• Elastomers and Composites
• /
• v.41 no.3
• /
• pp.147-156
• /
• 2006

To investigate the influence of the foaming temperature and carbon black content on the cure behaviors and foaming characteristics of the foams. natural rubber (NR) was foamed at five temperature zones (145, 150, 155, 160 and $165^{\circ}C$) and different feeding ratios of the carbon black. A decreasing trend of the scorch time, $t_{s2}$ and cure time, $t_{90}$ was observed upon increasing foaming temperature and carbon black content. The optimal temperature for vulcanization and foaming of NRs in this study was considered to be $165^{\circ}C$ where density of the loomed NRs is lower than those at other four temperature regions. The rule rate index of the NRs foamed at $145^{\circ}C$ is smaller than those at 150, 155, 160 and $165^{\circ}C$. The results of the expansion ratio and micrographs of the foamed NRs were founded to support the density characteristics. The thickness of each of the struts formed inside the rubber matrix decreases with increasing the foaming temperature, while it increases with increasing the carbon black content.

• Polymer(Korea)
• /
• v.25 no.5
• /
• pp.679-690
• /
• 2001

High resilience PU foams were prepared with polyether type cell opener. The influences of cell opener concentration on the kinetics, rheology, structural stability morphology and open cell content of the obtained foam were investigated and the role of cell opener during cell opening was determined. And mechanical properties as a function of cell opener concentration were studied. It was observed that urea formation reaction was delayed due to high hydrophilicity of cell opener The decrease of viscosity and the increase of tan $\delta$ were confirmed with increasing cell opener concentration so that the resulted foam had low structural stability and high open cell content. The deterioration of matrix and uniform dispersion of hydrogen-bonded urea in matrix with cell opener concentration was revealed by SEM analysis. As a result, elastic properties of the foam matrix were decreased due to high hydrophilicity of cell opener during the preparation of high resilience polyurethane foam and foam with high open cell content resulted. Hardness, tensile strength, tear strength, elongation of foam were decreased with increasing cell opener concentration.

• Elastomers and Composites
• /
• v.35 no.2
• /
• pp.106-114
• /
• 2000

The foam of ethylene vinyl acetate (EVA)/styrene-vinyl isoprene-styrene triblock copolymer(SVIS) blend was prepared to improve the shock-absorption and compression set characteristics at room temperature. The effects of blowing agent and blend ratio of EVA/SVIS on expansion ratio, cell structure and mechanical properties of the foam were investigated. As the SVIS content increased, the viscosity of blends was increased but the crosslinking rate was slow down, the expansion ratio was decreased. and the specific gravity was increased. At room temperature, the resilience was not affected by increasing the amount of blowing agent. The value of tan ${\delta}$ was increased by increasing the amount of SVIS. As a result, the value of compression set was decreased. This is due to the increased values of specific gravity and crosslinking density of the EVA/SVIS foam.

• Elastomers and Composites
• /
• v.35 no.2
• /
• pp.138-148
• /
• 2000

In order to investigate the possibility of EPDM micro cellular pad (MCP) as an impact sound insulation product, we studied static/dynamic properties and vibration transfer characteristics of EPDM MCP depending on shape, thickness, degrees of foaming by using material test system (MTS) and lab scale mock-up test apparatus. Static/dynamic rigidity is increased when shape is simple. thickness and degrees of foaming low. We could see that dynamic stiffness is proportional to the transmissibility of EPDM MCP. When dynamic stiffness is increased, characteristic peak at transmissibility curve moves high frequency range or snows increase of maximum value of transmissibility. For lab scale mock-up test and finite element method, EPDM MCP shows low vibration velocity and superior mode shape to just concrete plus slab structure. We could confirm that possibility of EPDM MCP as a impact sound insulation product is high.

• Polymer(Korea)
• /
• v.28 no.5
• /
• pp.412-425
• /
• 2004

The influence of expandable graphite (EG) on flame retardancy and foaming properties of the NBR/GTR foams was studied. The foaming properties were similar to those of NBR/GTR foams without EG when the EG contents were 10$\~$30 phr. The LOI values were increased with the EG content. For cone-calorimeter test, the data showed the trend similar to that from experiment. When the composition ratios of the compounds of NBR/GTR were 100$\~$0/80$\~$20 (w/w), and the EG contents were 10$\~$30 phr, we obtained high flame retardancy foams with low heat release rate (HRR), total heat release (THR), effective heat of combustion (EHC) and carbon monoxide yield (COY). The smoke density is similar to CO yield values obtained by the cone-calorimeter test. TGA analysis also showed the results approximately similar to those from the LOI and cone-calorimeter experiments.

• Composites Research
• /
• v.26 no.6
• /
• pp.343-348
• /
• 2013

In the present study, quasi-static tests and impact tests were performed for investigating the mechanical behaviour of EPP (Expanded polypropylene) and EPS (Expanded polystyrene). Four different density cylindrical type specimens were prepared for EPP and EPS and 0.001 $s^{-1}$ and 0.1 $s^{-1}$ of strain rate conditions for quasi-static tests and 100 J, 200 J and 300 J of incident energy conditions for the instrumented impact tests were considered.

• Journal of the Korean Society for Precision Engineering
• /
• v.19 no.6
• /
• pp.136-144
• /
• 2002

Melting method has long been considered difficult to realize because of problems such as the low foamability of molten metal, the varying size of cellular structures and solidification shrinkage. The parameters to solve the problem in electric furnace were stirring temperature, stirring velocity, heating velocity and foaming temperature It is important to consider the effects of induction heating, because it brings about the inner flow by the temperature gradient. Aspect ratio also depends on the induction heating. Mechanical properties are dependent on cell sizes and aspect rations. Therefore, this paper presents the effects of these parameters on the cell sizes. For the sake of this, combined stirring process was used to fabricate aluminum foam materials by the above mentioned parameters. Image analysis was performed to calculate the cell sizes, distributions, and aspect ratioes at the cross section of feared aluminum in the direction of height.

• Composites Research
• /
• v.22 no.4
• /
• pp.27-32
• /
• 2009

Characterisation of the stress-strain relationship as well as crashworthiness of cellular polymer was investigated under constant impact energy with different velocities, considering inertia and strain rate effects simultaneously during the impact testing. Quasi-static and impact tests were carried out for two different density (64 $kg/m^3$, 89 $kg/m^3$) cellular polymer specimens. Also, the equations, coupled with the Sherwood-Frost model and the Impulse-Momentum theory, were employed to build the constitutive relation of the cellular polymer. The nominal stress-strain curves obtained from the constitutive relation were compared with results from impact tests and showed to be in good agreement.

• Proceedings of the Korean Institute of Industrial Safety Conference
• /
• 2000.06a
• /
• pp.124-129
• /
• 2000

산업현장의 건물, 설비 등의 보온 및 단열을 위해 우레탄폼, 스치로폼 등 다양한 종류의 프라스틱류 단열재를 사용하고 있다. 이들은 착화 및 연소속도가 빠르고 연소시 유독가스를 다량 발생시켜 심각한 재산 및 인명피해를 초래하고 있다. 그러나, 이들 발포플라스틱들은 연소하기 쉬운 재료로서 급속한 화염전파, 높은 열방출율, 많은 양의 연기발생 등 화재의 위험성이 상대적으로 높다는 문제점을 안고 있다. (중략)

• Elastomers and Composites
• /
• v.46 no.4
• /
• pp.343-351
• /
• 2011

We prepared polyurethane foam/cloisite30B/phosphates composites and characterized their rise time, density, cell morphology, and thermal properties. The composites were synthesized with polyadipatediol-cloisite30B composite (f=2.0), polyether-polyol (f=4.6), polymeric 4,4-diphenyl methane diisocyanate (f=2.5), and D-580 (phenyl polyoxyalkenyl phosphate). As a blowing agent, cyclopentane and distilled water were used at various concentrations of D-580 from 0 to 2.81 wt%. The rise times of PUF/Closite30B/Phosphate composites blown with distilled water were faster than those blown with cyclopentane by 30%. The composites blown with cyclopentane had spherical-shape cells and the cell diameter was decreased with increasing D-580 wt%. While $T_g$ of the composites blown with cyclopentane linearly decreased with increasing the D-580 content, the $T_g$ of the composites blown with distilled water increased with the D-580 content. All PUF/Closite30B/Phosphate composites began to decompose from $250^{\circ}C$. The composites blown with cyclopentane showed the second thermal decomposition at temperatures higher than $500^{\circ}C$. The thermal stability of all composites increased with the D-580 content. The effect of D-580 on the thermal stability of the composites was measured higher at the composites blown with distilled water.