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ZnO 나노 입자가 분산 된 Resin을 이용한 굴절률 조절 및 광 산란 패턴 형성을 통한 비정질 실리콘 박막태양전지의 효율 향상

  • Ko, Bit-Na;Kim, Jae-Hyeon;Kim, Gyu-Tae;Sin, Ju-Hyeon;Jeong, Pil-Hun;Chu, So-Yeong;Choe, Hak-Jong;Hyeon, Seok;Lee, Heon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.295-295
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    • 2014
  • 일반적으로 박막 태양전지의 효율은 박막 종류에 따른 광 흡수율에 의해 결정되며, 이는 증착한 박막의 두께에 의해 결정된다. 증착한 박막의 두께가 두꺼워질수록 광 흡수율은 증가하지만, 박막 두께가 지나치게 두꺼워지면 열화 현상으로 인한 모듈의 효율 감소가 생기므로 적절한 박막의 두께가 요구된다. 특히 a-Si:H의 경우 가시광 영역에서 높은 흡수계수를 가지고 있어서 얇은 박막 두께로도 태양전지의 제작이 가능하지만, 동일한 박막 두께에서 효율을 더욱 향상시키기 위한 다양한 광 포획 기술에 대한 연구가 많이 진행 되고 있다. 본 연구에서는 자외선을 이용한 nano-imprint lithography 기술을 이용하여 a-Si:H 태양전지의 유리기판 위에 pattern을 삽입하여 광 산란 효과를 향상 시키고자 하였다. 또한 유리기판의 굴절률 (n=1.5)과 투명전극의 굴절률 (n=1.9)의 중간 값을 갖는 ZnO nanoparticles (n=1.7)이 분산 된 imprinting resin을 사용함으로써 점진적으로 굴절률을 변화시켜, 최종적으로 a-Si:H 층까지의 광 투과율을 높이고자 하였다. 제작한 기판의 종류는 다음과 같다. 첫 번째 기판으로는 유리기판 위에 ZnO nanoparticles이 분산 된 imprinting resin을 spin-coating 하여 점진적인 굴절률의 변화에 의한 투과도 향상을 확인하고자 하였다. 두 번째 기판으로는 규칙적인 배열을 갖는 micro 크기의 패턴을 형성하였다. 마지막으로는 불규칙한 배열을 갖는 nano 크기와 micro 크기가 혼재 된 패턴을 형성하여 투과도 향상과 동시에 빛의 산란을 증가시키고자 하였다. 후에 이 세가지 종류를 기판으로 사용하여 a-Si:H 기반의 박막 태양전지를 제작하였다. 먼저 제작한 박막 태양전지용 기판의 광학적 전기적 특성을 분석하였다. 유리 기판 위에 형성한 패턴에 의한 roughness 변화를 확인하기 위해 atomic force microscopy (AFM)를 이용하여 시편의 표면을 측정하였다. 또한 제작한 유리 기판 위에 투명 전극층을 형성 후, 이로 인한 전기적 특성의 변화를 확인하기 위해 hall measurement system을 이용하여 sheet resistance, carrier mobility, carrier concentration 등의 특성을 측정하였다. 또한, UV-visible photospectrometer 장비를 이용하여 각 공정마다 시편의 광학적 특성(투과도, 반사도, 산란도, 흡수도 등)을 측정하였고, 최종적으로 제작한 박막 태양전지의 I-V 특성과 외부양자효율을 측정하여 태양전지의 효율 변화를 확인하였다. 그 결과 일반적인 유리에 기판에 제작된 a-Si:H 기반의 박막 태양전지에 비해, ZnO nanoparticles이 분산 된 imprinting resin을 spin-coating 하여 점진적인 굴절률 변화를 준 것만으로도 약 12%의 태양전지 효율이 증가하였다. 또한, micro 크기의 패턴과 nano-micro 크기가 혼재된 패턴을 형성한 경우 일반적인 유리를 사용한 경우에 비해 각각 27%, 36%까지 효율이 증가함을 확인하였다.

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Vegetation Cover Type Mapping Over The Korean Peninsula Using Multitemporal AVHRR Data (시계열(時系列) AVHRR 위성자료(衛星資料)를 이용한 한반도 식생분포(植生分布) 구분(區分))

  • Lee, Kyu-Sung
    • Journal of Korean Society of Forest Science
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    • v.83 no.4
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    • pp.441-449
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    • 1994
  • The two reflective channels(red and near infrared spectrum) of advanced very high resolution radiometer(AVHRR) data were used to classify primary vegetation cover types in the Korean Peninsula. From the NOAA-11 satellite data archive of 1991, 27 daytime scenes of relatively minimum cloud coverage were obtained. After the initial radiometric calibration, normalized difference vegetation index(NDVI) was calculated for each of the 27 data sets. Four or five daily NDVI data were then overlaid for each of the six months starting from February to November and the maximum value of NDVI was retained for every pixel location to make a monthly composite. The six bands of monthly NDVI composite were nearly cloud free and used for the computer classification of vegetation cover. Based on the temporal signatures of different vegetation cover types, which were generated by an unsupervised block clustering algorithm, every pixel was classified into one of the six cover type categories. The classification result was evaluated by both qualitative interpretation and quantitative comparison with existing forest statistics. Considering frequent data acquisition, low data cost and volume, and large area coverage, it is believed that AVHRR data are effective for vegetation cover type mapping at regional scale.

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An Analytical Study on Generation of Pore-Water Pressures Induced by Flow and Waves in Seabed, and Resulting Liquefaction (흐름과 파에 의한 해저지반내 간극수압의 발생과 액상화에 관한 해석적인 연구)

  • Lee, Kwang-Ho;Kim, Dong-Wook;Kim, Do-Sam;Bae, Ki-Seong;Jeon, Jong-Hyeok
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.27 no.5
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    • pp.324-338
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    • 2015
  • Analytical solutions for interaction between seabed and waves such as progressive wave or partial standing wave with arbitrary reflection ratio or standing wave have been developed by many researchers including Lee et al.(2014; 2015a; 2015b; 2015c; 2015d) and Yamamoto et al.(1978). They handled the pore-water pressure as oscillating pore-water pressure and residual pore-water pressure separately and discussed the seabed response on each pore-water pressure. However, based on field observations and laboratory experiments, the oscillating and residual pore-water pressures in the seabed do occur not separately but together at the same time. Therefore, the pore-water pressure should be investigated from a total pore-water pressure point of view. Thus, in this paper, the wave-induced seabed response including liquefaction depth was discussed among oscillating, residual, and total pore-water pressures' point of view according to the variation of wave, seabed, and flow conditions. From the results, in the field of flow with the same direction of progressive wave, the following seabed response has been identified; with increase of flow velocity, the dimensionless oscillating pore-water pressure increases, but the dimensionless residual pore-water pressure decreases, and consequently the dimensionless total pore-water pressure and the dimensionless liquefaction depth decrease.

Effects of Isoflurane/Remifentanil and Isoflurane/Fentanyl Anesthesia in Beagle Dogs (비글견에서 아이소플루란/레미펜타닐 및 아이소플루란/펜타닐 조합의 마취 효과)

  • Park, Jiyoung;Oh, Seung-June;Lee, Hae-Beom;Jeong, Seong Mok
    • Journal of Veterinary Clinics
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    • v.32 no.2
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    • pp.148-153
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    • 2015
  • This study was performed to compare two opioid drugs with isoflurane and to determine the difference between isoflurane/remifentanil anesthesia and isoflurane/fentanyl anesthesia in terms of the anesthetic effects in beagle dogs. Isoflurane was maintained at 0.5 MAC, and the opioid drug was administered as a constant rate infusion. The anesthesia was maintained for 2 hours, and isoflurane and opioid drugs were discontinued 2 hours later. After discontinuing the anesthetics, the extremity movement time, eye global positioning time, gag reflex time, head up time, sternal recumbency time, standing time, walking time and complete recovery times were recorded for each dog. Both of the studied anesthetic protocols were suitable in beagle dogs because the anesthetic status was well maintained until the end of the procedure, and rapid recovery times were demonstrated in this experiment. And this study shows that the isoflurane/remifentanil group was more reliable than the isoflurane/fentanyl group because the recovery time CV was lower. Therefore, isoflurane/remifentanil combination anesthesia could be a better choice than isoflurane/fentanyl anesthesia if the patient is severely ill and stable recovery time is needed.

The Comparison of Effectiveness in Prehospital Protocol Education on CardioPulmonary Resuscitation (심폐소생술에 대한 현장업무 프로토콜 교육 효과 비교)

  • Shin, Sang-Yol;Jung, Ji-Yeon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.11
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    • pp.3418-3426
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    • 2009
  • The purpose of this study was to investigate the feasibility of field operation protocol for cardiopulmonary resuscitation(CPR) in person with non-traumatic arrest. This study was performed from May 1 through June 27, 2008, and subjects were 150 students who are attending the department of Emergency Medical Service in J and K universities which located in Jeollabuk-do and Jeollanam-do areas. Practical conformance was verified using by nonequivalent control group pretest-posttest design. This study divided into two groups; experimental group that employed field operation protocol and control group that applied conventional CPR protocol, and comparative analyzed statistically the necessary time of the items of each protocol. The results indicated that each performance time of 18 items was reduced over 3 seconds except 5 items(assessment of consciousness, airway control, two times of artificial respiration, check of circulation, and five cycles of CPR). And time of 6 items(intubation, peripheral intravenous line, reassessment of consciousness, pupil reaction, carotid artery pulse, and vital sign) was minimized more than 60 seconds, and total performing time was shortened 110.85 seconds. The results suggested that total performing time in pre and post test where the protocol was applied for two groups showed a statistically significant decrease(t=-6.580, p=.000). Consequently, field operation protocol for cardiopulmonary resuscitation(CPR) in person with non-traumatic arrest will be a available manual which support prompt and accurate decision making, and improve emergency medical service.

A Comparative Study on Dynamic Behavior of Soil Containers that Have Different Side Boundary Conditions (측면 경계 조건이 다른 토조들의 동적거동 비교에 관한 연구)

  • Kim, Jin-Man;Ryu, Jeong-Ho;Son, Su-Won;Na, Ho-Young;Son, Jeong-Woong
    • Journal of the Korean Geotechnical Society
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    • v.27 no.12
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    • pp.107-116
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    • 2011
  • Rigid soil containers (or rigid boxes) are often used for 1g shaking table tests. The rigid boxes, however, do not accurately simulate the amplification of ground acceleration and phase difference of seismic motion in the model ground due to the confinement of shear deformation and the reflection of seismic wave at the box walls. Laminar soil containers (or laminar shear boxes) can simulate the free field motion at convincingly superior accuracy than the rigid ones. In this study, the soft ground is modeled for both types of boxes and is subjected to seismic loading using a 1g shaking table. The comparison of the results using the two types of soil containers illustrates that, in case of the rigid box, the ground acceleration shows non uniform distribution and the phase synchronization of input motion. Whereas, the dynamic behavior of the laminar shear box shows good agreement with the free field behaviors such as the amplification of ground acceleration and the occurrence of phase difference.

Effect Evaluation by Activity and Geometry Difference in Calibration on LSC (LSC 장비를 이용한 교정시 Activity 및 Geometry 차이에 의한 영향 평가)

  • Han, Sang-Jun;Lee, Kyung-Jin;Lee, Seung-Jin;Kim, Hee-Gang;Park, Eung-Seop
    • Journal of Radiation Protection and Research
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    • v.33 no.1
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    • pp.21-26
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    • 2008
  • When the calibration on Liquid Scintillation Counter using the Solid $^3H$ Standard Source of 200,000DPM is executed, the uncertainty due to activity and geometry difference, exists. Therefore, this paper intends to evaluate environmental samples comparatively accurately as decreasing this uncertainty existing in the process of calibration. For this, measurements on samples manufactured by $^3H$ Standard Source and sensitivity study were performed. Also, this paper verified calibration results using Radioactivity-Error-Analysis Method, and evaluated quantitatively the effect by geometry and activity difference based on verification result. According to the result of sensitivity study, in case of using the exposure time of 75 sec and Repeat method, the measuring accuracy and precision of about $1{\sim}3%$ were increased in comparison with the existing method. By analysis result, the effect by activity difference did not appear, and a plastic cell existing into Teflon vial made a role as reflector. The less the effect of plastic cells are decreased, the more activity is high, and the effect of those can be neglected at the activity of 200,000 DPM.

A Robust Method for Automatic Generation of Moire Reference Phase from Noisy Image (노이즈 영상으로부터 모아레 기준 위상의 강인 자동 생성 방법)

  • Kim, Kuk-Won;Kim, Min-Young
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.5
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    • pp.909-916
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    • 2009
  • This paper presents the automatic vision algorithm to generate and calibrate reference phase plane to improve the accuracy of 3D measuring machine of using phase shifting projection moire method, which is not traditional N-bucket method, but is based on direct image processing method to the pattern projection image. Generally, to acquire accurate reference phase plane, the calibration specimen with well treated surface is needed, and detailed calibration method should be performed. For the cost reduction of specimen manufacturing and the calibration time reduction, on the specimen, not specially designed, with general accuracy level, an efficient calibration procedure for the reference phase generation is proposed. The proposed vision algorithm is developed to extract the line center points of the projected line pattern from acquired images, derive the line feature information consisting of its slope and intercept by using sampled feature points, and finally generate the related reference phase between line pairs. Experimental results show that the proposed method make reference phase plane with a good accuracy under noisy environment and the proposed algorithm can reduce the total cost to make high accurate calibration specimen, also increase the accuracy of reference phase plane, and reduce the complex calibration procedure to move grid via N-bucket algorithm precisely.

A Study on the Evaluation of Cleaning Ability Using Optically Stimulated Electron Emission Method (광전자방출(OSEE)법을 이용한 세정성 평가 연구)

  • Min, Hye-Jin;Shin, Jin-Ho;Bae, Jae-Heum
    • Clean Technology
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    • v.14 no.2
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    • pp.95-102
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    • 2008
  • In order to choose alternative environmental-friendly cleaning agents, it is very important in the present point that the systematic selection procedures should be introduced and applied to the industry through the evaluation of their cleaning ability, environmental characteristics, and economical factors, and that the objective and effective evaluation methods of cleanliness should be established for the industry. Thus, a novel cleaning evaluation method utilizing optically stimulated electron emission (OSEE) among various methods of cleaning ability was studied in this study. The contaminants used in this cleaning experiments were flux, solder, grease, cutting oil, and mixed soil of 35% grease and 65% cutting oil. The cleaning agents developed or prepared in our laboratory were employed and their cleaning ability were comparatively evaluated by the OSEE, gravimetry and contact angle methods. The experimental results in this work showed that flux cleaning efficiency measured by the OSEE method was similar to that of the gravimetric method, but that the OSEE method could not be compared with gravimetric method for the case of solder or grease cleaning because the contaminants radiate or absorb ultra-violet light. In case of cutting oil cleaning, the gravimetric method indicated its limitation of cleaning efficiency of cutting oil since it showed cleaning efficiency of 100%, even though residual soil remaining on the substrate surface a little after its cleaning. The comparative experimental results of cleaning ability evaluated by the OSEE- and contact angle measurement methods showed that they were similar in case of cleaning of flux, mixed soil and cutting oil. It was judged that the contact angle measurement method could evaluate the cleaning ability more precisely than the OSEE method for cleaning solder and grease.

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Image Mosaicking Using Feature Points Based on Color-invariant (칼라 불변 기반의 특징점을 이용한 영상 모자이킹)

  • Kwon, Oh-Seol;Lee, Dong-Chang;Lee, Cheol-Hee;Ha, Yeong-Ho
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.46 no.2
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    • pp.89-98
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    • 2009
  • In the field of computer vision, image mosaicking is a common method for effectively increasing restricted the field of view of a camera by combining a set of separate images into a single seamless image. Image mosaicking based on feature points has recently been a focus of research because of simple estimation for geometric transformation regardless distortions and differences of intensity generating by motion of a camera in consecutive images. Yet, since most feature-point matching algorithms extract feature points using gray values, identifying corresponding points becomes difficult in the case of changing illumination and images with a similar intensity. Accordingly, to solve these problems, this paper proposes a method of image mosaicking based on feature points using color information of images. Essentially, the digital values acquired from a digital color camera are converted to values of a virtual camera with distinct narrow bands. Values based on the surface reflectance and invariant to the chromaticity of various illuminations are then derived from the virtual camera values and defined as color-invariant values invariant to changing illuminations. The validity of these color-invariant values is verified in a test using a Macbeth Color-Checker under simulated illuminations. The test also compares the proposed method using the color-invariant values with the conventional SIFT algorithm. The accuracy of the matching between the feature points extracted using the proposed method is increased, while image mosaicking using color information is also achieved.