• Title/Summary/Keyword: 미량유기물질

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Physicochemical Stability of Anthocyanins from a Korean Pigmented Rice Variety as Natural Food Colorants (천연색소로서 한국산 유색미 안토시아닌의 안정성 연구)

  • Yoon, Joo-Mi;Cho, Man-Ho;Hahn, Tae-Ryong;Paik, Young-Sook;Yoon, Hye-Hyun
    • Korean Journal of Food Science and Technology
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    • v.29 no.2
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    • pp.211-217
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    • 1997
  • The physical and chemical stability of anthocyanins from a Korean pigmented rice variety was investigated at various conditions of pH, temperature, metal ion, sugar, organic acid and light. The anthocyanin pigments were relatively stable with half-lives of 36 days (pH 2.0) and 17 days (pH 3.0), while they were decomposed in a day at neutral and basic pH of 7.0 and 9.0 at $25^{\circ}C$. The anthocyanins also showed high thermal stability at pH 3.0; the half-lives were 7.4 hr, 23.6 hr and 96.3 hr at $95^{\circ}C,\;75^{\circ}C\;and\;50^{\circ}$, respectively. Addition of di- and tri-valent metal ions at pH 3.0 resulted in the increase of color intensity and stability throughout 21 days of storage periods at $25^{\circ}C$. Most sugars added accelerated the degradation of anthocyanin pigments, so that fructose showed the greatest degradation effect on the pigments. Addition of citric acid at pH 3.0 increased stability of anthocyanins, while tartaric acid decreased stability. The anthocyanins were very sensitive on light irradiation with a degradation half-life of 14 hr under 20,000 lux-light dosage at pH 3.0.

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Complex Terrain and Ecological Heterogeneity (TERRECO): Evaluating Ecosystem Services in Production Versus water Quantity/quality in Mountainous Landscapes (산지복잡지형과 생태적 비균질성: 산지경관의 생산성과 수자원/수질에 관한 생태계 서비스 평가)

  • Kang, Sin-Kyu;Tenhunen, John
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.12 no.4
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    • pp.307-316
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    • 2010
  • Complex terrain refers to irregular surface properties of the earth that influence gradients in climate, lateral transfer of materials, landscape distribution in soils properties, habitat selection of organisms, and via human preferences, the patterning in development of land use. Complex terrain of mountainous areas represents ca. 20% of the Earth's terrestrial surface; and such regions provide fresh water to at least half of humankind. Most major river systems originate in such terrain, and their resources are often associated with socio-economic competition and political disputes. The goals of the TERRECO-IRTG focus on building a bridge between ecosystem understanding in complex terrain and spatial assessments of ecosystem performance with respect to derived ecosystem services. More specifically, a coordinated assessment framework will be developed from landscape to regional scale applications to quantify trade-offs and will be applied to determine how shifts in climate and land use in complex terrain influence naturally derived ecosystem services. Within the scope of TERRECO, the abiotic and biotic studies of water yield and quality, production and biodiversity, soil processing of materials and trace gas emissions in complex terrain are merged. There is a need to quantitatively understand 1) the ecosystem services derived in regions of complex terrain, 2) the process regulation occurred to maintain those services, and 3) the sensitivities defining thresholds critical in stability of these systems. The TERRECO-IRTG is dedicated to joint study of ecosystems in complex terrain from landscape to regional scales. Our objectives are to reveal the spatial patterns in driving variables of essential ecosystem processes involved in ecosystem services of complex terrain region and hence, to evaluate the resulting ecosystem services, and further to provide new tools for understanding and managing such areas.

Effect of Dietary Organic or Inorganic Minerals (Selenium and Copper) on Layer's Production and Their Transfer into the Egg (사료 내 유기태 및 무기태 미네랄(셀레늄, 구리)의 수준별 첨가가 산란계의 생산성과 계란 내 이행에 미치는 영향)

  • Park, T.S.;Kim, J.Y.;You, S.J.;Lee, B.K.;Kim, J.M.;Kim, E.J.;Ahn, B.K.;Kang, C.W.
    • Korean Journal of Poultry Science
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    • v.36 no.2
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    • pp.103-110
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    • 2009
  • This experiment was conducted using 350 Lohmann Brown layers (67 weeks of age) to evaluate the dietary effect of organic or inorganic Se and Cu on their contents in chicken eggs. The layers were divided into seven groups and fed a commercial diet or one of the six experimental diets containing different levels of Se and Cu (T1, 0.3ppm organic Se; T2, 1.0ppm organic Se; T3, 1.0ppm inorganic Se; T4, 125ppm organic Cu; T5, 250ppm organic Cu; and T6, 250ppm inorganic Cu) for 5 weeks. No significant differences were observed in egg production and its qualities among groups. The contents of blood cholesterol in the birds fed various levels of Se and Cu were not significantly different as compared to control. Se contents in eggs were linearly increased as dietary Se levels increased for both sources, but Se contents from the groups fed organic Se were slightly higher than those fed inorganic Se. Sensory characteristics of eggs were not influenced by dietary treatments. In conclusion, Se contents in eggs were linearly increased as dietary levels of organic or inorganic Se increased, but eggs in layers fed the diet containing organic Se did not show higher Se contents than those in birds fed dietary inorganic Se.

Removal of Dissolved Humic Acid with Physicochemical Treatment Process (물리화학적 공정에 의한 용존성 Humic Acid의 제거)

  • Kim, Jong-Shik;Choi, Joon-Ho
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.737-742
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    • 1999
  • This study was conducted for the two purposes; one was removal of dissolved humic acid, the well-known precursor of trihalomethanes (THMs), by physicochemical treatment processes such as ozone oxidation, coagulation and activated carbon adsorption. The other was qualitative identification of by-products in chlorination of the dissolved humic acid. When ozone oxidation was applied to remove the dissolved humic acid, pH was abruptly decreased. It was indicated that humic acid was not perfectly converted to $CO_2$ and $H_2O$, but to low fatty acid. In coagulation process, the coagulant was polyaluminumchloride which was widely used for drinking water treatment in recent years. With the dosage of 160 mg/L, total organic carbon(TOC), $COD_{Cr}$ and color were removed with 23%, 24% and 5% respectively. Color was effectively removed by ozone oxidation process, which was the first order reaction, with the reaction rate constant of $0.067min^{-1}$. In activated carbon adsorption process, preozonation process could remove more effectively the dissolved humic acid than that without preozonation. When the dissolved humic acid and sodium hydrochloride were reacted with 1 mg-NaOCl/mg-TOC, only trihalomethanes were detected.

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Preparation and characterization of the primary gas standards for isoprene (아이소프렌 일차표준가스의 제조 및 특성 평가)

  • Kim, Taesu;Kang, Chul-Ho;Kim, Yong Doo;Lee, Seungho;Kim, Dalho
    • Analytical Science and Technology
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    • v.27 no.6
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    • pp.357-363
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    • 2014
  • Isoprene is a one of the biogenic volatile organic compounds (BVOCs) and it is known as a source of the tropospheric ozone and formaldehyde. In addition, isoprene is a trace component of the exhaled breath and it is a potential biomarker for the diagnosis of diseases such as lung cancer. In these regards, isoprene gas standards are required for the accurate measurement of isoprene in air samples. To establish a standard for isoprene gas, gravimetric preparation and characterization of primary gas standards were studied. The primary gas standards were produced independently in 4 aluminum cylinders and concentrations were examined by GC-FID. As a result, the uncertainty of the gravimetric preparations including purity of the raw material was 0.01% and reproducibility of the preparation of independent 4 cylinders was 0.08%. The primary gas standards for isoprene showed 14 months of long-term stability. The relative expended uncertainty of 2.8% (95% of confidence level, k=1.96) was assigned to the certified value of 10 ${\mu}mol$/mol level of isoprene based on the quantitative evaluation of the purity, weighing, reproducibility, adsorption and long-term stability.

Physicochemical Analysis and Sensory Evaluation of Fermented Soy Sauce from Gorosoe(Acer mono Max.) and Kojesu(Betula costata T.) Saps (고로쇠 및 거제수나무 수액 간장의 이화학적 분석 및 관능 평가)

  • Choi, Sun-Young;Sung, Nak-Ju;Kim, Haeng-Ja
    • The Korean Journal of Food And Nutrition
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    • v.19 no.3
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    • pp.318-326
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    • 2006
  • Soy sauce was prepared with the addition of Gorosoe and Kojesu saps instead of tap water to make ordinary soy sauce, respectively. The changes of free sugar, organic acid, mineral, amino acid and nucleotides and other compounds during the fermentation of soy sauce were assessed. The free sugar were found to be fructose, glucose, galactose and sucrose in soy sauce of saps but sucrose was not detected in ordinary soy sauce. Galactose contents were dominant free sugar in all samples. The contents of butyric acid were dominant among 7 kinds of organic acid while fumaric acid was trace amount during the fermentation of soy sauce. The contents of potassium and phosphorus among 13 kinds of minerals were dominant during the fermentation of soy sauce. In the amino acid composition of soy sauce, dominant amino acid was glutamic acid(185.6${\pm}$1.0 mg/100 ml above), but proline and arginine were not detected. AMP detected above 7.5${\pm}$O.2 ${\mu}$mol/100 ml was dominant while inosine was not detected during the fermentation of soy sauce. The results of sensory evaluation in the fermented soy sauce of Gorosoe was 'liked more' than that of soy sauce of Kojesu and control.

Small Metal Ion Effect on The Harvest of Perilla Leaves in Aquiculture (수경재배 들깻잎의 수확량에 미치는 미량금속 이온 효과)

  • 배계선;성대동;정대수
    • Journal of Life Science
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    • v.8 no.6
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    • pp.702-710
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    • 1998
  • The perillas were cultivated to investigate for the small metal ion effect on the harvest of perilla loaves in aquicul-ture system in the constant flow rate. The perillas were und-ergrown at the condition of low concentration of KNO$_3$and NH$_4$ H$_2$ PO$_4$as below 270ppm and 152ppm respectively. The high concentration of the metal and non-metal ca-tions of $Ca^{2+}$, $K^+,NH^{4+},Mn^{2+},Zn^{2+},Cu^{2+},Na^+,Mo^{+6}$ are influenced to the growth of plant length of perillas at the earlier time. The low concentration of the metal cations of $Ca^{2+}, K^+, NH^{4+}, NO_3^-, H_2PO_4^-$ are influenced to lower growth of perillas. The concentration of the cations of $Ca^{2+}, K^+$and $NH_4^+$ and the anions of $NO_3^-$and $H_2PO_4^-$ are affected the growth of leaf length and width of leaf of perillas. The spectoscopic analytical results showed that the perillas were growing rapidly in the period of 6 days from June 7 to June 12 by high amount of $Mg^{2+}$ ion with accumulation inside perillas. The crude protein, the crude fat and the hydrocarbon are accumulated in the leaves of perillas by binding the inorganic with amino acids to provide the nutritions needed for growth of perillas.

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Analysis on the Components of the Elaeagnus multiflora Thunb. Leaves (뜰보리수 잎의 유용성분 분석)

  • Yoon, Kyung-Young;Hong, Ju-Yeon;Shin, Seung-Ryeul
    • Food Science and Preservation
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    • v.14 no.6
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    • pp.639-644
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    • 2007
  • This study analyzed components of the leaves of Elaeagnus multiflora as part of studies on the nutritional and functional materials of fruits and leaves of this plant. The moisture content of the leaves was 71.6% and the carbohydrate, crude protein, lipid and ash contents were 24.1, 1.4, 0.4 and 2.5%, respectively. Concentrations of reducing sugars, soluble proteins and polyphenols were 460.0, 503.3 and 805.6 mg/100 g, respectively. Fructose was the dominant free sugar, and arabinose, maltose, glucose, and a small amount of trehalose were also detected. Malic acid was the main organic acid in E. multiflora leaves, and acetic acid, citric acid, lactic acid, and succinic acid were also present. E. multiflora leaves were high in K, Ca and Mg. Of hydrolyzed amino acids, alanine was present at the highest concentration (112.0 mg/100 g), with threonine, leucine, valine and phenylalanine being the next most common. Glutamic acid and ornithine were the dominant free amino acid and amino acid derivative, respectively.

Operation of Advanced Water Treatment Processes for Downstream River Source Water (상수원수의 고도정수처리 공정 파일롯 운전 연구)

  • Wang, Chang-Keun;Oh, Sang-Eun
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.1
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    • pp.1-6
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    • 2012
  • Down Stream K River has high COD (4-10 mg/L) and high $NH_3$-N concentration (3.5 mg/L during winter period). Although $NH_3$-N itself is not reported harmful at this level, it must be removed to meet drinking water standard (0.5 mg/L). We constructed a pilot plant modifying the processes of conventional drinking water facilities. Prechlorination and powdered activated carbon (PAC) dechlorination was adopted prior to a flocculation tank to remove ammonia and prevent disinfection byproducts (DBPs) formation. Also, GAC processes was included after sand filter to remove residual DOC. This pilot having a capacity of 36 ton/day was operated for one year. The GAC processes were successful to remove ammonia and many organic pollutants (DOC, MBAS, UV-254 nm absorbance, etc). Influent DOC concentrations were very high as 3~6 mg/L throughout the plant operation. It was impossible to achieve 1.0 mg/L effluent DOC, indicating that bed depth (2 m) should be increased to achieve more strict DOC quality standards. When $Cl_2$ dose was well controlled ($Cl_2/NH_3$-N ratio 10~11 on a weight basis), $NH_3$-N removal was 98% and THMs was very low possibly due to low free residual chlorine and PAC dechlorination.

Geochemical Study of the Jigunsan Shale: A Sequence Stratigraphic Application to Defining a Middle Ordovician Condensed Section, Taebacksan (Taebaeksan) Basin (직운산 세일층의 지화학적 연구: 태박산분지 오오도비스 중기 응축층 규명을 위한 시퀀스층서학적 적용)

  • Ryu, In-Chang;Ryu, Sun-Young;Son, Byeong-Kook
    • Economic and Environmental Geology
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    • v.42 no.1
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    • pp.27-53
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    • 2009
  • A 30-m-thick Middle Ordovician Jigunsan Shale exposed along the southern limb of the Backunsan (Baekunsan) Syncline, Taebacksan (Taebaeksan) basin, has been simply considered as a transgressive shale sequence onlapped the underlying Maggol platform carbonates. Results of this study, however, suggest that majority of the Jigunsan Shale be interpreted as a regressive shale sequence downlapped onto a thin (ca. 240 cm) marine stratigraphic unit consisting of organic-rich (>3 wt.% of TOC) black shales in the lower Jigunsan Shale, which was accumulated at the time of maximum regional transgression. Detailed stratigraphic analysis in conjunction with XRD, XRF, and ICP-MS as well as Rock-Eval pyrolysis allows the thin marine stratigraphic unit in the Jigunsan Shale to define a condensed section that was deposited in a distinctive euxinic zone formed due to expansion of pycnocline during the early highstand phase. As well, a number of stratigraphic horizons of distinctive character that may have sequence stratigraphic or environmental significance, such as transgressive surface, maximum flooding surface, maximum sediment starvation surface, and downlap surface, are identified in the lower Jigunsan Shale. In the future, these stratigraphic horizons will provide very useful information to make a coherent regional stratigraphic correlation of the Middle Ordovician strata and to develop a comprehensive understanding on stratigraphic response to tectonic evolution as well as basin history of the Taebacksan Basin.