• 제목/요약/키워드: 반 스톡스 라만 분광법

검색결과 12건 처리시간 0.028초

시분해 반스톡스 라만 분광 신호의 스톡스광과 펌프광의 상관관계에 대한 의존성 계산 (Dependence of the time resolved anti-Stokes Raman signal on the correlation between pump and Stokes waves)

  • 고춘수
    • 한국광학회지
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    • 제8권5호
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    • pp.372-376
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    • 1997
  • 시분해 반스톡스 라만 분광법에서 펌프광과 스톡스광의 상관관계에 대한 의존성을 계산하였다. 시간 지연된 두 펌프광을 라만 매질에 입사시키면 하나의 펌프광에 발생된 스톡스광과 펌프광들의 결합에 의해 반스톡스광 신호를 얻을 수 있는데 지연시간에 따른 반스톡스광 신호의 규격화된 크기를 계산하였다. 매질의 라만 선폭이 레이저의 선폭 보다 매우 작지 않을 때에는 스톡스광이 펌프광과 완전한 상관관계를 갖지 못하므로 일반적인 매질에서 발생된 스톡스광과 펌프광의 상관관계에 대해 간단한 모델을 세우고 그 매개변수에 따른 신호의 변화를 계산하였다. 일반적으로 비선형 라만 실험에서는 선폭이 넓은 광원을 사용하므로 파동들을 chaotic field로 기술하여 계산을 하였으며 여러 가지 매질의 선폭에 대해 그 결과들을 비교하였다.

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비공명펌프 사광자혼합 : 3차 비선형 레이저 분광법을 위한 새로운 위상정합법 (Nonresonant-Pump Four Wave Mixing : New Scheme of Phase Matching for Third Order Nonlinear Laser Spectroscopy)

  • 이은성;최대식;이재용;한재원
    • 한국광학회:학술대회논문집
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    • 한국광학회 2002년도 하계학술발표회
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    • pp.222-223
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    • 2002
  • 3차 비선형 광학현상을 이용한 레이저 분광학은 코헤런트 반스톡스 라만산란(Coherent Anti-Stokes Raman Scattering, CARS)이나 축퇴 사광자혼합(Degenerate Four-Wave Mixing, DFWM)이 기계공학의 연소진단이나 화학분야에 응용된 이래 활발히 연구되어져왔다.[1] 비선형 광학현상의 특성상, 발생한 신호는 입사 레이저광들과의 위상정합조건이 만족되는 특정한 방향으로만 진행하고 레이저광처럼 가간섭성을 갖는다. (중략)

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CARS 측정 기술을 이용한 스파크 점화 기관에서의 화염 전 화학 반응에 의한 온도 변화에 관한 연구 (A Study of the Temperature Elevation Due to the Pre-flame Reaction in a Spark-Ignition Engine Using CARS Technique)

  • 최인용;전광민;박철웅;한재원
    • 한국자동차공학회논문집
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    • 제9권5호
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    • pp.9-16
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    • 2001
  • End-gas temperatures were measured using CARS technique in a conventional DOHC spark- ignition engine fueled with PRF80. The measured pressure data were analyzed using band pass filter method. The measured CARS temperatures were compared with adiabatic core temperatures calculated from measured pressures. Significant heating by pre-flame reaction in the end gas zone was observed in the late part of compression stroke under both knocking and non-knocking conditions. CARS temperatures measured at 10 crank angle degree before knock occurrence was higher than adiabatic core temperatures. These results indicate that there exist some exothermic reactions in low pressure and temperature region. CARS temperatures began to be higher than the adiabatic core temperature when the end-gas temperatures reached look. The temperature elevation due to the pre-flame reaction correlated better with CARS temperature than with cylinder pressure.

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동축류 버너에서 생성된 부분 예혼합 화염을 이용한 화염 온도 측정 검정원 연구 (Study on the partially premixed flames produced by a coflow burner as temperature calibration source)

  • 박철웅;한재원;신현동
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2000년도 제21회 KOSCO SYMPOSIUM 논문집
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    • pp.160-167
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    • 2000
  • We investigated a uniform temperature zone, produced by double flame structure of a coflow CH4/air partially premixed flame, to be used as a temperature calibration source for laser diagnostics. A broadband N2 CARS(coherent anti-Stokes Raman spectroscopy) system with a modeless laser was used for temperature measurement. When the stoichiometric ratio was 1.5, we found the uniform temperature zone in radial direction of the flame of which the averaged temperature was 2110 K with standard deviation 24 K. In the stoichiometric ratio range between 2.0 and 2.5, we found very stable temperature-varying zones in vertical direction at the center of the flame. The size of the zone was approximately 15 mm and it covered a temperature range from 300 K to 1900 K. We also suggest that this zone can be used as a calibration source for 2-D PLIF(planar laser induced flurescence) temperature measurement.

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CARS를 이용한 DOHC 스파크 점화 기관의 말단 가스 온도 측정 (End-Gas Temperature Measurments in a DOHC Spark-Ignition Engine Using CARS)

  • 최인용;전광민;박철웅;한재원
    • 한국자동차공학회논문집
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    • 제7권7호
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    • pp.122-128
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    • 1999
  • CARS(Coherent anti-Stokes Raman Spectroscopy) temperature measurement under engine-like condition was validated by measuring unburned gas temperatures of premixed propane-air flame in a constant volume combustion chamber. The measured temperatures were compared with predictions of 2 zone flame propagation model. End-gas temperatures were measured were measured by CARS technique in a conventional 4 cylinder DOHC spark-ignition engine fueled with PRF 80. Cylinder pressure was measured simultaneously with CARS signal and used as a parameter on fitting CARS spectrum to library of theoretical spectra. There was a good agreement between the measured temperature and adiabatic core temperature calculated from measured cylinder pressure. Significant heating by pre-flame reaction in the gas was observed in the late part of compression stroke.

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레이저유도 형광법을 이용한 화염내 OH 농도분포 계측 (Hydroxyl Radical Measurements in the Flame Using LIF)

  • 이병준;길용석;정석호
    • 대한기계학회논문집B
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    • 제20권2호
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    • pp.710-719
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    • 1996
  • Laser applied combustion diagnostic techniques-laser induced fluorescence (LIF) and coherent anti-Stokes Ramann spectroscopy (CARS)-are demonstrated. The profiles of hydroxyl radical (OH) and temperature in the counterflow burner are measured and compared with the numerical results. OH radical is excited on the Q$_1$(6) line of the $A^2$$\sum^+$$\leftarrow$$X^2{\prod}$(1, 0) band transition (281.1 nm) and LIF signal is measured at the the bands of (0, 0) and (1, 1) transition (306~326 nm). Absolute OH radical is obtained by using the laser absorption technique. The quenching effects are considered. Temperature is measured using broadband CARS system. Two dimensional OH radical profile is also obtained. The profiles of OH radical and temperature are found to agree well with those of numerical calculation.

층류 확산화염에서의 매연과 질소산화물의 배출특성 : 공기측/연료측 희석제 첨가에 따른 영향 (Soot and NOx Emissions in Laminar Diffusion Flames: Effects of Air-Side versus Fuel-Side Diluent Addition)

  • 이종호;엄재호;박철웅;전충환;장영준
    • 대한기계학회논문집B
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    • 제27권5호
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    • pp.596-603
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    • 2003
  • Present study has been conducted to see the relative effects of adding N: to fuel-side and air-side on flame structure, soot formation and NOx emissions. Experiments were carried out to ascertain to what degree chemical kinetics and/or molecular transport effects can explain the differences in soot formation and NOx emission by studying laminar diffusion flames. Direct photograph was taken to see the flame structure. CARS techniques was used to get the flame temperature profiles. And spatial distribution of soot could be obtained by PLII method. CHEMKIN code was also used to estimate the global residence time to predict NOx emissions at each condition. Results from these studies indicate that fuel-side dilution is more effective than air-side dilution in view of NOx emissions. However, air-side dilution shows greater effectiveness over fuel-side dilution in soot formation. And turbulent mixing and heat transfer problems were thought to be considered in practical applications.

층류 예혼합 화염의 예열공기 연소특성 (Characteristics of Preheated Air Combustion in a Laminar Premixed Flame)

  • 이종호;이승영;한재원;장영준;전충환
    • 대한기계학회논문집B
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    • 제26권7호
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    • pp.1039-1046
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    • 2002
  • Co-flow axisymmetric laminar premixed flame of methane was used to study the influence of air temperature and $N_2$ addition on the flame structure, temperature field and emission characteristics. OH 2-D images and temperatures along the centerline were measured experimentally by PLIF and CARS techniques respectively to observe the influences of dilution and thermal effects of $N_2$ in the gas mixture. Also, the concentration of NOx was measured at each condition by gas analyser to see the suppression effect of N2 addition on NOx emissions. It was found that OH concentrations distribute widely as air temperature goes higher, while the effect of $N_2$ addition is not significant. But $N_2$ addition highly contributes to the flame front and NOx emissions which was argued to be due to the reduction of flame temperature. In accordance with experimental study, numerical simulation using CHEMKlN code was carried out to compare the temperature results with those acquired by CARS measurement, and we could find that there is good agreement between those results.

CARS를 이용한 희박 예혼합 가스터빈 연소기내 온도 측정 (I) -연료/공기 혼합정도가 위상별 온도에 미치는 영향- (Phase-Resolved CARS Temperature Measurement in a Lean Premixed Gas Turbine Combustor (I) -Effect of Equivalence Ratio on Phase-Resolved Gas Temperature-)

  • 이종호;전충환;박철웅;한재원;장영준
    • 대한기계학회논문집B
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    • 제28권10호
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    • pp.1184-1192
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    • 2004
  • Experimental investigations were carried out in an atmospheric pressure, optically accessible and laboratory-scale dump combustor operating on methane gas. The objective of this study was to obtain the phase-resolved gas temperatures at different phases of the oscillating pressure cycle during unstable combustion. CARS temperature measurements were made at several spatial locations under lean premixed conditions to get the information on temperature field within the combustor. Also the effect of incomplete fuel-air mixing on phase-resolved temperature fluctuation was investigated. Results including phase-resolved averaged temperature, normalized standard deviation and temperature probability distribution functions (PDFs) were provided in this paper. Temperature PDFs gave an insight on the flame behavior. And strong correlation between phase-resolved temperature profile and pressure cycle was observed. Results of the phase-resolved high temperature gave an additional information on the perturbation of equivalence ratio at flame as well as the effect of mixing quality on NOx emission characteristics.

동축류 버너에서 생성된 부분 예혼합 화염을 이용한 화염 온도 측정 검정원 연구 (Study on the Partially Premixed Flames Produced by a Coflow Burner as Temperature Calibration Source)

  • 박철웅;한재원;신현동
    • 한국연소학회지
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    • 제5권1호
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    • pp.91-98
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    • 2000
  • We investigated a uniform temperature zone, produced by double flame structure of a co flow CH4/air partially premixed flame, to be used as a temperature calibration source for laser diagnostics. A broadband N2 CARS(coherent anti-Stokes Raman spectroscopy) system with a modeless laser was used for temperature measurement. When the stoichiometric ratio was 1.5, we found the uniform temperature zone in radial direction of the flame of which the averaged temperature was 2110 K with standard deviation 24 K. In the stoichiometric ratio range between 2.0 and 2.5, we found very stable temperature-varying zones in vertical direction at the center of the flame. The size of the zone was approximately 15 mm and it covered a temperature range from 300 K to 1900 K. We also suggest that this zone can be used as a calibration source for 2-D PLIF(planar laser induced flurescence) temperature measurement.

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