• Title/Summary/Keyword: 미소재료

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Detection of Acoustic Signal Emitted during Degradation of Lithium Ion Battery (리튬이온전지의 열화손상에 의한 음향방출 신호 검출)

  • Choi, Chan-Yang;Byeon, Jai-Won
    • Journal of the Korean Society for Nondestructive Testing
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    • v.33 no.2
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    • pp.198-204
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    • 2013
  • Acoustic emission(AE) signal was detected during charge and discharge of lithium ion battery to investigate relationships among cumulative count, discharge capacity, and microdamages. AE signal was received during accelerated charge/discharge cycle test of a coin-type commercial battery. A number of AE signals were successfully detected during charge and discharge, respectively. With increasing number of cycle, discharge capacity was decreased and AE cumulative count was observed to increase. Microstructural observation of the decomposed battery after cycle test revealed mechanical damages such as interface delamination and microcracking of the electrodes. These damages were attributed to sources of the detected AE signals. Based on a linear correlation between discharge capacity and cumulative count, feasibility of AE technique for evaluation of battery degradation was suggested.

Effect of load on the wear and friction characteristics of a carbon fiber composites (탄소 섬유 복합재의 마찰 및 마모 특성에 미치는 하중 효과)

  • Koh, Sung-Wi;Yang, Byeong-Chun;Kim, Hyung-Jin;Kim, Jae-Dong
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.40 no.4
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    • pp.344-350
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    • 2004
  • This is the study on dry sliding wear behavior of unidirectional carbon fiber reinforced epoxy matrix composite at ambient temperature. The wear rates and friction coefficients against the stainless steel counterpart specularly processed were experimentally determined and the resulting wear mechanisms were microscopically observed. Three principal sliding directions relative to the dominant fiber orientation in the composite wear selected. When sliding took place against smooth and hard counterpart, the highest were resistance and the lowest friction coefficient were observed in the antiparallel direction. When the velocity between the composite and the counterpart went up, the wear rate increased. The fiber destruction and cracking caused fiber bending on the contact surface, which was discovered to be dominant wear mechanism.

Numerical Analysis of Load Carrying Capacity of RC Structures Based on Concrete Damage Model (콘크리트 손상 모델을 적용한 콘크리트 구조물 구조내력 해석)

  • Woo, Sang Kyun;Lee, Yun;Yi, Seong Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.5
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    • pp.121-128
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    • 2012
  • In this paper, nonlinear analysis for reinforced concrete structure for power transmission line is performed by considering the characteristics of the failure, which are depend on loading conditions and concrete material models. On the numerical evaluation for the failure behavior, the finite element analysis is applied. For the concrete material model, microplane model based on concrete damage is introduced. However, to describe the crack bridging effect of long and short fiber of steel fiber reinforced concrete (SFRC), tensile softening model is suggested and applied for SFRC. An numerical results by finite element technique are compared with the experiment results for box culvert specimen. Comparing on the experimental and analytical results, validity and reliability of numerical analysis are investigated.

Corrosion and Mechanical characteristics for 9Cr-1MoVNb Steel under SO2 gas environment (SO2 가스 환경 하에서 9Cr 템퍼드-마르텐사이트강의 부식 및 기계적 특성)

  • Jeong, Gwang-Hu;Kim, Seong-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.109-109
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    • 2018
  • Cr-Mo 합금강은 고온 환경 하에서 높은 크리이프 강도와 우수한 내식성 때문에 발전설비, 석유 화학, 그리고 해양산업과 같은 여러 산업분야에서 널리 사용되고 있다. 특히, Cr-Mo 강의 내식성은 합금 내 Cr 함량에 크게 의존한다. 이는 고온에서 Cr과 O가 화학적 반응을 일으킴에 따라 보호성의 Cr 산화스케일을 형성하기 때문이다. 그러나 화석연료를 사용하는 발전설비의 경우, $SO_2$가 포함된 강한 부식성의 연소 가스가 배출되며, 이에 노출된 금속의 표면에서는 산화와 황화가 동시에 발생한다. 황화스케일은 산화스케일에 비해 매우 빠르게 성장하며, 그 특성이 매우 취약하기 때문에 황화 환경에서 금속의 내식성 및 기계적 물성치는 보다 크게 저하된다. 따라서 본 연구에서는 화력 발전소의 증기발생용 튜브 재료인 9Cr-1MoVNb 강을 선정하였으며, $SO_2$ 가스 환경 하에서의 부식 및 기계적 물성치 저하 특성을 평가하고자 하였다. 본 연구에서 사용된 9Cr-1MoVNb강의 화학 성분 조성은 0.1 C, 0.38 Si, 0.46 Mn, 0.25 Ni, 8.38 Cr, 0.93 Mo, 0.18 V, 0.09 Nb, 그리고 나머지는 Fe이다. 부식시험은 가공된 미소시험편과 인장시험편을 전기열처리로에 장입한 후, $650^{\circ}C$에서 $N_2+O_2+O_2+SO_2$ 조성의 가스를 분당 50 CC로 흘려주었다. 제작된 시험편에 대한 부식거동은 무게 증가량, optical microscope, scanning electron microsope, 그리고 energy dispersive x-ray spectrum을 통해 평가하였다. 그리고 기계적 물성치 평가를 위한 인장시험은 분당 2mm 변위제어를 통해 실시하였다. 그 결과, 9Cr-1MoVNb 강은 $SO_2$ 가스 환경 하에서 비 보호적인 Fe-풍부상의 산화 스케일층이 두껍게 형성됨에 따라 열악한 내식성을 나타냈다. 그에 따라 기계적 물성치는 저하되는 경향을 나타내었다.

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The Effect of the Core-shell Structured Meta-aramid/Epoxy Nanofiber Mats on Interfacial Bonding Strength with an Epoxy Adhesive in Cryogenic Environments (극저온 환경에서 에폭시 접착제의 물성 향상을 위한 나노 보강재의 표면 개질에 관한 연구)

  • Oh, Hyun Ju;Kim, Seong Su
    • Composites Research
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    • v.26 no.2
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    • pp.129-134
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    • 2013
  • The strength of adhesive joints employed in composite structures under cryogenic environments, such as LNG tanks, is affected by thermal residual stress generated from the large temperature difference between the bonding process and the operating temperature. Aramid fibers are noted for their low coefficient of thermal expansion (CTE) and have been used to control the CTE of thermosetting resins. However, aramid composites exhibit poor adhesion between the fibers and the resin because the aramid fibers are chemically inert and contain insufficient functional groups. In this work, electrospun meta-aramid nanofiber-reinforced epoxy adhesive was fabricated to improve the interfacial bonding between the adhesive and the fibers under cryogenic temperatures. The CTE of the nanofiber-reinforced adhesives were measured, and the effect on the adhesion strength was investigated at single-lap joints under cryogenic temperatures. The fracture toughness of the adhesive joints was measured using a Double Cantilever Beam (DCB) test.

Hydration of High-volume GGBFS Cement with Anhydrite and Sodium Sulfate (경석고 및 황산나트륨을 함유한 하이볼륨 고로슬래그 시멘트의 수화특성)

  • Moon, Gyu-Don;Choi, Young-Cheol
    • Journal of the Korea Concrete Institute
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    • v.27 no.2
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    • pp.177-184
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    • 2015
  • In order to use the high-volume slag cement as a construction materials, a proper activator which can improve the latent hydraulic reactivity is required. The dissolved aluminum silicon ions from ground granulated blast furnace slag (GGBFS) react with sulfate ions to form ettringite. The proper formation of ettringite can increase the early-age strength of high-volume GGBFS (80%) cement. The aim of this study is to investigate the hydration properties with sulfate activators (sodium sulfate, anhydrite). In this paper, the effects of $Na_2SO_4$ and $CaSO_4$ on setting, compressive strength, hydration, micro-structure were investigated in high-volume GGBFS cement and compared with those of without activator. Test results indicate that equivalent $SO_3$ content of 3~5% improve the early-age hydration properties such as compressive strength, heat evolution rate, micro-pore structure in high-volume GGBFS cement.

Growth of $PbMg_{1/3}Nb_{2/3}O_3$ Single Crystals by Flux Method (융제법에 의한 $PbMg_{1/3}Nb_{2/3}O_3$단결정 성장)

  • 임경연;박찬석
    • Korean Journal of Crystallography
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    • v.8 no.2
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    • pp.75-80
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    • 1997
  • A perovskite relaxor ferroelectrics PMN is used as an important material to investigate the diffusive phase transition phenomena. In this study PMN single crystals were grown and the microstructure were observed. For the growth of PMN single crystals, the spontaneous nucleation technique and the TSSG technique were used. 2-5mm single crystals were grown from PbO self flux and it was observed that only PMN crystals were grown when excess MgO was added over 100% as flux. Single crystals with well developed (001) faces were obtained from PbO-B2O3 flux. single crystals larger than 1 cm were grown from PbO-B2O3 flux by TXXG technique. For higher quality crystals, optimization of the variables such as the rotation speed of seed crystal, the orientation of seed crystal, and cooling rate is needed. With grown crystals, it was confirmed by TEM diffraction pattern of thin plate crystal that the 1:1 ordering of Mg2+ and Nb5+ with small volume exists.

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Nonlinear Finite Element-Boundary Element Analysis of Multi-Layered Structural Systems (유한요소와 경계요소의 조합에 의한 다층 구조계의 비선형 해석)

  • 김문겸;허택녕;이상도
    • Computational Structural Engineering
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    • v.7 no.4
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    • pp.57-67
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    • 1994
  • It is usual that underground structures are constructed within a multi-layered medium. In this paper, an efficient numerical modelling of multi-layered structural systems is studied using coupled analysis of finite elements and boundary elements. The finite elements are applied to the area in which the material nonlinearity dominates, and the boundary elements are applied to the far field where the nonlinearity is relatively weak. In the boundary element modelling of the multi-layered medium, fundamental solutions are not readily available. Thus, methods which can utilize existing Kelvin solutions are sought for the interior multi-layered domain problem. The interior domain problem which has piecewise homogeneous layers is analyzed using boundary elements with Kelvin solution, by discretizing each homogeneous subdomain and enforcing compatibility and equilibrium conditions between interfaces. Developed methodology is verified by comparing its results with those from the finite element analysis and it is concluded that coupled analysis using boundary elements and finite elements can be reasonable and efficient.

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Durability Performances of Concrete Produced with Recycled Bio-Polymer Based on Sargassum Honeri (괭생이모자반 기반의 자원순환형 바이오 폴리머를 혼입한 콘크리트의 내구성능)

  • Lee, Byung-Jae;Lee, Sun-Mok;Hyun, Jung-Hwan;Kim, Yun-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.445-451
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    • 2019
  • In this study, we evaluated the durability of concrete produced with recycled polymer that could replace synthetic polymer, which is the main raw material of bridge deck concrete pavement. As a result of the slump and air content test, the requirements of the Korea Highway Corporation Standard were satisfied with all mixing conditions. The slump was lowered when incorporating the recycled bio-polymer, compared to other mix proportions concrete. In contrast, the compressive strength was increased by 6.3~24.4% when the recycled bio-polymer was mixed, compared to the concrete produced with synthetic polymer. It should be noted that the compressive strength was lowered when synthetic polymer was added to concrete mixture. Durability test results showed the best durability when incorporating synthetic polymer. The durability of concrete also increased as the amount of recycled bio-polymer increased, however, the impact was slightly smaller than that of synthetic polymer.

Assessment of Yield Characteristics of Gas Pipeline Materials by Observing Surface-Local Deformation (미소 표면변형 관찰을 통한 가스배관 부재의 항복특성 평가)

  • Lee, Yun-Hee;Baek, Un-Bong;Cheong, In-Hyeon;Nahm, Seung-Hoon;Lee, Sang-Houck
    • Journal of the Korean Institute of Gas
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    • v.12 no.2
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    • pp.92-98
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    • 2008
  • A combination of the instrumented indentation and 3D morphology measurement has been tried in order to perform a real-time property measurement of degraded materials in gas pipelines; three-dimensional indent morphologies were recorded using a reflective laser scanner after a series of insturmented indentations on three metallic specimens. Dimensions of the permanent deformation zone and contact boundary were analyzed from the cross-sectional profile over an remnant indent and used for estimating yield strength and hardness, respectively. Estimated yield strength was comparable with that from uniaxial tensile test and actual hardness implying material pile-up effects was lower than the calculated value from indentation curve by $20{\sim}30%$. It means that this 3D image analysis can explain the material pile-up effects on the contact properties. Additionally, a combined system of indentation and laser sensor was newly designed by modifying a shape of the indentation loading fixture.

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