• Title/Summary/Keyword: 발화 특성

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Autoignition Characteristics of Limonene - Expanded Polystyrene Mixture (Limonene - Expanded Polystyrene 혼합물의 자연발화 특성)

  • 송영호;하동명;정국삼
    • Fire Science and Engineering
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    • v.18 no.1
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    • pp.1-6
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    • 2004
  • In the reutilization process using limonene, the organic solvent to reduce volume of EPS, the AIT was measured with the variation of concentration and volume of mixture, in order to present the fund-mental data on the fire hazard assessment of limonene - EPS mixture at storage and handling. And ignition zone was compared with non-ignition zone. The equation related to AIT, activation energy and ignition delay time, used by the most scientific basis for predicting AIT values, was suggested using linear regression analysis as ln t = 0.704/T-5.819. And the equation related to concentration of mixture and AIT was also suggested to predict ignition hazard of combustible mixture using nonlinear regression analysis as $T_m/=248.32+69.27X+172.60X^2$. It enabled to predict ignition temperature according to variation of ignition delay time and concentration of mixture by the suggested equations.

Measurement and Prediction of Autoignition Temperature (AIT) and Ignition Delay Time of n-Pentanol and p-Xylene Mixture (n-Pentanol p-Xylene 과 혼합물의 최소자연발화온도와 발화지연시간의 측정 및 예측)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.31 no.5
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    • pp.1-6
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    • 2017
  • The fire and explosion properties of combustible materials are necessary for the safe handling, storage, transportation and disposal. Typical combustion characteristics for process safety include auto ignition temperature(AIT). The AIT is an important index for the safe handling of combustible liquids. The AIT is the lowest temperature at which the material will spontaneously ignite. In this study, the AITs and ignition delay times of n-pentanol and p-xylene mixture were measured by using ASTM E659 apparatus. The AITs of n-pentanol and p-xylene which constituted binary system were $285^{\circ}C$ and $557^{\circ}C$, respectively. The experimental AITs and ignition delay times of n-pentanol and p-xylene mixture were a good agreement with the calculated AITs and ignition delay times by the proposed equations with a few A.A.D. (average absolute deviation). Therefore, it is possible to estimate the AITs and ignition delay times in other compositions of n-pentanol and p-xylene mixture by using the predictive equations which presented in this study.

A Study on the Reliability of the Combustible Properties for Acrylic Acid (아크릴릭산의 연소특성치의 신뢰성 연구)

  • Ha, Dong-Myeong
    • Journal of Energy Engineering
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    • v.24 no.3
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    • pp.20-26
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    • 2015
  • For the reliability of the combustible properties of arylic acid, this study was investigated the explosion limits of acrylic acid in the reference data. The flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. The lower flash points of acrylic acid by using Setaflash and Pensky-Martens closed-cup testers were experimented in $48^{\circ}C$ and $51^{\circ}C$, respectively. The lower flash points of arylic acid by using Tag and Cleveland open cup testers were experimented in $56^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for acrylic acid. The AIT of acrylic acid was experimented as $417^{\circ}C$. The lower explosion limit(LEL) and the upper explosion limit(UEL) by the measured the lower flash point and the upper flash point of acrylic acid were calculated as 2.2 Vol% and 7.9 Vol%, respectively.

A Study on Characteristics of Auto Ignition and Activation Energy of Ethylene Glycol and Diethylene Glycol (Ethylene Glycol과 Diethylene Glycol의 자연발화 특성과 활성화에너지에 관한 연구)

  • Kim, Jung-Hun;Choi, Jae-Wook
    • Journal of the Korean Institute of Gas
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    • v.20 no.2
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    • pp.16-22
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    • 2016
  • Auto ignition characteristic is an important factor for handling combustible substance and fire prevention. This research studied about auto ignition characteristic and activation energy of Ethylene Glycol (EG) and Diethylene Glycol (DEG) by using ASTM D2155 type ignition temperature measuring apparatus. As the auto ignition temperatures, it was possible to get $434^{\circ}C$ for EG within sample amount range of $75{\sim}160{\mu}l$ and $387^{\circ}C$ for DEG within sample amount range of $130{\sim}150{\mu}l$. Also, it was possible to get $579^{\circ}C$ and $569^{\circ}C$ as instantaneous ignition temperatures with sample amount of $140{\mu}l$ for EG and DEG respectively. By using least square method from Semenov equation on measured ignition temperature and ignition delay time from this study, it was possible to calculate activation energy of EG as 25.41 Kcal/mol and DEG as 14.07 Kcal/mol. Therefore, it was possible to claim that DEG has more risk of auto ignition since the auto ignition temperature, instantaneous ignition temperature and activation energy of DEG is lower than EG.

Production of English Vowels by Korean Learners (한국인 학습자의 영어 모음 발화 연구)

  • Lee, Kye-Youn;Cho, Mi-Hui
    • The Journal of the Korea Contents Association
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    • v.13 no.9
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    • pp.495-503
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    • 2013
  • The purpose of this study was to investigate how Korean speakers produce English vowels. Twenty one Korean learners produced the vowels [i, ɪ, eɪ, ɛ, æ, ɑ, ʌ, ɔ, oʊ, ʊ, u] in bVt or pVt forms of real words. Acoustic measurements were conducted for the vowel formant frequencies (F1, F2) and duration. Results showed that Korean learners tended to produce the vowel duration longer than native English speakers. Also, the front vowels produced by Korean participants tended to be produced at the more frontal part of the tongue. In addition, Korean participants distinguished the tense and lax pairs not through quality(F1, F2) but through vowel duration. This is different from the native English speakers in that they differentiate tense and lax pairs by quality(F1, F2) as well as vowel duration. Based on these results, pedagogical implications are discussed.

Ethylene 공정 안전을 위한 Ethylene Gas의 안전특성치 고찰

  • 하동명;이수경
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2003.10a
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    • pp.170-175
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    • 2003
  • 화학과 석유화학 산업의 많은 공정에서는 가연성가스가 공정 가스로 사용되거나 발생될 수도 있다. 최근 석유화학단지에서 화재 및 폭발이 빈번하게 발생되고 있으므로 이에 대한 재해를 예방하기 위해서는 공정 조건에서의 이들 가연성가스의 연소특성을 알 필요가 있다. 연소특성들로는 폭발한계, 인화점, 최소자연발화점, 최소산소농도, 최소발화에너지, 연소열 등을 들 수 있다.(중략)

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A Study on the Analysis of the Tube for Detecting Ignition Point (발화점 감지 튜브 특성분석에 관한 연구)

  • Choi, Young-Kwan;Yoon, Byeong-Don;Kim, Eung-Kwon;Shin, Myong-Chul
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2010.10a
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    • pp.341-344
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    • 2010
  • 발화점 감지 튜브 자동소화장치는 화재발생시 일정한 온도가 되면 튜브가 녹아 가스가 방출되면서 소화용기내의 소화약제가 방출되어 화재를 진압하는 장치로써 전력의 공급 없이도 화재의 감지 및 소화가 가능한 자동소화장치이다. 본 논문에서는 감지온도 $100^{\circ}C{\sim}110^{\circ}C$에서 열에 반응하여 가스방출이 가능한 첨단 폴리머 튜크 재질의 발화점감지 튜브를 개발하고자 기존 발화점 감지 튜브의 특성을 분석하였다.

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A Study on the Ignition Temperature and Ignition Induction Time According to Storage Amount of Wood Pellets (우드펠릿의 저장량에 따른 발화온도 및 발화유도시간에 관한 연구)

  • Kim, Hyeong-Seok;Choi, Yu-Jung;Kim, Jung-Hun;Jeong, Phil-Hoon;Choi, Jae-Woo
    • Fire Science and Engineering
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    • v.33 no.1
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    • pp.7-14
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    • 2019
  • While wood pellets are often used as a fuel in thermoelectric power plants and firewood boilers, there is a risk of ignition temperature when strong wood pellets, which have a high calorific value, for prolonged periods of time. In this research study, the minimum auto ignition temperature and the ignition limitation temperature according to the change in flow rate depending on the size of the test vessel were calculated, and based on these temperatures, the apparent activation energy was calculated to predict the combustive properties of the material. The apparent activation energy was calculated to be 190.224 kJ/mol. The thicker the sample is storage in the vessel, the longer the ignition induction time was due to the increased difficulty in heat being transferred from the surface of the vessel to the middle section area of the vessel. For vessel of the same size, the higher the flow rate, the lower the auto ignition temperature was. It was also confirmed that increases in the size of the test vessel lowered the auto ignition temperature and increased the ignition induction time.

Speech Rate and Pauses in the Speech of Migrant Women from Multicultural Families (다문화가정 이주여성의 발화속도와 쉼)

  • Hwang, Ji-Sung;Lee, Sook-Hyang
    • The Journal of the Acoustical Society of Korea
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    • v.31 no.2
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    • pp.63-72
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    • 2012
  • The purpose of this paper is to provide basic data for development of Korean teaching programs for immigrant women from multicultural families through the acoustic analysis of their speech rate and pauses. They showed slower speech rate, longer pause duration, and higher frequency of pauses compared to a Korean women's group. Philippine women, whose residence duration in Korea is relatively longer than that of Vietnamese women, were more similar to Korean women. The slower speech rate of the immigrant women seems to be due to their slower articulation rate and their reading habit of inserting a pause after almost every word in a sentence.