• Title/Summary/Keyword: 물성저하

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SHEAR BOND STRENGTH AND FAILURE PATTERNS ACCORDING TO THE THICKNESS OF RESIN BASE IN BRACKET BONDING (브라켓 부착시 레진 베이스의 두께에 따른 전단결합강도와 파절양상에 관한 연구)

  • Kim, Jae-Hyuk;Hwang, Hyeon-Shik
    • The korean journal of orthodontics
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    • v.28 no.4 s.69
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    • pp.659-668
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    • 1998
  • The purpose of this study was to evaluate the possibility of the decrease of bond strength due to increased thickness of resin base in indirect bracket bonding technique. Metal brackets were bonded to the resin blocks involving bovine lower incisors and the thickness of resin bases was increased by increments of 0.5 mm from 0.0 mm to 2.0 mm. They were divided into two groups, one group is that the thickness of resin base was increased but the loading point from the tooth surface was maintained constantly, the other group is that the loading point from the tooth surface and the resin base thickness were increased concomitantly. The shear bond strength was tested on universal testing machine and the failure patterns were assessed with the adhesive remnant index(ARI). The results were as follows: 1. When the distance from the tooth surface to the loading point was maintained constantly, shear bond strength was increased significantly according to the decrease of distance from the bracket base to the loading point and the increase of resin base thickness. 2. When the distance from the tooth surface to the loading point and the resin base thickness were increased concomitantly, shear bond strength was decreased according to the increase of resin base thickness but significant differences were ignorable. 3. There were no significant differences in ARI scores according to the change in the thickness of resin base. The results of the present study indicated that shear bond strength was not much affected by the thickness of resin base, whereas was decreased according to the increase of distance from bracket base to the loading point.

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Numerical Study on Freezing and Thawing Process in Modular Road System (모듈러 도로시스템의 동결-융해에 대한 수치해석적 연구)

  • Shin, Hosung;Kim, Jinwook;Lee, Jangguen;Kim, Dong-Gyou
    • Journal of the Korean Geotechnical Society
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    • v.33 no.3
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    • pp.49-62
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    • 2017
  • In order to understand response of geo-structures to the freezing-thawing process in the ground, it is necessary to consider phase change of the pore water of the ground and also to understand soil interaction with structures. In this study, numerical analysis was carried out for freezing and thawing effect on the modular road system. Neumann's theoretical equation for freezing-thawing processes in porous media can be used to estimate frozen depth and heaving from basic soil properties and ground and surface temperature, but its application is limited to the case for the sediment with fully saturated condition and zero unfrozen water content. Numerical analysis of the modular road system was performed on various soil types and different ground water table as the varying freezing index. The amount of heaving in the silty soil was much larger than those in granite weathered soil or sandy soil, and lowering groundwater level reduced ground heaving induced by freezing. Numerical analysis for temperature history of the ground surface predicted residual heaving near the surface by the freeze-thaw process in silty soil. It ought to reduce stiffness and bearing capacity of the ground so that it will impair stability and serviceability of new road system. However, the amount of residual heaving was insignificant for the road system installed in weathered soil granite and sandy soil. Since modular road system is a pavement structure mounted on the supporting substructure unlike the prevalent road pavement system, strict criteria should be applied for uniform and differential settlement of the pavement system.

Analysis of Mechanical Behavior of Existing Tunnel by the Construction of Shaft Nearby (근접한 수직구 건설에 따른 기존 터널의 역학적 거동 분석)

  • 이석원;조만섭;이성원
    • Journal of the Korean Geotechnical Society
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    • v.19 no.5
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    • pp.109-122
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    • 2003
  • In order to release the pressure fluctuations and micro-pressure wave induced by the entering of train into the small cross sectional tunnel, it has been reported that the construction of air shaft has more advantages with respect to economy and constructability than the enlargement of cross section of existing tunnel. The field monitorings and analytical studies were conducted simultaneously in this study to analyze the mechanical behavior of existing railway tunnel, new cross tunnel and new shaft by the construction of new shaft nearby. The results showed that the minimum distance from existing tunnel to new shaft which secures the stability of existing tunnel was found to be half diameter of existing tunnel. On the three dimensional mechanical behavior of existing tunnel by the construction of new shaft, the results from the analytical study and field monitoring had a similar trend. The analytical study and field monitoring results, however, produced somewhat different results on the mechanical behavior of new shaft itself. These conclusions induce that the analytical method which has been applied on the analyses of horizontal tunnel could not be applied in the same way on the analysis of vertical shaft.

Study on the Quality Improvement of Sardine Surimi (정어리 냉동고기풀의 품질개선에 관한 연구)

  • Oh, Kwang-Soo;Moon, Soo-Kyung;Lee, Eung-Ho;Kim, Bok-Gyu
    • Korean Journal of Food Science and Technology
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    • v.25 no.4
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    • pp.327-333
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    • 1993
  • The processing conditions and quality of sardine surimi were examined: Raw sardine meat was separated, washed in 0.2% $NaHCO_3$ and 0.15% NaCl solution, and then dewatered by centrifuge. The dewatered sardine meat was chopped, mixed with 20% emulsion curd (soybean protein : water : refined sardine oil=1:5:2.6), 4% sorbitol, 4% sucrose, 0.2% polyphosphate and 0.1% sodium erythorbate by stone mortar. The mixed sardine meat was frozen with contact freezer, packed in carton box and then stored at $-25{\pm}2^{\circ}C$. The moisture, crude protein and lipid contents of the sardine surimi product was 73.3%, 15.0% and 6.9%, respectively. Fatty acid composition of product consisted of 28.8% of saturates, 24.3% of monoenes and 47.7% of polyenes and the major fatty acids were 16:0, 20:5, 18:1, 22:6 and 16:1. The results of changes in POV, TBA value, fatty acids, texture and sensory score of products during frozen storage showed that lipid oxidation and freeze denaturation of product could be retarded, and flavor enhanced by addition 20% emulsion curd and 0.1% sodium erythorbate. In an attempt to apply sardine surimi in producing surimi-based product, it was concluded that pollack surimi could be substituted with sardine surimi up to 40% without showing any significant changes in texture and taste of surimi-based product.

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Studies on the characteristics of stone structures by shape reversal, geotechnical and dynamic structural engineerings (석조구조물의 효율적 유지관리를 위한 형상역공학적, 지반공학적 및 구조동역학적 특성연구 - 첨성대를 중심으로 -)

  • Shon, Bo-Woong;Kim, Seong-Beom
    • 한국지구물리탐사학회:학술대회논문집
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    • 2004.08a
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    • pp.25-48
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    • 2004
  • Structures show the phehomena of deformation and lowering of function with time-lapse by artificial environments and changes of geotechnical conditions or accumulation of initial deformation elements. This study aims the structural assessment of cultural property, Chum-Sung-Dae, located in Kyeongju city, Korea. It was built about 1,300 years ago, and has undergone deformation and ground-subsidence with time-lapse. Non-destructive evaluation techniques were applied to the Chum-Sung-Dae, to protect it from survey Because of this reason, 3D precise laser scanning surveying system was applied to measure the exact size of Chum-Sung-Dae, displacement and declining angles. Geophysical exploration also was applied to study the subsurface distribution of geotechnical parameters or physical properties. Natural frequencies were measured from real and model of Chum-Sung-Dae to study the dynamic characteristics of vibration and/or earthquake load and stiffness of structures.

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재료 동적영향을 고려한 주냉각재 배관 LBB 적용시 Dynamic Strain Aging의 영향 분석

  • 양준석;박치용;정우태;유기완;김진원
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05b
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    • pp.305-311
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    • 1998
  • 최근들어 고려된 LBB(Leak Before Break) 적용요건중 동적파괴시힘 절차에는 울진 3&4호기 이후 파단전누설개념이 적용되는 배관이 탄소강으로 제작될 경우. 이 배관이 Dynamic Strain Aging (DSA)에 의해 파괴저항치가 감소되지 않는다는 것이 정량적으로 입증되지 않는 한, 동 배관의 파괴 물성치 결정시 DSA의 영향이 고려되어야 하며, DSA 영향을 평가하기 위해서는 동적과괴시험이 수행되어야 함을 요건화 하고 있다. 본 연구에서는 DSA 효과에 의한 파괴저항(J-R) 특성의 저하가차세대원전 원자로냉각재배관 파단전누설개넘(LBB) 적용시 설계 안전여유도에 영향을 미치지 않는 정도임을 평가하는데 있다. 따라서 ASME Section III에서 탄소강으로 분류하고 있는 강종별 파괴인성 변화를 고찰하고, 차세대원전 주냉각재배관 재료인 SA508 Class la의 최대 파괴인성 감소치를 예측하여, 울진 3&4호기에서 측정된 엘보우용 SA516-Gr.70 강의 DSA 영향 평가 결과와 비교 분석하여 차세대원전 주냉각재배관의 DSA영향을 평가하였다. 도출된 결론으로는 DSA 영향을 고려한 SA508 Class la의 J 및 dJ/dA 값은 극히 보수적으로 추정할 때 50% 이상 감소하는 것으로 예측된다. 이러한 DSA 영향을 고려하였을 경우 배관재 모재의 파괴인성치는 Weld-SAW의 J/T 값 수준으로 감소하였다. 그러나 현 LRB 해석이 가장 낮은 J/T값을 갖는 Weld-SAW Auto의 균열길이 2a인 J/T선도에 의거하여 수행되고 있다는 점을 고려한다면 비록 DSA가 배관재에 영향을 주는 가장 보수적인 값(J 및 dJ/dA값을 50% 이상)을 사용한다고 하더라도 차세대원전 LBB 적용에 문제가 되지 않음을 알 수 있다. 즉 차세대원자로 주냉각재배관에 LBB를 적용하는데는 DSA 영향은 상대적으로 중요하지 않다는 결론을 얻었다. 표면에 수소화물이 농축되어 있는 hydride layer가 형성됨을 관찰하였으며 ~5,000ppm 이상의 경우에는 수소화물의 방향성이 random하였으며 특히, ZIRLO$^{TM}$ 시편의 경우에서는 원주방향으로 길게 이어진 수소화물과 기계적 성질에 치명적인 반경방향의 수소화물이 평행하게 배열된 것을 관찰하였다.하였을 때는 Li$_2$O의 첨가에 의해 치밀화가 주로 일어났고, 반면에 $N_2$-7vol.%H$_2$ 분위기에서 소결하면 Li$_2$O의 첨가에 의해 작은 기공은 소멸되고 큰 기공이 생성되었다.지나치게 모국어의 영향만 강조하고 다른 요인들에 대해서는 다분히 추상적인 언급으로 끝났지만 이 분석을 통 해서 배경어, 목표어, 특히 중간규칙의 역할이 괄목할 만한 것임을 가시적으로 관찰할 수 있 다. 이와 같은 오류분석 방법은 학습자의 모국어 및 관련 외국어의 음운규칙만 알면 어느 학습대상 외국어에라도 적용할 수 있는 보편성을 지니는 것으로 사료된다.없다. 그렇다면 겹의문사를 [-wh]의리를 지 닌 의문사의 병렬로 분석할 수 없다. 예를 들어 누구누구를 [주구-이-ν가] [누구누구-이- ν가]로부터 생성되었다고 볼 수 없다. 그러므로 [-wh] 겹의문사는 복수 의미를 지닐 수 없 다. 그러면 단수 의미는 어떻게 생성되는가\ulcorner 본 논문에서는 표면적 형태에도 불구하고 [-wh]의미의 겹의문사는 병렬적 관계의 합성어가 아니라 내부구조를 지니지 않은 단순한 단어(minimal $X^{0}$ elements)로 가정한다. 즉, [+wh] 의미의 겹의문사는 동일한 구성요 소를 지닌 병렬적 합성어([$[W1]_{XO-}$ $[W1]_{XO}$ ]$_{XO}$)로

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Changes in the Optical and Thermal Properties of Low-Temperature Cured Polyimide Thin Films Using the Catalyst (촉매를 이용한 저온경화 폴리이미드 박막의 광학적/열적 특성 변화)

  • Park, Myeong-Soon;Kim, Kwang-In;Nam, Ki-Ho;Han, Haksoo
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.320-326
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    • 2013
  • In this study, various polyimide films were synthesized via low temperature cure in order to understand changes in their physical properties when using 4,4'-oxydianiline (ODA) as a diamine and dianhydride molecules with different backbones on a single diamine such as 4,4'-Oxydiphthalic anhydride (ODPA), 4,4-hexafluoroisopropylidene diphthalic dianhydride (6FDA), and 3,3', 4,4'-benzophenone tetracarboxylic dianhydride (BTDA). After the synthesis of poly(amic acid), polyimide films were fabricated by adding 1,4-diazabicyclo [2.2.2]octane (DABCO), a low-temperature catalyst, at various wt% to poly(amic acid)s. Changes of optical and thermal properties were compared and analyzed between polyimide films without catalyst and polyimide films with catalyst by FT-IR, UV-Vis transmittance, DSC/TGA, and WAXD analysis. Wide-angle X-ray diffraction (WAXD) analysis revealed that the mean intermolecular distance decreased with the use of a catalyst by the type of dianhydride. Thus, while the optical properties of the films improve by a low-temperature cure performed using a catalyst, their thermal properties decrease. These changes can be explained by the changes in the morphological structure of the films triggered by a catalyst-induced reduction in the mean intermolecular distance. Moreover, the results show that the type of dianhydride determines the degree of change in the optical and thermal properties in each types of polyimide, demonstrating that changes in the optical and thermal properties are directly associated with the backbone of the polyimide structure.

An Experimental Study on Pumpability Characteristics of High Strength Concrete Mixed Polymix (폴리믹스 혼입 고강도 콘크리트의 펌프압송 성상에 관한 실험적 연구)

  • Lee, Joo-Ho;Moon, Hyung-Jae;Kim, Jeong-Jin
    • Journal of the Korea Concrete Institute
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    • v.24 no.5
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    • pp.509-516
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    • 2012
  • The aims of this research is to develop a fire resistant admixture to enhance high-pressured pumping of high-strength concrete (HSC) with a compressive strength of 60~80 MPa. Generally, the efficiency of HSC high-pressured pumping is dramatically reduced due to entanglement of short fibers added to prevent fire spalling. Therefore, the fire resistant admixture that can facilitate pumping of fire resistant HSC is urgently needed presently. The fire resistant HSC mix is comprised of Polypropylene fiber, Nylon fiber and Polymer powder. The test results showed that the slump-flow was improved by approximately 70% of the HSC without fire resistant admixture. However, the air void content was increased slightly due to the addition. The standard design compressive strength at 28-days was satisfied, while its flexural strength was similar to the concrete without the admixture. Since the flexural strength was 12~15% of its compressive strength, the general trend of flexural to compressive strength ratio in normal concrete was maintained. Even though its elastic modulus was decreased by adding the admixture, the study results showed that the concrete can be used for construction since all of the test results exceeded the code requirements.

Evaluation on Weathering Characterization on Rock Types Using Artificial Weathering Test (인공풍화시험을 이용한 암종별 풍화특성 평가)

  • Heo, Yeul;Kang, Changwoo;Kwon, Youngcheul;Bae, Wooseok
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.8
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    • pp.23-32
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    • 2017
  • For exposed slopes, the weathering degree over time has a major effect on the engineering properties of rocks and the slope stability. Rocks are gradually changed by weathering into soil over time, and the resulting physical, chemical and mechanical changes of rocks affect the engineering stability of the slope. However, there are not many ways to objectively evaluate the weathering degree of a slope. In this study, therefore, to investigate the weathering characteristics of rocks, granite, gneiss and shale distributed in the Chungbuk region were sampled by weathering stage and changes in their component minerals and tissues were investigated. Furthermore, artificial weathering was induced using the freezing and thawing test and quantitatively investigated through porosity and absorption rate. In addition, the changes of microcracks due to artificial weathering were evaluated through box fractal dimension ($D_B$). Through mineralogical study the phase change of constituting minerals, the growth of secondary minerals, the development of micro-cracks and the fabric changes due to weathering were observed. The mineralogical, chemical and engineering evaluations of the weathering degree through the experimental results in this study are expected to be useful for analyzing the weathering characteristics and causes by rock type and for proposing a methodology to evaluate the degradation of physical properties comparatively and quantitatively.

Emulsion Polymerization of Vinyl acetate-Butyl acrylate Copolymer (유화 중합에 의한 비닐 아세테이트-부틸 아크릴레이트 공중합체의 합성 연구)

  • 설수덕;임종민
    • Polymer(Korea)
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    • v.28 no.2
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    • pp.135-142
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    • 2004
  • Poly(vinyl acetate) (PVAc) prepared by emulsion polymerization has broad applications for additives such as paint binder, adhesive for wood and paper due to its low glass transition temperature which help to plasticize substrate resins. Since emulsion polymerization has a disadvantage that surfactant and ionic initiator degrade properties of the product polymer, poly(vinyl acetate-co-butyl acrylate) (VVc-BA) was synthesized using potassium persulfate as catalyst and poly(vinyl alcohol) (PVA) as protective colloid to prevent the degradation. The copolymer latex product was internally plasticized and has enhanced colloid stability, adhesion, tensile strength and elongation. During VAc-BA emulsion polymerization, no coagulation and complete conversion occur with the reactant mixture of 0.7wt% potassium persulfate, 15wt% poly(vinyl alcohol) (PVA-217), and the balanced monomer that the weight ratio of vinyl acetate to butyl acrylate is 19. As the concentrations of PVA increase, the copolymerization becomes faster and polymer particles are more stable, resulting in enhanced mechanical stability of the VAc-BA copolymer. However, the size of the polymer particles decreases with increasing PVA contents. Properties of the VAc-BA copolymer, such as minimum film formation temperature, glass transition temperature, surface morphology, molecular weight and molecular weight distribution, tensile strength and elongation, were characterized using differential scanning calorimeter, transmission electron microscope and other instruments.