• Title/Summary/Keyword: 물리·화학적 성질

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Interaction of Fibroblast Cell onto Physicochemically Treated PLGA Surfaces (물리화학적 처리된 PLGA 표면의 섬유아세포와의 상호작용)

  • 강길선;이상진;전주형;이진호;이배방
    • Polymer(Korea)
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    • v.24 no.6
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    • pp.869-876
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    • 2000
  • In order to improve the cell-compatability of poly(L-lactide-co-glycolide) (75 : 25 by mole ratio of lactide to glycolide, PLGA) surfaces, the physicochemical treatments have been demonstrated. Chemical treatments were 70% perchloric acid. 50% sulfuric acid and 0.5 N sodium hydroxide solution and physical methods were corona and plasma treatment. The water contact angle of surface treated PLGA decreased from 73$^{\circ}$ to 50~60$^{\circ}$, i.e., increased hydrophilicity, due to the introduction of oxygen-containing functional group onto PLGA backbone by the measurement of an electron spectroscopy for chemical analysis. It could be observed that the adhesion and growth of fibroblast cell on physicochemically treated PLGA surfaces, especially perchloric acid treated PLGA surface, were more active than on the controt. In conclusion, it seems that surface wettability as hydrophilicity of PLGA plays an important role in cell adhesion, spreading and growth.

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Some Mineralogical and Physico-Chemical Properties of Fuller's Earths from Tertiary Sediments in South Korea (삼기층중(三紀層中)에서 산출(産出)되는 산성백토(酸性白土)에 관(關)한 광물학적(鑛物學的) 조성(組成) 및 물리화학적(物理化學的) 성질(性質)에 관(關)하여)

  • Moon, Hee Soo;Morgan, D.J.
    • Economic and Environmental Geology
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    • v.16 no.3
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    • pp.149-161
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    • 1983
  • Fuller's earth deposits from Miocene sedimentary sequences in Gyeong Sang-do contain up to 95% Ca-montmorillonite accompanied by cristobalite, clinoptilolite, mordenite, quartz, feldspar and X-ray amorphous material. Differential thermal analysis, infrared and electron microscopic data are given for the montmorillonite component. The ease with which the exchangeable calcium of the montmorillonite could be replaced by sodium (to give a product with properties similar to that of a bentonite) was monitored by the Atterberg liquid limit test. Some samples tested as possible binders for foundry moulding sands gave results that compared favourably with material currently being used for this application. Many of the samples also met the OCMA specifications for clays used in drilling muds.

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Fundamental Study on the Utilization of Electric Furnace Slag as a Fine Aggregate for Concrete (전기로(電氣爐)슬래그를 잔골재로 사용한 콘크리트에 관한 기초적(基礎的) 연구(硏究))

  • Moon, Han Young;Choi, Jae Jin;Choi, Yun Wang
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.9 no.2
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    • pp.55-61
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    • 1989
  • This is a basic experimental research tried to use electric furnace slag as a fine aggregate for concrete. Chemical component and physical properties of electric furnace slag were studied, and expansion mechanism and aging method for stabalization of electric furnace slag were discussed. Concrete properties electric furnace slag as a fine aggregate were also studied in this paper.

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Physical and Chemical Properties of Chlorine Bypass System-Dust from Cement Manufacturing (시멘트 생산 시 발생하는 Chlorine Bypass System-dust의 물리 및 화학적 특성)

  • Han, Min-Cheol;Lee, Dong-Joo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.310-315
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    • 2019
  • This study conducted a series of studies to find alternative ways to use Chlorine Bypass System-dust(CBS-dust) in cement production. The results of engineering characteristics of CBS-dust are summarized as follows. First of all, the density of CBS-dust is 2.40, lighter than cement and the pH was 12.50 which was strong alkaline. In terms of particle size, it was 11.70 ㎛ which was finer than cement. With chemical properties, calcium oxide(CaO) was the highest as 35.10%, potassium oxide(K2O) was 32.43%, potassium chloride(KCl) was 19.46%, sulfur oxide(SO3) was 6.81%, and the remaining chemical components are SiO2, Fe2O3, Al2O3, MgO, and the like. Therefore, if CBS-dust is used as early-strength chemical admixtures in the concrete secondary products that use a large amount of mineral admixtures without rebar, it can be an effective method for increasing the strength of concrete as an alkali activator and preventing early-frost damage of Cold Weather Concrete.

Soil Physical and Chemical Properties of Kaolinite Opencast Mines and Adjacent Red Pine Forests in Sancheong-gun (산청군 고령토(백토) 노천 광산 채굴지와 인접 소나무 임분의 토양 물리·화학적 성질)

  • Kim, Kyung Tae;Baek, Gyeongwon;Choi, Byeonggil;Ha, Jiseok;Kim, Choonsig
    • Journal of Korean Society of Forest Science
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    • v.109 no.4
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    • pp.382-389
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    • 2020
  • Soil properties in opencast mines are a key factor in reclamation (revegetation) of mining areas. In this study we determined the soil physical and chemical properties of kaolinite tailings, reclaimed areas, and adjacent natural red pine (Pinus densiflora S. et Z.) forests in kaolinite opencast mines in Sancheong-gun, Gyeongsangnam-do. Six sites were chosen for collection of soil samples to determine soil physical and chemical properties at a soil depth of 10 cm. Soil bulk density was significantly higher (P < 0.05) in the kaolinite tailings (1.51 g·cm-3) than in the reclaimed areas (1.19 g·cm-3) and red pine forests (0.93 g·cm-3), whereas air phase in the kaolinite tailings (14.2%) was significantly lower than in the red pine forests (32.6%). Clay content in the red pine forests was significantly higher than in the reclaimed areas (18.7%) or kaolinite tailings (14.8%), whereas soil structural stability index was significantly lower in the reclaimed areas (1.61%) and kaolinite tailings (0.87%) than in the red pine forests (7.75%). Soil pH was significantly higher in the kaolinite tailings (pH 6.68) and reclaimed areas (pH 6.27) than in the red pine forests (pH 5.31). Soil organic carbon and total nitrogen were significantly higher in the red pine forests (C: 36.03 mg·g-1; N: 2.08 mg·g-1) than in the reclaimed areas (C: 5.00 mg·g-1; N: 0.31 mg·g-1) than in the kaolinite tailings (C: 2.12 mg·g-1; N: 0.07 mg g-1). The amount of available phosphorus was not significantly different among the three treatments. The concentration of exchangeable potassium was significantly lower in the kaolinite tailings (0.08 cmolc·kg-1) than in the reclaimed areas (0.21 cmolc·kg-1) and red pine forests (0.30 cmolc·kg-1). These results indicate that, because of high soil bulk density and low soil organic carbon, total nitrogen, available phosphorus, and exchangeable potassium in kaolinite tailings and reclaimed mining areas, soil nutrient management is needed in order to reclaim the vegetation in these type of areas.

Studies on the Morphological, Physical and Chemical Properties of the Korean Forest soil in Relation to the Growth of Korean White Pine and Japanese Larch (한국산림토양의 형태학적 및 이화학적성질과 낙엽송, 잣나무의 성장(成長)에 관한 연구(硏究))

  • Chung, In-Koo
    • Korean Journal of Soil Science and Fertilizer
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    • v.12 no.4
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    • pp.189-213
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    • 1980
  • 1. Aiming at supply of basic informations on tree species siting and forest fertilization by understanding of soil properties that are demanded by each tree species through studies of forest soil's morphological, physical and chemical properties in relation to tree growth in our country, the necessary data have been collected in the last 10 years, are quantified according to quantification theory and are analyzed in accordance with multi-variate analysis. 2. Test species, larch and the Korean white pine, are plantable in extensive areas from mid to north in the temperate zone and are the two most recommended reforestation tree species in Korea. However, their respective site demands are not known and they have been in confusion or considered demanding the same site during reforestation. When the Korean white pine is planted in larch sites, it has shown relatively good growth. But, when larch is planted in the Korean white pine site it can be hardly said that the larch growth is good. To understand on such a difference soil factors have been studied so as to see how the soil's morphological, physical and chemical factors affect tree growth helped with the electronic computer. 3. All the stands examined are man-made mature forests. From 294 larch plots and 259 white pine plots dominant trees are cut as samples and through stem analysis site index is determined. For each site index soil profiles are made in the related forest-land for analysis. Soil samples are taken from each profile horizon and forest-land productivity classification tables are worked out through physical and chemical analysis of the soil samples for each tree species for the study of relationships between physical, chemical and the combined physical/chemical properties of soil and tree growth. 4. In the study of relationships between physical properties of soil and tree growth it is found out that larch growth is influenced by the following factors in the order of deposit form, soil depth, soil moisture, altitude, relief, soil type, depth of A-horizon, soil consistency content of organic matter soil texture bed rock gravel content aspect and slope. For the Korean white pine the influencing factors' order is soil type, soil consistency bed rock aspect depth of A-horizon soil moisture altitude relief deposit form soil depth soil texture gravel content and slope. 5. In the study of relationships between chemical properties of soil and tree growth it is found out that larch growth is influenced by the following factors in the order of base saturation organic matter CaO C/N ratio, effective $P_2O_5$ PH.exchangeable $K_2O$ T-N MgO C E C Total Base and Na. For the Korean white pine the influencing factors' order is effective $P_2O_5$ Total Base T-N Na C/N ratio PH CaO base saturation organic matter exchangeable $K_2O$ C E C and MgO. 6. In the study of relationships between the combined physical and chemical properties of soil and tree growth it is found out that larch growth is influenced by the following factors in the order of soil depth deposit form soil moisture PH relief soil type altitude T-N soil consistency effective $P_2O_5$ soil texture depth of A-horizon Total Base exchangeable $K_2O$ and base saturation. For the Korean white pine the influencing factors' order is soil type soil consistency aspect effective $P_2O_5$ depth of A-horizon exchangeable $K_2O$ soil moisture Total Base altitude soil depth base saturation relief T-N C/N ratio and deposit from. 7. In the multiple regression of forest soil's physical properties larch's correlation coefficient is 0.9272 and for the Korean white pine it is 0.8996. With chemical properties larch has 0.7474 and the Korean white pine has 0.7365. So, the soil's physical properties are found out more closely related with tree growth than chemical properties. However, this seems due to inadequate expression of soil's chemical factors and it is proved that the chemical properties are not less important than the physical properties. In the multiple regression of the combined physical and chemical properties consisting of important morphological and physical factors as well as chemical factors of forest soils larch's multiple correlation coefficient is found out to be 0.9434 and for the Korean white pine it is 0.9103 leading to the highest correlation. 8. As shown in the partial correlation coefficients larch needs deeper soil depth than the Korean white pine and in the deposit form colluvial and creeping soils are demanded by the larch. Adequately moist to too moist should be soil moisture and PH should be from 5.5 to 6.1 for the larch. Demands of T-N soil texture and soil nutrients are higher for the larch than the Korean white pine. Thus, soil depth, deposit form, relief soil moisture PH N altitude and soil texture are good indicators for species sitings with larch and the Korean white pine while soil type and soil consistency are indicative only limitedly of species sitings due to their wide variation as plantation environments. For larch siting soil depth deposit form relief soil moisture PH soil type N and soil texture are indicators of good growth and for Korean white pine they are soil type soil consistency effective $P_2O_5$ and exchangeable $K_2O$, which is demanded more by the Korean white pine than larch generally. 9. Physical properties of soil has been known as affecting tree growth to greatest extent so far. However, as a result of this study it is proved through computer analysis that chemical properties of soil are not less important factors for tree growth than chemical properties and site demands for larch and the Korean white pine that have been uncertain So far could be clarified.

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Production of Asphalt Concrete Used Iron-and Steelmaking Slage as Fillers (철강슬래그를 충전제로 이용한 아스콘 제조(I))

  • Ban, Bong-Chan;Joo, Jae-Woo
    • Resources Recycling
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    • v.5 no.3
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    • pp.9-16
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    • 1996
  • The purpose of ths rescarch was to detcrmine a po\sihle application of the slag thc sliigs of iron-and steelmaking as afiller at asphalt concrete. The slags were crnshed for bcller recycling of lhree typical slags as ascon tiller. and thcn thcphysical and chemical properlies welt examincd The mechanical properliea of asphall cnncrete after filling with slagpowders under 200 mesh us fillers wcre tested to fulfill thc Korean Standnrds. Optimum tempcrafure of mixing the slagswith asphalt wils 140-160$^{\circ}$C. The density, the stabilily. gap ratio and the samration degree were 2.37 glcm', 810 kg. 3.4"'||'&'||'and 80.4%, respectively.tively.

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내연기관용 윤활유 첨가제의 국산화에 대한 연구

  • 김종호
    • Tribology and Lubricants
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    • v.3 no.2
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    • pp.15-22
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    • 1987
  • 윤활유는 일반적으로 윤활기유의 물성을 개량하기 위해 여러종류의 윤활유 첨가제를 포함하고 있는데 이 첨가제는 윤활기유가 가지고 있는 물성을 강화시키기 위해 첨가하는 것과 윤활기유에는 없는 물성을 얻기 위해 첨가하는 두가지로 나눌수 있다. 윤활기유의 산화분해, 열분해, 마찰이나 마모의 감소등을 위해 첨가흔 넉승 전자에 속하는 경우이고 기유 분해분의 침적을 막아주거나 부식을 방지하며 온도에 따른 점도변화를 극소화시키기 위한 첨가제는 후자에 해당한다. 즉 윤활유 첨가제는 윤활기유의 물리적, 화학적 성질을 보완 또는 강화시키므로서 윤활유로서의 소기의 목적을 달성하도록 첨가하는 화학물질을 말한다. 본 보에서는 위에서 열거한 여러종류의 첨가제 중 사용물량이 많아 수입대체 효과가 뚜렷한 6종의 첨가제의 국산화에 대한 연구결과를 간략하게 기술하였으며 앞으로 2회에 걸쳐 나누어 설명코자 한다.

Synthesis of Various Molecular Weight Polyaniline by Controlled Nucleation Site Number (핵심성장자리 수 조절을 통한 다양한 분자량을 갖는 폴리아닐린 합성)

  • Hong, Jang Hoo;Jang, Kwan Sik;Moon, Woo Yeon
    • Applied Chemistry for Engineering
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    • v.17 no.5
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    • pp.504-508
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    • 2006
  • Molecular weight of polyaniline is controlled in the range of oligomer to low molecular weight by controlling the ratio of aniline dimer (p-aminodiphenylamine) to monomer. Aniline dimers act as nucleation sites in chain growth during the polymerization of aniline. The molecular weights of polyanilines are estimated by GPS and relative viscosity measurement. The physical and chemical properties of polyanilines with various molecular weights are studied by UV-Vis, FT-IR, and electrical conductivity measurements.

Hair Strengthening Effect of Silane Coupling and Carbodiimide Chemistry (카르보디이미드 반응과 실란 커플링을 이용한 모발강화 효과)

  • Son, Seong Kil;Choi, Wonkyung;Lim, Byung Tack;Song, Sang-hun;Kang, Nae Kyu
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.44 no.2
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    • pp.133-139
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    • 2018
  • Chemically damaged hair is vulnerable to external stimuli in daily life due to the weakened physical properties of the hair strand itself. The purpose of this work was to determine whether chemical conjugation between hair keratin proteins restores tensile strength and thus results inpreventing further deterioration under repeated combing. A model damaged hair tress was produced by a typical perm-process. Then, it was internally crosslinked by the bifunctional crosslinker (3-aminopropyl)triethoxysilane (APTES), via both silane coupling and carbodiimide chemistry. Physical properties, including tensile strength, Young's modulus, and plateau stress, were measured to verify the effect of internal crosslinking, and the existence of crosslinking was verified by Fourier transform infrared (FT-IR) spectroscopy. The degrees of hair breakage and split ends were evaluated by repeated combing-drying tests. Physical properties of chemically damaged hair were restored by internal crosslinking. Successful crosslinking of APTES via both silane coupling and carbodiimide chemistry was verified by FT-IR spectra. Prevention of breakage and split ends after repeated combing with heat was observed. Human hair can be weakened by chemical damage including perm-processing, so restoring such properties is a major issue in the hair care industry. This work shows that internal crosslinking of damaged hair via chemical conjugation would be a potent method to restore the healthy hair.