corrosion resistance and bond strength characteristics of anti-corrosive cement coated reinforcements. To this end, a comprehensive experimental study has been done to explore the corrosion and bond behavior of those coated reinforcements. The test results indicate that the anti-corrosive cement coated reinforcements do not exhibit any corrosion after corrosion tests and the bond strengths are very good as much as plain bar. It is seen that the anti-corrosive cement coated reinforcements can be efficiently used to enhance the durability of reinforced concrete structures.

• Journal of Korean Society of Steel Construction
• /
• v.19 no.1
• /
• pp.79-86
• /
• 2007

The corrosion durability of steel bridge coatings, such as organic and metallic coatings, is often evaluated by field exposure tests, but such tests take from several years to decades to complete. As a potential method for fast corrosion testing, accelerated exposure tests were considered in this study. The S6-cycle accelerated exposure test, specified in the Japanese Industrial Standards (JIS K5621), was carried out on uncoated structural steels for 30, 60, 90, 120 and 150 days, and the resultant weight loss was determined. The weight loss was compared with that obtained from previous field exposure tests, and acceleration factors of the S6-cycle test to field exposure test sites were determined. The application of the S6-cycle accelerated exposure tests to field environments was presented based on the acceleration factor and the amount of flying salt.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2018.06a
• /
• pp.44-44
• /
• 2018

칼라도장강판은 금속 제품의 제품화 공정 중에 도장 공정을 생략함으로 경제적이며, 제조공정 중 발생할 수 있는 VOCs(Volatile Organic Compounds)의 배출 염려가 없어 건축 및 가전 산업에 다용되고 있다. 칼라도장강판은 용융아연도금강판(GI), 전기아연도금강판(EGI), 용융알루미늄아연합금도금강판 등이 기재로 적용되고 있으며, 최근 마그네슘 성분이 첨가되는 고내식 도금강판 개발과 함께 고내식 도금강판을 이용한 칼라도장강판의 개발 및 수요 발굴을 위한 연구가 활발하게 진행 중에 있다. 칼라강판의 구성은 일반적으로 도막 밀착성 확보를 위한 화성처리층, 기재와 도막간의 밀착성과 내식성 개선을 위한 하도층(primer layer), 가공성, 내오염성, 의장성 등의 기능성 부여를 위한 상도층(top layer)의 구조로 도장되어 있다. 도료는 가공성, 내오염성, 경도 등의 기능성이 우수한 폴리에스테르 수지계가 가장 폭넓게 사용되고 경화제로는 멜라민 화합물과 이소시아네이트 화합물이 널리 사용되고 있다. 칼라도장 강판은 1970년대 이후 본격적으로 보급되어 사용되기 시작하였으며, 화성처리층은 밀착성과 내식성이 우수한 크로메이트처리가 널리 사용되고, 하도층은 방청성이 우수한 크로메이트계 방청 안료를 함유시킨 도료가 일반적이다. 그러나, 전기전자 제품에 적용되는 칼라도장강판은 2006년에 RoHS 규제의 시행과 더불어 6가 크롬 사용 제한의 영향으로 크롬프리 화성처리가 일반화되어 적용되고 있으며, 그 동안 6가 크롬 제안이 유보적이었던 건축용 칼라도장강판 또한 크롬프리 화성처리층 및 크로메이트계 방청 안료의 하도층 적용을 회피하고 있는 추세이다. 이에 따라, 고내식 합금도금강판을 기재로 사용하고 기존의 화성처리층과 하도층에 크롬프리 수지를 적용하는 연구개발이 활발하게 진행 중에 있다. 본 연구에서는 마그네슘이 첨가된 고내식 합금도금강판으로 Al-Mg-S i강판과 용융 Zn-Al-Mg 합금도금강판에 기존의 상용화 공정에서 사용되는 크롬계 및 크로프리 화성처리 적용 칼라도장강판에 대한 내식성 등 칼라도장강판의 특성에 대해 발표한다.

• Korean Chemical Engineering Research
• /
• v.49 no.6
• /
• pp.745-751
• /
• 2011

In this study, zinc or cerium exchanged zeolite was introduced to develop a novel anti-corrosion pigment. The primer paint was made using them and was coated on galvanized(GI) steel. The anti-corrosion performance was measured using electrochemical impedance spectroscopy(EIS). And scanning vibrating electrode technique(SVET) was employed to observe the cut-edge corrosion process of the coated GI steel. From EIS and SVET results, it could be confirmed that Ce ion-exchanged zeolite showed the anti-corrosion performance higher than Shieldex C303 and Zn ionexchanged zeolite. Finally, it was found that metal ion-exchanged zeolite may provide new possibility as the smart cathodic corrosion inhibitor delivery systems on galvanized steels.

• Journal of Bio-Environment Control
• /
• v.29 no.2
• /
• pp.196-201
• /
• 2020

In order to increase the durability of the pipe framed greenhouse, galvanized steel pipes with four corrosion protection treatments were installed in the greenhouse. After 20 years, experiments on surface corrosion and strength change were conducted. Control (untreated) pipes exposed in the atmosphere showed a 1.3% reduction in strength, but little difference from other treatments. The strength of heavy protective coating pipes buried in the ground decreased by 0.6%, showing little change, but untreated pipes decreased by 15.7%. And antirust paint and asphalt coating pipes decreased by 4.2~4.4%. Pipes exposed in the atmosphere did not show severe corrosion in all samples. There was no change in heavy protective coating pipes, and no rust was found in antirust painting pipes either and there was only slight discoloration. Asphalt coating pipes discolored black and some rust was found, and untreated pipes were rusted by 20~30% of the surface. However, untreated pipes buried in the ground were completely rusted, and asphalt coating pipes were rusted by 80~90% of the surface. Antirust painting pipes were rusted by 20~30%, and heavy protective coating pipes did not change almost. The heavy protective coating treatment showed a clear corrosion protection effect even in the parts buried in the ground, and the antirust painting treatment also showed some corrosion protection effect. Therefore, it is judged to be applicable to the field of pipe framed greenhouses.