• Journal of the Korean Wood Science and Technology
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• v.33 no.3 s.131
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• pp.53-63
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• 2005

This study attempted to obtain the basic data of utilizable possibility of preservative treated wood as a material used in a marine ranch. To evaluate the leaching stability of CCA-, CCFZ-, and ACQ-treated woods in seawater, the specimens treated with 2% and 3% (w/v) of CCA, CCFZ, and ACQ were exposed to deionized water, synthetic seawater and natural seawater for 41 days and then each component released was periodically determined. There was little amount of copper and chromium released from CCA-treated wood exposed in both deionized and seawater. Although relatively large amount of arsenic was released from CCA-treated wood, the release rate in seawater was lower than that in deionized water. The release rate of chromium and zinc from CCFZ-treated wood were somewhat greater in deionized water, but lower in seawater than in deionized water. Retention level and salinity of synthetic seawater had little effect on the release rate of components. The ACQ-treated wood had greater copper release than CCA- and CCFZ-treated wood, and the amount of copper released did not affected by leaching media used.

• Korean Journal of Soil Science and Fertilizer
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• v.43 no.1
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• pp.60-67
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• 2010

Although several studies have reported that Cr, Cu and As can leach from CCA-treated woods, few studies have been conducted on this topic in Korea. Therefore, this study was conducted to monitor Cr, Cu and As leaching from CCA-treated wood products and to develop a rapid identification method for CCA-treated wood products by using indicators such as PAN stain. Soil samples were collected at depths of 0-70 cm and wood samples were collected by thickness of wood layer. The soil and wood samples were then digested and analyzed for Cr, Cu and As concentrations using an atomic absorption spectrometer. The As and Cu concentrations decreased sharply with depth from 34.38 and 33.65 mg $kg^{-1}$ at 0-1 cm to 1.72 and 7.84 mg $kg^{-1}$ at 70 cm, respectively. In general, As was more mobile than Cr and Cu in the soil. For wood samples, the Cr, Cu and As concentrations were higher in the outer layer (0-0.5cm) than the inner layers (0.6-4.5cm). Evaluation of rapid identification methods revealed that 100% acetone with 0.1% PAN indicator was the best combination for detection of CCA-treated wood in the field.

• Journal of the Korean Wood Science and Technology
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• v.44 no.5
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• pp.743-749
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• 2016

The concentration control of wood preservatives is necessary to produce a preservative treated wood having a uniform quality. Concentration measurement method of wood preservatives to be easily used in the field has not been developed yet. This study examined the way to estimate the concentration from turbidity of ACQ wood preservative that can be relatively easily measured by using a portable turbidity meter. The addition of phosphoric acid solution in an alkaline ACQ solution having a very low turbidity is created a suspension of the white substance and the turbidity suddenly increased. The optimum amount of addition of the phosphoric acid solution is until the pH of ACQ solution reaches 7, the turbidity of the ACQ solution reaches maximum value. Excessive addition of the phosphoric acid solution results in a turbidity decrease with acidification of the ACQ solution. Also ACQ solution becomes transparent. The high significance was recognized with positive correlation between the concentration and the turbidity of the ACQ solution. From the t-test, The significant difference between the actually measured concentrations and the concentrations predicted by the regression equation for industrial ACQ solutions was not recognized. Thus, it was possible to know that concentration prediction and control of industrial ACQ solution using the turbidity and a regression equation. Therefore, using the regression equation and turbidity is expected to be able to management the concentration of ACQ solution in the industrial field.

• Journal of the Korean Wood Science and Technology
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• v.31 no.4
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• pp.44-49
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• 2003

This study was carried out to evaluate the weathering durability of waterborne preservative (AAC, ACQ, CCA, CuAz) treated Japanese red pine (Pinus densiflora S. et Z.) sapwood samples by accelerated weathering, and to find out the factor of stability. When considered the color changes, weight losses, surface degradation, and microstructure changes due to weathering, ACQ-, CCA-, and CuAz-treated samples were durable against weathering; the weathering durability of AAC-treated samples was poor and similar to untreated controls. The lignin content in aqueous extracts collected from ACQ-, CCA-, and CuAz-treated samples during weathering was lower than that from untreated and AAC-treated ones. From these findings, we might concluded that weathering durability of ACQ-, CCA-, and CuAz-treated samples was enhanced by the fixation of preservative component(s) onto the lignin structure, which is very susceptible to weathering.

• Journal of the Korean Wood Science and Technology
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• v.32 no.2
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• pp.1-8
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• 2004

Heavy metals were removed from CCA- and CCFZ- treated wood using a brown-rot fungi Tyromyces palustris. The amount of effective elements extracted from treated woods was compared for different treatment methods. The relationship between the amount of heavy metals removed and concentrations of oxalic acid for treated wood was examined. Also, the relationship between mycelia weight and removal rate was examined. The removed quantity of heavy metal from treated wood according to fermentation methods was examined. The extraction amount of chromium and arsenic components increased with increasing oxalic acid concentration, but the extraction amount of copper did not improved much. A 287 mg of mycelia weight can remove chromium and arsenic over 60% in 3 g CCA chips and copper was also removed over 50%. The chromium, copper and arsenic were removed over 60% by shaking fermentation, the removal rate of copper by static cultivation was higher than that of shaking fermentation. The removal rate of chromium, copper and arsenic were 72%, 61% and 59% with air-lift bioreactor, respectively.

• Korean Chemical Engineering Research
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• v.44 no.2
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• pp.227-233
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• 2006

Solvent extraction of pentachlorophenol (PCP) from wood chips of the PCP-treated ammunition box has been studied using methanol, ethanol and acetonitrile. Experimental variables were chosen as the composition of solvents, the ratio of solvent per dried wood, size of the substance, extraction temperature and sonication applied to the samples. The average concentration of PCP was 720 ppm and methanol was the most effective for PCP extraction. Above 99％ of PCP were removed from the sample (initial concentration of PCP; 1297 ppm) within 2 h at room temperature by methanol. The minimal ratio of methanol per dried wood chip(v/w) was 10. Type of substances(chip or sawdust), extraction temperature and sonication showed little effects on PCP extraction.

• Journal of the Korean Wood Science and Technology
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• v.43 no.6
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• pp.804-809
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• 2015

Since Korea is home to Reticulitermes speratus, a kind of subterranean termites that prefer dark and humid conditions, there have been increasing damages to wooden structures by termites. One noticeable attribute of Korean subterranean termites is that they prefer than Pinus densiflora, the major construction material for Korean traditional houses. And because wide varieties of termites are distributed all over the world, it is not so easy to choose appropriate control methods depending on specific areas. This necessitates careful applications of the following control methods depending on the kinds of termites: fumigation treatment, soil termiticide, preservatives and insect treatment, termite colony elimination system, chemical treatment, and other physical and biological treatment methods. The purpose of this study is to investigate the control effects of environmentally-friendly Alkaline copper quaternary (ACQ), Copper Azole (CuAZ) and Micronized copper quarter (MCQ) on the termites contributing to the damage of wooden structures. It was found in this study that wood with preservative treatment produced a significantly higher termicidal efficacy than untreated wood.

• Journal of the Korean Wood Science and Technology
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• v.10 no.3
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• pp.165-165
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• 1982

In order to improve decaying properties of the plywood, the effectiveness of the Malenit treatment on the shear strength and decaying properties of the plywood has been investigated. The results are as follows. 1. No decrease of the shear strength of the plywood has shown despite of plywood treatment with Malenit right after plywood made or veneer treated with the same preservative prior to plywood manu. factured. 2. The effectiveness of Malenit treatment on decaying property of the plywood has shown much greater than that of the untreated plywood and red pine sapwood. 3. Weight decreases of the test specimens due to the infection of the different fungi have seen in different ways. If fungi infected weight decreases of the specimens are different in it's degree due to the fungi.

• Journal of Korean Society of Forest Science
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• v.23 no.1
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• pp.48-50
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• 1974

• Proceedings of the Korean Institute of Landscape Architecture Conference
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• 2007.03a
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• pp.117-120
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• 2007