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Study on the reaction crystallization of silver chloride in Rushton type semi-batch reactor (Rushton type 반회분식 반응기에서 염화은 반응성 결정화에 관한 연구)

  • 이종석;김우식
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.4
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    • pp.609-619
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    • 1996
  • Experimental study on effects of factors on the reaction crystallization of silver chloride in rushton type reactor. The size and size distributions of the silver chloride crystals were observed to be markedly affected by the agitation speed of solution, and feeding rate, feeding mode and concentration of reactants. From experimental data it was inferred that in the reaction crystallization of silver chloride the supersaturation level of silver chloride and concentration of excess ions in the solution, and mass transfer rate around the crystals were implicitly interrelated with factors and directly affected on the crystal nucleation and grwoth processes. However, the morphology of the silver chloride crystal was not changed by factors.

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Characteristics of the Bioreactors of Hydrogen-producing Immobilized Cells (II) -Overall Effectiveness Factor in Continuous Reactors- (수소생산 고정화 생물 반응기의 특성(II) -연속 반응기에서의 총괄 효율인자 -)

  • 이명재;선용호;한정우;조영일
    • Microbiology and Biotechnology Letters
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    • v.16 no.6
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    • pp.510-516
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    • 1988
  • The effects of input substrate concentration and dilution rate on mass transfer resistance in the operation of immobilized cell reactors were investigated using Rhodospirillum rubrum KS-301 immobilized by Ca alginate as reactor element and glucose as growth-limiting substrate. The kinetic parameters were obtained to estimate effectiveness factors. In the packed-bed reactor, internal mass transfer resistance was predominating although external resistance could not be neglected. The overall effectiveness factor was decreased with increase of dilution rate. In the continuous stirred-tank reactor, external resistance was nearly neglected and the overall effectiveness factor was not affected by dilution rate. In this experiment the overall effectiveness factors in PBR and CSTR were estimated to be 0.70 and 0.71 at D$_{i}$ = 0.2/h, R = 0.15 cm, and S$_{i}$ : 1.0g/L, respectively.

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Photochemical Reaction Simulation of Toluene/NOx Mixture Using the Morpho Model (Morpho를 이용한 톨루엔/NOx 광화학 반응 실험결과의 해석)

  • 이영미;이승복;배귀남;문길주
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.455-456
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    • 2003
  • 광화학 스모그 현상을 재현하기 위한 메카니즘은 약 20,000개의 반응식과 수천개의 종이 포함되어야 하므로 자세한 반응 메카니즘을 포함하는 데는 한계가 있다(Dodge, 2000). 최근에 morphecule이라 부르는 대리종(surrogates)을 사용하는 방법(morphecule approach)이 개발되었다. 이 메카니즘은 반응 속도, 생성율, 생성물의 형태를 포함하여 lumped surrogates와 관련된 인자들이 모사하는 전체 시간 중 각 t시간 동안 일정하고 그 시간이후에는 인자들이 변화한다고 가정한다. 또한 특성이 비슷한 유기 화합물의 다양한 그룹을 표현할 때 morphecule이라 부르는 특정 화학종들을 사용한다. (중략)

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Factor Analysis of USLE about Bongdong station in the Mankyoung river basin - Focused on Rainfall Erosivity(R) - (만경강 봉동 수위관측소 유역에 대한 USLE 인자특성 분석 - 강우침식인자를 중심으로 -)

  • Lee, Jae-Hyug;Shim, Eun-Jeung;Lee, Yeon-Kil;Kim, Tae-Woong
    • Proceedings of the Korea Water Resources Association Conference
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    • 2012.05a
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    • pp.511-511
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    • 2012
  • 강우침식인자는 강우사상(rainfall event)으로 인한 토양침식량을 산정하는 지표(index)로서 일정기간 토양침식의 정도를 산정할 수 있는 범용토양유식공식(Universal Soil Loss Equation)을 구성하고 있는 인자 중 가장 값의 변동성이 크고 동일한 조건에서 토양유실량 산정에 큰 영향을 미치는 인자다. 강우침식인자의 산정은 유량탐사 센서나 강우게이지 자료(pluviograph)로부터 12.7mm이상, 최소 15분간 6.35mm이상의 호우사상을 추출하여 해당하는 호우사상에 대한 강우에너지식에 30분 최대강우강도를 곱한 값의 연평균값을 계산한 것이다(Wischmeier and Smith, 1978). 본 연구에서는 범용토양유실공식(USLE)의 강우침식인 자(R)를 산정하고 지리정보시스템(GIS)을 활용하여 공간적 분포를 나타낼 수 있는 만경강 유역 상류부에 위치한 봉동 수위관측소 유역의 토양침식도를 연도별로 도시하였으며, 2001~2010년까지의 10개년 강우량을 바탕으로 토양침삭량을 산정하였다. 그 결과는 강우량이 많을수록 침식인자가 크게 산정되는 일반적인 결과를 기대 할 수 있지만, 2001~2010년까지 10개년 강우침식인자를 분석한 결과 강우량이 많다하여 침식인자의 변화 값이 크게 반응하는 값보다 강우강도에 의해 침식인자가 크게 반응하는 결과를 보였다. 따라서 강우침식인자는 강우량보다는 강우강도에 좌우됨을 알 수 있었다.

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Study on the Characteristics of Response Correction Factor of Ionization Chamber in RW3 Solid Phantom for High Energy X-rays (RW3 고체팬텀에서 고에너지 X-선에 대한 전리함 반응보정인자의 특성에 관한 연구)

  • Lee, Jeong-Ok;Jeong, Dong-Hyeok;Kim, Bu-Gil
    • Journal of radiological science and technology
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    • v.32 no.2
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    • pp.205-212
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    • 2009
  • The response correction factor ( h) is a factor to convert the response of the chamber in solid phantom to the response in water. In RW3 solid phantom, the dependency of beam quality and depth for high energy X-rays are known characteristics, however the dependency of field size, SSD, and chamber type are unknown. In this work we have studied the unknown characteristics on the dependency of response correction factor. The farmer type chamber (FC65G) and small chamber (CC13) were used and two beam qualities of 6 and 15 MV were evaluated. The measured response correction factors at the depth of 5 cm and 10 cm were h = 1.015 and 1.021 for 6 MV X-rays, and h = 1.024 and 1.029 for 15 MV X-rays. In conclusion the response correction factor did not depend on the field size and SSD while depending on the beam quality and depth. In the chambers, there are small differences between the two chambers used in this study but we think additional study for more chambers should be required. The results in this study can be used for analyzing the measured values from ionization chamber dosimetry in RW3.

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조력 T세포 인자에 의한 면역반응의 억제

  • 이종길
    • The Microorganisms and Industry
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    • v.16 no.3
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    • pp.20-25
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    • 1990
  • 면역계에는 조력T세포(helper T cell)와는 반대로 면역반응을 억제적으로 조절하는 것이 주 기능인 억제성 T세포(suppressor T cell)가 존배한다는 것이 아려져 있다. 이 억제성 T세포가 존재한다는 개념이 면역학및 임상의학에 준 영향은 매우 지대하여, 앨러지나 자가 면역질환 같은 질병은 억제성 T세포의 결핍으로, 그리고 면역 결핍증같은 질병은 T세포가 지나치게 활성화된 것으로 설명되기에 이르렀다. 한마디로 거의 모든 저하된 면역반응은 억제성 T세포와 연관하여 설명되었다. 그러나 억제성 T세포가 발견된지 근 20년이 되고 그에 관한 논문이 5000여편에 달하는 최근까지도 억제성 T세포 및 이들 세포가 만드는 억제성 T세포 인자에 대한 실체는 정확히 규명되지 못하고 있다. 오히려 억제성 T세포가 조력 T세포처럼 별개의 세포군으로 존재한다는 것을 부인하는 학자도 최근 나오게 되었다.(이 분야의 연구에서 나타난 문제점들이 정리되어 있음). 그러나 억제성 T세포의 존재를 부인하는 학자들도 T세포가 면역 반응의 억제에 관여한다는 사실, 적어도 그 현상 자체를 부인하지는 않았다. 다시말하면, 면역반응이 T세포에 의하여 억제되는 현상은 이미 수 천년의 논문을 통하여 입증되고 있다. 면역반응의 억제에 있어서 억제성 T세포및 억제성 T세포 인자의 역할은 앞으로의 연구를 통해 명확히 규명될 것이며, 정말 억제성 T세포가 있느냐 없느냐 하는 것은 이 총설의 주제가 아니다. 다만 여기서는 조력 T세포도 경우에 따라서는 면역반응의 억제에 관여한다는 최근의 연구결과를 간단히 소개하고자 한다.

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Determination of Optimized Operational Parameters for Photocatalytic Oxidation Reactors Using Factorial Design (요인분석법을 이용한 광촉매 산화반응조의 최적 운영인자 도출)

  • Hur, Joon-Moo;Cheon, Seung-Yul;Rhee, In-Hyoung;Kim, Jong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.23 no.2
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    • pp.85-91
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    • 2004
  • The objective of this study is to determine the optimum conditions of operational parameters using factorial design for phenol degradation in photocatalytic oxidation reactors. Factorial design is widely used to select the dominant factors and their ranges in experiments involving several factors where it is necessary to study the effect of factors on a response. The effects of initial concentration of phenol, intensity of UV light and surface area of catalyst on phenol degradation were investigated. Two levels were considered in this study so that the experiment was a $2^3$ factorial design with three replicates. The experimental results show that an increase in initial concentration of phenol from 5 to 50 mg/L intensity of UV light from 5,000 to $20,000\;{\mu}W/cm^2$, and surface area of catalyst from 740 to $2,105\;cm^2$ enhanced the phenol degradation rate by an average of 1.86, 1.79, and 2.10 mg/L hr, respectively. Interaction effects do not appear to be as large on the phenol degradation rate as the main effects of single factors. The optimum working condition for photocatalytic oxidation reactors, despite the higher three factors the better removal rate, is the highest surface area or catalyst.

Development of Bioreactors for Hydrogen-Producing Immobilized Photosynthetic Bacteria(II) : Evaluation of Immobilized Bioreactor for Hydrogen Productivity and Mass Transfer Resistance (광합성 박테리아를 이용한 고성능 수소 생산 고정화 생물반응기의 개발(II) :고정층 반응기와 연속 교반탱크 반응기에서의 수소 생산성 및 물질전달 저항 비교)

  • 선용호;한정우
    • KSBB Journal
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    • v.8 no.3
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    • pp.256-265
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    • 1993
  • In this study, it was observed that hydrogen productivity varied with changes of input g1ucose concentration and dilution rate in FBR( Fixed Bed Reactor), and CSTR(Continuous Stirred Tank Reactor). We evaluated and compared reaction rate Parameters and internal external and overall mass transfer resistances of immobilized carrier in both reactors. Apparent $K_m$ decreased with increasing dilution rate in FBR but showed a constant value above $0.4h^{-1}$ of dilution rate in CSTR. The experimental results in FBR showed nearly analogous to those in CSTR, however, the performance of FBR resulted in lower hydrogen productivity and an external effectiveness factor but a higher internal effectiveness factor than in CSTR. The overall effectiveness factor obtained with various input 91ucose concentrations showed similar values in both reactors.

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A Review of Geochemical Factors Governing the Phase Transformation of Birnessite (버네사이트 상변화 반응의 지화학적 반응 조절인자 연구)

  • Namgung, Seonyi;Chon, Chul-Min;Lee, Giehyeon
    • Economic and Environmental Geology
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    • v.50 no.6
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    • pp.545-554
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    • 2017
  • Birnessite is one of the dominant Mn (oxyhydr)oxide phases commonly found in soil and deep ocean environments. It typically occurs as nano-sized and poorly crystalline aggregates in the natural environment. It is well known that birnessite participates in a wide variety of bio/geochemical reactions as a reactive mineral phase with structural defects, cation vacancies, and mixed valences of structural Mn. These various bio/geochemical reactions control not only the fate and transport of inorganic and organic substances in the environment, but also the formation of diverse Mn (oxyhydr)oxides through birnessite transformation. This review assessed and discussed about the phase transformation of birnessite under a wide range of environmental conditions and about the potential geochemical factors controlling the corresponding reactions in the literature. Birnessite transformation to other types of Mn (oxyhydr)oxides were affected by dissolved Mn(II), dissolved oxygen, solution pH, and co-existing cation (i.e., $Mg^{2+}$). However, there still have been many issues to be unraveled on the complex bio/geochemical processes involved in the phase transformation of birnessite. Future work on the detail mechanisms of birnessite transformation should be further investigated.