• Title/Summary/Keyword: 반응성 상호작용

Search Result 660, Processing Time 0.028 seconds

Work Implementation and Analysis for Playful Communication of Netart (넷아트의 유희적 소통을 위한 작품분석 및 구현)

  • Kim, Byeung-Won;Kim, Jong-Seo;Kwak, Hoon-Sung
    • The Journal of the Korea Contents Association
    • /
    • v.8 no.12
    • /
    • pp.81-90
    • /
    • 2008
  • The development of digital technologies has changed the paradigm of an information-oriented society. Accordingly, the media-art and the net-art using digital media have been developed more interactively. Under the this influence, various experimental works using digital media are being produced and having a try to combination of art and digital on the network. In this paper, we looked into the relation between characteristics and playful of the net-art and analized the relation among interactive, network characteristics and intuitive play implemented on the net-art. Based upon these analyses, we intend to offer new aesthetic experiences through playful expression for humorous emotion on a traditional character, Dokkaebi.

Bond Orbital Theory of Chemical Reactivity (反應性의 結合 Orbital 理論)

  • Yang, Kang;Ree, Tai-Kyue
    • Journal of the Korean Chemical Society
    • /
    • v.8 no.1
    • /
    • pp.20-24
    • /
    • 1964
  • The linear combination of bond orbitals method is used to investigate the reactivity of halomethanes in abstraction reactions by atoms. The activation energy is evaluated on the assumption that, in an activated complex, two electrons in a bond to be broken become completely isolated from the rest of the ${\sigma}$-electron systems. Such a model leads to an intuitively attractive concept that the interactions between the reactive bond and the neighboring bonds govern the reactivity of ${\sigma}$-electron systems. The resulting equation for the activation energy, ${\varepsilon},\;is:\;{\narepsilon}= ${\varepsilon}={\zeta}+$$${\sum}_{i=1}^3$${\eta}c-I,$ c-4 Here, subscript C-4 indicates the bond to be broken, while C-i represents the other three bonds surrounding the reactive bond; ξ is the activation energy of a hypothetical reaction of an isolated C-4 bond and an attacking atom; and ${\eta}$C-i,C-4 stems from the stabilizing interacting of C-4 bond with neighboring C-i bonds. A choie of η′s consistent with bond strength data simplifies the above equation to a form ${\varepsilon}={\zeta}\;+\;N{\eta}c$-H, C-4 where N denotes the number of C-H plus C-F bond in halomethanes. In agreement with this equation, experimental -values increase linearly with increasing N.

  • PDF

A Study on Macroeconomic Linkages between the USA and Japan (미일간 거시경제적 연계성에 대한 연구)

  • Lee, Jai Ki
    • International Area Studies Review
    • /
    • v.15 no.3
    • /
    • pp.175-188
    • /
    • 2011
  • This study aims to examine how the U.S. economic shocks affect the Japanese economy. It is widely believed that the U.S. economy has a significant effect on the Japanese economy. Actually, the U.S. accounts for a considerable amount of Japan's exports and imports. To the economic policymakers, it is very important to know how economic disturbances generated by the U.S. are transmitted to the Japanese economy. A vector autoregression(VAR) model is employed to investigate the international transmission channel of economic disturbances. The interactions of the U.S.-Japansese economy are investigated by using variance decompositions(VDCs). The results of this study provided the evidence that the U.S. economic shocks were important for the Japanese economy during the sample period. This study supports the notion of economic dependence of smaller open economy such as Japan as compared with larger economy such as the U.S.

Vibration-to-Vibration Energy Transfer Between HF and DF in the Mixture (HF와 DF 혼합계내에서의 상호간 진동-진동 에너지 이동)

  • Chang Soon Lee;Yoo Hang Kim
    • Journal of the Korean Chemical Society
    • /
    • v.28 no.1
    • /
    • pp.26-33
    • /
    • 1984
  • The rate constants for the following vibration-to-vibration energy exchange reactions have been calculated theoretically for the temperature range from 300 to 800K and for n = 2 to 5. HF(v=n) + DF(v=0) ${\to}$ HF(v=n-l) + DF(v=l) + ${\Delta}E$(a) DF(v=n) + HF(v=0) ${\to}$ DF(v=n-l) + HF(v=l) + ${\Delta}E$(b) In calculation the loosely-held, non-rigid dimer collision model and semiclassical method have been employed. The results show that the rate constants for the processes (a) are much greater than those for the processes (b). Also, it is found that the rate constants for the processes (a) increase with decreasing temperature and with increasing quantum number, while those for the processes (b) show the opposite tendencies. These findings are explained in terms of the sign and magnitude of the energy mismatch, ${\Delta}E$.

  • PDF

Cesium Adsorption Properties of Activated Carbon with Oxygen Functional Groups Introduced by Ozonation Treatment (오존 처리에 의해 산소 작용기가 도입된 활성탄소의 세슘 흡착 특성)

  • Eunseon Chae;Chung Gi Min;Chaehun Lim;Young-Seak Lee
    • Applied Chemistry for Engineering
    • /
    • v.35 no.1
    • /
    • pp.23-28
    • /
    • 2024
  • Cesium is a potential toxic contaminant due to its high solubility, which allows it to easily penetrate the human body and potentially induce cancer or DNA mutations. In this study, oxygen functional groups were introduced on activated carbons (ACs) by ozone treatment to enhance the cesium adsorption capacity. As the ozone treatment time increased, the oxygen content on the ACs surface increased. Subsequently, the electrostatic interaction between ACs and cesium enhanced, resulting in higher cesium ion adsorption efficiency across all samples. In particular, the sample treated with ozone for 7 minutes at an internal ozone concentration of 50000 ppm had roughly 12% greater oxygen functional group content and the highest cesium removal effectiveness (97.6%). Meanwhile, samples treated for 5 minutes showed a 0.3% cesium removal rate difference compared to those treated for 7 minutes, which was caused by the surface chemical similarity of the two samples due to the reactive characteristics of ozone gas. However, the cesium adsorption performance of ozonated activated carbon seems to be mainly influenced by the amount of oxygen functional groups introduced to the surface, although the specific surface area and pore structure of the activated carbon are also important.

MT response on the two dimensional anisotropic structure (2차원 이방성 구조의 MT 반응)

  • Lee, Chun Gi;Gwon, Byeong Du
    • Journal of the Korean Geophysical Society
    • /
    • v.2 no.2
    • /
    • pp.123-134
    • /
    • 1999
  • Magnetotelluric responses may be affected by strong anisotropy of the high-conductivity layers (HCL) in the upper mantle or lower crust. We have studied two-dimensional anisotropy MT modelling to examine the effect of high anisotropic media. Electrical properties of a homogeneous anisotropic body are defined by a symmetric conductivity tensor and the problem is described by coupled diffusion equation in the frequency domain. In two-dimensional anisotropic environments, diagonal elements of the impedance tensor have higher values than those in isotropic environments. In some cases, TM mode phases reach more than 90°and apparent resistivities decrease for some frequency range because of telluric distortion. GB decomposition may be used to recover regional responses, but can be affected by the regional anisotropic effect. Considering these results, BC87 dataset was interpreted with a modified anisotropic model.

  • PDF

Base Drag Characteristics with Exothermic Bleed/Jet (발열성 유출류와 제트를 고려한 기저부 저항 특성)

  • Shin J.R.;Choi J.Y.;Kim C.K.
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • 2006.05a
    • /
    • pp.327-330
    • /
    • 2006
  • Numerical simulations were carried out to investigate the base drag characteristics of a base bleed projectile with a central propulsive jet by considering the base homing process. Overall fluid dynamic process is modeled by Wavier-Stokes equations for reacting flows with two-equation $k-\omega$ SST turbulence closure. The combustion process is modeled by finite-rate chemistry with a given partially burned exit condition of the BBU (base-bleed unit). Besides the demonstrating the capability of the present CFD solver for the base drag and the interaction of the base flow with a rocket plume, present study gives an insight into the fluid dynamics and the combustion process of the hybrid-propulsion projectile.

  • PDF

Analysis for Steady-State and Transient Combustion Characteristic of Solid Propellant Rocket Engine (고체 추진제 로켓엔진의 정상 및 비정상 연소특성 해석)

  • 김후중;김용모;윤명원
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • 2003.05a
    • /
    • pp.233-239
    • /
    • 2003
  • The present study has numerically investigated the combustion processes in the solid propellant rocket engine. The two step global reaction model for condensed phase and five step global reaction mechanism for gas phase are adopted to predict the detailed flame structure near double-base solid propellant surface. The turbulence-chemistry interaction is represented by the PaSR(Partially Stirred Reactor) model. To reduce the uncertainties for convective heat transfer near solid fuel surface having strong blowing effect, the Low Reynolds number k-$\varepsilon$ turbulent model is employed. Based on numerical results, the detailed discussion has been made for the turbulent combustion processes and transient behavior of pressure and temperature fields in the solid propellant rocket engine.

  • PDF

Uber die Einfluss der Adduktbildungs-Substanz in der Bildung des Cyclodextrin mit Enzymlosung (Cyclodextrine의 효소적 생성에 미치는 Addukt 형성물질의 영향)

  • 이길상
    • YAKHAK HOEJI
    • /
    • v.6 no.1
    • /
    • pp.35-41
    • /
    • 1962
  • 전분액은 Bac. macerans로 분해시킬때 Cyclodextrin이 형성되는 것은 Schardinger Freudenberg등에 발견된 사실이었으나 아직도 그 정확한 생성량에 대한 정량적인 조사는 되어있지 않으므로 저자는 본 연구를 통하여 .alpha.-, .betha.-, .gamma.-dextrin의 정량법을 paper-chromatography법으로 확립시켰다. 또한 이때 각분자와 주분자의 포위화합물의 현미경사진에 의한 결정형성모양과 동시에 그 모액중에 있는 Cyclodextrin의 함량등으로 cyclodextrin의 포위성을 증명하는 실험과 이러한 사실에 기인하여, Enzyme액으로 cyclodextrin이 생성되어 나올때 그 생성률의 변화를 조사한 결과를 cyclohexan을 첨가해 줄때 그 생성률이 가장 양호해지는 것을 보았다. 또한 본 연구를 통하여 .alpha.-Dextrin을 Enzyme과 공동작용시키면 .betha.-Dextrin이 형성되어 지는데, 각분자의 첨가로 그 .betha.-Dextrin의 생성량이 증가해지며 이때 Glucose를 가해주면 그 반응이 촉진되어 여기에 하나의 척매적인 작용을 하는 것으로 본다. 이것은 전분이 효소로써 분해될때 직쇄의 Dextrin이 생긴 다음 이것이 glucosyl기 전이반응의 반복으로써 Cyclodextrin이 형성되는 것을 입증하는 것인데 Glucosyl 기의 공여체로써 Glucose및 Maltose를 사용하였을때 이와같은 사실이 촉진되는 것을 볼 수 있다. 그러나 이와 같은 촉매적 역할에도 불구하고 .betha.-Dextrin을 Enzym과 공동작용시켜도 .alpha.-Dextrin이 형성되지 않는 것을 보아 .alpha.-Dextrin과 .betha.-Dextrin의 상호변화에 대해서 우리는 .alpha.-Dextrin에서 .betha.-Dextrin으로는 변화할수 있으나 .betha.-Dextrin으로 부터 .alpha.-Dextrin으로는 변화가 진행되지 않는 것으로 본다. 전반적으로 본 연구를 통하여 전분액을 Bac. macerans로 분해시킬때 시간의 경과를 따라 생성되어지는 Cyclodextrin의 함량의 변화를 추적하여 4시간전후에서 최고량이 되는 것을 볼 수 있으며 동시에 포위화합물을 형성시킬수 있을때는 그 생성률이 큰 영향을 이르킬수 있는 것을 지적할 수 있다.

  • PDF

The Impact of Brightness, Polarity, and Hue Difference on Legibility and Emotional Effect of Word in Visual Display (시각디스플레이에서 단어와 배경간의 밝기, 대비부호, 색상차이에 따른 가독성 및 감성효과)

  • Jung, Hye-Heon;Cho, Kyung-Ja;Han, Kwang-Hee
    • Korean Journal of Cognitive Science
    • /
    • v.17 no.4
    • /
    • pp.337-356
    • /
    • 2006
  • This research was conducted to see the impact of brightness, polarity, and hue diference on legibility and emotional effcts of the word. In the experiment 1, stimuli with three levels of brightness difference and two-typed polarity were used. The results showed that legibility, aesthetics, and preference increased with increasing brightness difference. In the experiment 2, the same stimuli if experiment 1 included four hues: red, green, blue, yellow. As a result, the effects of brightness and polarity and the interaction effect of brightness and polarity on legibility were significant. Also, the effects of brightness, polarity, and hue and the interaction effect of brightness and hue on aesthetics and preference were significant. These results showed that legibility, aesthetics, and preference increased with increasing brightness difference of word and background and positive polarity was better than negative. Aesthetics and preference rating increased according to the following order: red, blue, green, yellow. In addition, the interaction effect of brightness and polarity on legibility was because reaction time of negative polarity was longer than positive at the small brightness difference condition. The interaction effect of brightness and hue on aesthetics and preference ws because the aesthetics rating of hue at the large brightness difference condition had significant difference compared with small brightness difference. In the experiment 3, participants rated text designs and simple color stimuli with 18 emotional adjectives to see the similarity of their emotion. The conclusion was that to reflect the subjective feelings of a rotor on the text design, it would be appropriate to use the rotor on background of the text design.

  • PDF