• Journal of the KSME
• /
• v.24 no.4
• /
• pp.284-290
• /
• 1984

국내 쓰레기의 일인당 배출량은 외국보다 많은 2 kg/인. 일 정도이나, 주로 연탄재로 인한 것 이며, 발열량은 500 600 kcl/kg 으로 매우 낮아 보조연료가 필요한 수준이다. 따라서 소각로를 건설할 경우 이에 대한 발열량 증가를 위한 행정적인 조치 및 주민계몽의 노력을 기울여야 할 것이다. 국내의 쓰레기 처리방법은 거의 완전히 매립에 의존하고 있으나 외국의 경우는 소각, 매립 자원재활용, 퇴비화 등의 순으로 처리되고 있으므로 우리 나라도 이와 같은 추세를 따라야 할 것이며, 특히 자원재활용을 위한 "오레곤 병법"등과 같은 행정적인 조치는 우리 나라도 조속히 도입하여야 할 것이다. 소각로의 기술은 주로 유럽기술에 의해 지배되고 있으며, 최근 미국의 RDF 및 일본지역의 FBC 개발연구 등도 괄목할 만하다. 그러나 기본적으로, 유럽기술이라 할 지라도 국내 적용을 위해서는 기본적인 국내의 쓰레기 특성에 맞게 사양을 변경하여야 할 것이 므로 국내 실정에 맞는 소각로설계 연구를 추진해야 할 것이다. 특히 우리 나라는 외국보다 저발열량, 고수분 함량의 쓰레기이므로 이를 단순히 보조연료로만 처리하는 것보다 기술적으로 합리적인 보조연료 절감 방안을 강구하여야 할 것이다.하여야 할 것이다.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
• /
• 1993.11a
• /
• pp.88-91
• /
• 1993

유동층 반응기 (H=0.8 m, ID=0.08 m) 에서 폐타이어의 열분해를 수행함에 있어 열분해에 사용되는 열을 외부에서 공급함과 동시에 일부는 내부에서 자체적으로 연소시켜 열을 얻고자 하였다. 온도 증가에 따라 가스의 수율은 40 %까지 증가하였고, 반면에 오일의 수율은 감소하였다. 또한 가스중에 heavy hydrocarbon 이 감소함과 동시에 H$_2$ 및 light hydrocarbon 이 증가하였고 이로 인해 가스 부피당 발열량은 감소하는 것으로 나타났다. 가스의 체류시간도 가스조성에 상당히 영향을 미치는 것으로 나타났으며, 본 시스템에서 발열량 및 가스생성량은 2 u$_{mf}$ 에서 최소치를 나타내는 것으로 보였다. 또한 $O_2$ 농도의 증가는 결국에는 생성가스의 연소를 일으키며, 적당한 $O_2$ 농도의 설정으로 이의 연소를 최소화하는 작업이 필요하다.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
• /
• 1993.11a
• /
• pp.92-95
• /
• 1993

실험실 규모의 유동층 반응기(0.8 m H $\times$ 0.08 m I.D.) 에서 반응온도(700 -80$0^{\circ}C$), 유동화속도(1.5 - 3 Umf)의 영향에 따른 생성물의 수율, 생성가스의 조성, 생성가스의 발열량의 변화를 질소 분위기하에서 조사하였다. 반응온도를 700 에서 850 $^{\circ}C$로 증가시킬 때 촤의 수율은 36% 정도로 온도에 따라 큰 차이를 보이지 않은 반면 가스의 수율은 온도가 증가함에 따라 22 %에서 800 $^{\circ}C$까지 30%가량 증가하다 그 이상의 온도에서는 증가하지 않았다. 또한 수소와 메탄은 온도가 증가함에 따라 그 생성량이 증가하는 반면 에탄과 프로펜은 감소하였으며 단위 부피당 가스의 발열량은 감소하였다.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
• /
• 2013.11a
• /
• pp.221-222
• /
• 2013

다양한 첨가제가 들어가는 고분자 화합물(compound)의 제조에 있어 난연 발포 보조제인 팽창흑연(Expandable Graphite, EGP)은 흡유가가 낮기 때문에 비교적 많은 양을 첨가해도 혼합(Mixing)이 잘 되는 것으로 알려져 있다. 본 논문에서는 대표적인 인계 난연제 APP(Ammonium Polyphosphate)를 사용한 난연 EPDM(Ethylene Propylene Diene Monomer) 폼에 팽창흑연 첨가량을 증가시키면서 산소 지수와 발열량을 통해 난연 성능의 변화를 분석하였다. 산소지수는 ISO 4589-2 상온 산소지수 방법을, 발열량 평가는 ISO 5660-1 콘 칼로리미터를 활용하였다.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.17 no.1
• /
• pp.27-38
• /
• 2009

To investigate the feasibility of refuse derived fuels (RDFs) combined of sewage sludge and combustible wastes such as substitutive fuels instead of a stone coal, several different RDFs made with different mixtures of sewage sludge and combustible wastes were analyzed by various experiments. The combustion characteristics for the RDFs were investigated by analyzing fuel gases, and heating values were also measured by a bomb calorimeter. The fundamental properties such as moisture contents, ratios of combustible materials, amounts of ashes, heavy metals, ratios of each chemical elements and heating values were analyzed in accordance with mixing ratios of wt(%) for researching the characteristics of the RDFs. $RDF_{k-1}$ was made of mixing materials which were dried sewage sludge, food wastes and combustible wastes. $RDF_{k-2}$ was made of mixing materials which were peat-moss, tar and sewage sludge. Combustion experiments were carried out at the optimal conditions which were m=2 under air-fuel condition and $850^{\circ}C$. The retention times in the combustor were set at 5, 10 and 15minutes. 50 g of RDFs was put in the combustor for each experiments. The ranges for heating values of $RDF_{k-1}$ with different mixing ratios were from 6,900 kcal/kg to 8120 kcal/kg. The ranges for heating values of $RDF_{k-2}$ with different mixing ratios were from 4,014 kcal/kg to 8,050 kcal/kg. As a result of this study, the heating values, moisture contents, components of chemical elements and mixing ratios of the materials in RDFs had big effects on the efficiency of the combustion. In $RDF_{k-1}$, the higher amounts of combustible wastes in the mixtures, the higher heating values, concentrations of $C_xH_y$ and amounts of ashes were produced. In $RDF_{k-2}$, the higher tar amounts in the mixtures caused the higher heating values, amounts of ashes, concentrations of CO gas and CxHy.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2016.11a
• /
• pp.160-160
• /
• 2016

최근 indium tin oxide (ITO)의 높은 전기 전도도 및 광투과율을 이용하여 줄 발열을 기초하는 투명 면상 발열체에 대한 연구가 활발히 진행 되고 있다. 하지만 단일 ITO박막으로 제작한 투명 면상 발열체는 다양한 문제점들을 가지고 있다. 따라서 본 연구에서는 단일 ITO박막을 이용한 투명 면상 발열체의 단점을 보완하는 하이브리드 구조 투명 면상 발열체를 제작하여 금속 삽입층의 두께에 따른 전기전도도, 광투과율을 관찰 하였다. 그 결과 하이브리드 구조의 투명 면상발열체의 발열량, 온도 균일성등이 기존의 단일 ITO 박막의 투명 면상 발열체보다 효율이 크게 향상 된 것을 확일 할 수 있었다.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.12 no.10
• /
• pp.4679-4688
• /
• 2011

This study was performed to the municipal waste generation amounts and characteristics for B city in Gangwon province, predicted the methane gas generation rate emitted from landfill, and analyzed the possibility of energy recovery to RDF(Refuse Derived Fuel) using combustible waste. The study results showed that the average bulk density of municipal waste for B city was 144.0 kg/$m^3$, and the average ratios of combustible waste were 36.0 % of paper, 21.6 % of vinyl, and 19.7 % of food waste. respectively. In the experiment for heating value, high and low heating value(moisture) was measured to 3,471 $kca{\ell}$/kg and 2,941 $kca{\ell}$/kg, respectively. After the prohibition of burying of food waste in landfill, the heating value of municipal waste was dramatically increased due to increase of the ratio of paper, vinyl, and plastic waste. The prediction results of methane gas generation rate emitted from landfill showed that the gas generation rate is increasing to 2,505.7 CH4 ton/year in 2021. After then, the rate is decreasing gradually. When the RDF facility is installed, the rate is decreasing after peaking at 1,956.9 CH4 ton/year in 2013. The generation rate of LFG emitted from waste landfill of B city was analyzed to 9.92 $m^3$/min, similar to 10.11 $m^3$/min for other city.

• Tunnel and Underground Space
• /
• v.21 no.6
• /
• pp.518-525
• /
• 2011

In this study, the natural ventilation pressure resulting from the large altitude difference which is a characteristic of high radioactive waste repository and the caloric value of the heat emitted by wastes was calculated and based on the results, natural ventilation quantities were calculated. A high radioactive waste repository can be considered as being operated through closed cycle thermodynamic processes similar to those of thermal engines. The heat produced by the heating of high radioactive wastes in the underground repository is added to the surrounding air, and the air goes up through the upcast vertical shaft due to the added heat while working on its surroundings. Part of the heat added by the work done by the air can be temporarily changed into mechanical energy to promote the air flow. Therefore, if a sustained and powerful heat source exists in the repository, the heat source will naturally enable continued cyclic flows of air. Based on this assumption, the quantity of natural ventilation made during the disposal of high radioactive wastes in a deep geological layer was mathematically calculated and based on the results, natural ventilation pressure of $74{\sim}183$Pa made by the stack effect was identified along with the resultant natural ventilation quantity of $92.5{\sim}147.7m^3/s$. The result of an analysis by CFD was $82{\sim}143m^3/s$ which was very similar to the results obtained by the mathematical method.

• Journal of the Korea Construction Safety Engineering Association
• /
• s.54
• /
• pp.20-28
• /
• 2011

• Analytical Science and Technology
• /
• v.7 no.3
• /
• pp.329-338
• /
• 1994

The retention behaviors of natural gas components were studied on a single column by gas chromatography. The dead time, $t_0$ was obtained by using extrapolation of homologous series to determine capacity factors. The plots of retention data for homologous series and carbon number at different temperatures were shown to converge into a single point, which point was determined as a dead time. The results of the effect of temperature on the column efficiency for n-butane exhibited the plate number, N incerased with temperature, but the resolution among the fast eluted components decreased. The adsorption enthalpy (${\Delta}H^0{_{ads}}$) for each component on 28% DC 200 stationary phase was determined, and in order to investigate the retention behaviors of natural gas components the regression analysis of log $t_R$, log k' and log ${\alpha}$ vs. van der Waals volume(Vw), molecular connectivity index(X) and hydrophobic fragmental constant(f) were carred out. Good correlation was found between log k' vs. Vw, and log k' vs. f. The correlations between the physical properties of natural gas and the physical parameters were investigated by the linear regression analysis. The relationships between Vw vs. molecular weight and heating value(${\Delta}H_{comb}$), X vs. boiling point, and f vs. molecular weight, boiling point and heating value exhibited the high correlation coefficient more than 0.99. Using the regression equation between the heating value of natural gas and Vw the predicted heating values from $C_6$ to $C_{10}$ showed good agreement with those reported in the literature within 0.2% relative error.