• Applied Chemistry for Engineering
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• v.28 no.3
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• pp.286-289
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• 2017

Synthesis of zeolite 4A was carried out to optimize the nanoparticle synthesis process using statistical experimental design method. The zeolite 4A was synthesized by controlling the concentration of the silicon precursor, sodium metasilicate (SMS), and characterized by XRD, SEM and nitrogen adsorption. In particular, the property of zeolite 4A can be determined by XRD analysis. Using the general factor analysis in the design of experiments, we analyzed main effects and interactions according to the reactor, reaction temperature and reaction time. The optimum reaction condition for the synthesis of zeolite 4A crystallinity was using an autoclave for 3 hours at $110^{\circ}C$. Furthermore, the optimal synthesis conditions of zeolite 4A with various crystallinity using Ludox as a silicon precursor were presented of what using both the surface and contour plot.

• Journal of the Korea institute for structural maintenance and inspection
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• v.17 no.6
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• pp.130-137
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• 2013

This research was performed through the experimental design to get the statistical analysis on foamed concrete mixed plaster with hydrogen peroxide. In this experiment, we set the ratio of each material, which part of lightweight concrete, as experimental factors and evaluated on the mechanical properties by statistical analysis for response variables obtained from experiments. Experimental factors are plaster replacement, water binder ratio, and hydrogen peroxide ratio. Response variables are dry density, compressive strength, and flexural strength. Mixing design of the foamed concrete set up a total of 15 experimental points by Box-Behnken (BB) method of the response surface analysis. Thus, the results of a study were summarized as follows. Values of the probability in experimental factors (plaster replacement, water binder ratio and hydrogen peroxide ratio) on the response variables were estimated to be significant at the 95% of confidence limit. On response surface analysis for dry density of foamed concrete, water binder ratio and hydrogen peroxide ratio were estimated to be significant (${\alpha}$ = 0.05), and the relationship between the amount of void and the water content for dry density is inverse proportional. On response surface analysis for the compressive strength of foamed concrete, water binder ratio, hydrogen peroxide ratio and (hydrogen peroxide ratio)$^2$ was estimated to be significant (${\alpha}$ = 0.05). On response surface analysis for the flexural strength of foamed concrete, water binder ratio, hydrogen peroxide ratio was estimated to be significant (${\alpha}$ = 0.05). Through multi response surface analysis, we found the optimal area that meets performance goals.

• Clean Technology
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• v.23 no.4
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• pp.413-420
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• 2017

The batch experiments and response surface methodology (RSM) have been applied to the investigation of the Cs adsorption with zeolite X synthesized using coal fly ash generated from the thermal power plant. Regression equation formulated for Cs adsorption was represented as a function of response variables. The model was highly relevant because the decision coefficient ($r^2$) was 0.9630. It was confirmed from the statistical results that the removal efficiency of Cs was affected by the order of experimental factors as pH > Cs concentration > temperature. The adsorption kinetics were more accurately represented by a pseudo second-order model. The maximum adsorption capacity calculated from the Langmuir isotherm model was $151.52mg\;g^{-1}$ at 293 K. Also, according to the thermodynamic parameters calculated from Vant Hoff equation, it could be confirmed that the adsorption reaction was an endothermic reaction and a spontaneous process.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.35 no.6
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• pp.696-701
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• 2002

Optimal conditions for preparing of chitooligosaccharides from chitosan with cellulase was researched by response surface methodo-logy, Penicillium funiculosum derived cellulase was most effective for chitooligosaccharides production as the point of hydrolyzing activity and commercial utility. The result which measures the change of degrading ratio at time course, 10 hr reaction showed a exponential increase and after that time degrading ratio was not changed. The optimal conditions determined by response surface methodology with central composite design of total 26 species were $0.5\%$ of chitosan, 143 U enzyme, 49$^{\circ}C$ of reaction temperature, 13.2 hr of reaction time and pH 3.8. Major chitooligosaccharides produced from chitiosan on optimal conditions were dimer and trimer.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2017.05a
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• pp.146-146
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• 2017

산화비스무트는 리튬이온과의 반응에서 현재 상용화된 그래파이트보다 높은 이론용량을 가지고 있으나, 리튬이온과의 반응에서 비교적 큰 부피팽창 특성을 가져 리튬이차전지의 음극재로서 상용화가 어려운 단점이 있다. 본 연구에서는, 이러한 문제점을 개선하기 위하여 양극산화법을 통해 충 방전시 부피팽창 변화가 매우 적은 타이타니아 나노튜브를 제조한 후, 그 위에 스프레이 방법으로 산화비스무트를 코팅하여 두 물질의 복함체를 만듦으로써 용량과 구조적 안정성을 향상시키는 방법을 소개한다. 음극재의 구조적 특성은 고분해능 주사전자현미경 (HR-SEM), 고분해능 엑스선 회절분석기(XRD)를 통해 조사하였으며, 전기화학 임피던스 분광법 (EIS), 순환전류법 (CV), 충 방전 싸이클 분석을 통해 리튬이차전지의 작동원리와 보다 향상된 성능을 규명하였다.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2011.04a
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• pp.689-692
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• 2011

본 논문에서는 해양작업 상태의 하중조건을 고려한 부유식 원유생산 저장 하역 장치에 설치된 라이져 보강구조의 강도설계에 관련하여 다양한 근사화 기법 기반 설계 최적화 및 그 성능을 비교하고자 한다. 설계 최적화 문제는 하중조건별 구조강도의 제한조건 하에서 중량을 최소화하여 설계변수인 구조 부재치수가 결정되도록 정식화 된다. 비교 연구를 위해 사용된 근사화 기법은 반응표면법 기반 순차적 근사최적화(RBSAO), 크리깅 기반 순차적 근사최적화(KBSAO), 그리고 개선된 이동최소자승법(MLSM) 기반 근사최적화 기법인 CF-MLSM와 Post-MLSM이다. 본 연구에 적용한 MLSM 기반 근사최적화 기법들은 제한조건의 가용성을 보장할 수 있도록 새롭게 개발되었다. 다양한 근사화 모델 기반 설계 최적화 기법에 의한 결과는 설계 해의 개선 및 수렴속도 등의 수치적 성능을 기준으로 실제 비근사 설계최적화 결과와 비교검토 하였다.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.32 no.7
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• pp.13-18
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• 2004

This paper describes an efficient and robust optimization method for helicopter rotor airfoil design in forward flight. Navier-Stokes analysis was employed to compute the dynamic response of an airfoil, which simulates the unsteady rotor flow-field in forward flight. The optimization system consists of two categories; Response Surface Method to construct the response surface model based on D-optimal 3-level factorial design, and Genetic Algorithm to obtain the optimum solution of a defined objective function including penalty terms of constraints. The influence of design variables and their interactions on the aerodynamic performance was examined through the optimization process.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2009.05a
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• pp.154-154
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• 2009

경질 3가 크롬 도금액은 내적인 구성 조성물의 화학비나, 외적인 온도, 시간 등 여러 가지 실험인자들의 복잡한 작용으로 인해 어떤 인자가 어떠한 작용에 상호 영향을 미치는지 파악하기가 쉽지 않다. 통계 프로그램을 사용하여 실험계획법을 작성하고, 측정된 반응치료로부터 분석을 실시하여 최적경사경로를 도출하였다. 또한, 잔차분석과 호감도 함수를 이용한 최적화가 진행되었다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2007.11a
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• pp.83-84
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• 2007

Damascene 공정을 이용하여 80nm급의 trench 패턴 내에 구리 배선 형성을 위해 무전해 구리 도금법을 이용하였다. 화학 반응으로 진행되는 무전해 도금법에 의한 구리이온의 초미세 패턴 내 환원 과정에 구리 이온의 물질 전달과정이 구리 도금층의 표면 특성과 superconformality에 미치는 영향을 살펴보았다. 회전 전극에 고정된 칩의 회전 속도가 증가함에 따라 구리 도금층의 비저항이 감소하고, trench 내 균일 도금성이 향상되는 것으로 나타났다.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.35 no.4
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• pp.401-407
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• 2011

The conventional method of magnetic abrasive polishing is not suitable for non-magnetic materials because such polishing is basically possible when magnetic force exists and the magnetic force in non-magnetic materials is very low. The installation of an electromagnet under the working area of a non-magnetic material, which is called second-generation magnetic abrasive polishing in this study, can enhance the magnetic force. Experimental evaluation and optimization of process parameters for polishing magnesium alloy steel was performed by adopting the design of experiments and the response surface method. The results indicated that the intensity of the magnetic force and spindle speed are significant parameters that affect the improvement of surface roughness. A prediction model for the surface roughness of the magnesium alloy steel is developed using the second-order response surface method.