• Journal of the Korean Chemical Society
• /
• v.18 no.1
• /
• pp.50-57
• /
• 1974

A practical method applicable to the synthesis of aromatic dihydrazines was proposed by reducing tetrazonium salt in strong mineral acid media. By diazotizing p-phenylenediamine with sodium nitrite in a medium of concentrated hydrochloric acid or 45 % perchloric acid at $-5 {\sim} -10{\circ}C$ and reducing the tetrazonium salt with stannous chloride, p-phenylenedihydrazine (PPDH) was separated in the form of hydrochloride as colorless fine needles. Since PPDH was subject to oxidation and unstable, the free base could not be isolated. PPDH${\cdot}$2HCl was decomposed at $^180{\circ}C$ without showing sharp melting point. It behaved largely as aromatic monohydrazines, and reacted immediately with aldehydes and ketones in acetate buffer, giving generally yellow to brownish condensation products, dihydrazones. This suggests that PPDH will react with dicarbonyl compounds producing high molecular polymers or cyclization products.

• Journal of Korea Port Economic Association
• /
• v.25 no.1
• /
• pp.271-292
• /
• 2009

Opening and regional economic integration are characteristic of global economic trends that have been made since the 1990s. Accordingly, all economic blocs of the world are largely reorganized into three poles, European Economic Bloc, American Economic Bloc and Northeast Asian Economic Block which are respectively led by EU, the United States and the rapidly emerging economic power, China. Considering this direction of global economy, the current status of Northeast Asia, China's unprecedentedly enormous port development project and Japan's introduction of an epoch-making port policy towards the restoration of its port competitiveness, Korea is urgently need to take its own initiatives and positive actions that can cope with the above situations. The purpose of this study is to propose ways of strategic cooperation for Korea-Japan joint development. For the purpose, this researcher provides the concept and preconditions of hub-port, investigates hub-port development strategies of rival companies in Northeast Asia and discusses the potential of the development of the Korea-Japan Strait Economic Zone which is located between Busan port and Japan's Honshu(Simonoseki port) and Kyushu(Kitakyushu port).

• Transactions of the Korean hydrogen and new energy society
• /
• v.27 no.3
• /
• pp.290-297
• /
• 2016

The absorbent loss due to degradation in $CO_2$ capture process using aqueous alkanol amine solution has adverse effect on the economics of overall process. The degradation causes absorbent loss, equipment corrosion, foaming, adhesive material producing and viscosity increase in operation. In this study, the degradation characteristics of $CO_2$ capture process using MEA (monoehtanolamine) under various conditions such as $O_2$ partial pressure, $CO_2$ loading and absorbent temperature. The effects of iron, which generated from the equipment corrosion, on absorbent degradation were studied using $Fe_2SO_4$ containing MEA solution. The produced gases were analyzed by FT-IR(Fourier Transform Infrared Spectrophotometer) and the specifically measured $NH_3$ concentration was used as a degradation degree of aqueous MEA solution. The experiments showed that the higher $CO_2$ loadings (${\alpha}$), $O_2$ fraction ($y_{O2}$) and reaction temperature enhanced the more degradation of aqueous MEA solution. Comparing other operation parameters, the reaction temperature most affected on the degradation. Therefore, it could be concluded that the above parameters affects on degradation should be considered for the selections of $CO_2$ absorbent and operating conditions.

• The Journal of Korean Institute of Communications and Information Sciences
• /
• v.28 no.8A
• /
• pp.633-643
• /
• 2003

UWB impulse radio signals have an very short duration, extremely wide bandwidth and share the same frequency spectrum with other existing systems. It was determined by the Federal Communications Commission (FCC) that UWB systems could cause interference with other systems, such as Global Positioning System (GPS) for example. Therefore, at present. the FCC has restricted the use of UWB systems to frequencies above 3.1㎓. In this paper, We evaluated performance of UWB system using proposed pulses in ［1］［2］ that are strictly limited in time to remove interference while, at the same time, contain their power distribution to a frequency band from 3.1㎓ to 10.6㎓. In particular, We evaluated the BER Performance in relation to system parameters such as pulse duration. $\delta$, the number of users. Nu. and the number of symbols, M. We found the optimal pulse duration $\delta$ through computer simulation using developed UWB pulses in ［1］［2］. It is shown that performance evaluation between the UWB communication system using these UWB pulses ［1］［2］and the Gaussian monocycle pulse in M-ary PPM and BPSK schemes. These results can be contributed to construct M-ary PPM UWB communication system in terms of multiuser parameters and pulse duration.

• The Journal of Korean Institute of Communications and Information Sciences
• /
• v.40 no.1
• /
• pp.1-8
• /
• 2015

In this paper, a double-input single-output architecture of a LNA(Low Noise Amplifier) is presented to enable to be devised for light weight and small-sized OTM(On-The-Move) satellite communication system suitable to be mounted on vehicles. In spite of advantages of the double-input single-output architecture of a LNA such as reduction of the number of physical channels, it results in time-varying phase error between a fundamental mode path and a high-order mode path. This paper shows that the error can be corrected by adding pilot signals to the LNA and using signal processing, and also gives the measurement data to use the method mentioned above.

• The Journal of Korean Institute of Communications and Information Sciences
• /
• v.33 no.3A
• /
• pp.311-318
• /
• 2008

We propose new pulse shapes for FCC-compliant ultra-wideband (UWB) radios. The projections onto convex sets (POCS) technique is used to optimize temporal and spectral shapes of UWB pulses under the constraints of all of the desired UWB signal properties: efficient spectral utilization under the FCC spectral mask, time-limitedness, and good autocorrelation. Simulation results show that for all values of the pulse duration, the new pulse shapes not only meet the FCC spectral mask most efficiently, but also have nearly the same autocorrelation functions. It is also observed that our truncated (i.e., strictly time-limited) pulse shapes outperform the truncated Gaussian monocycle in the BER performance of binary TH-PPM systems for the same pulse durations. The POCS technique provides an effective method for designing UWB pulse shapes in terms of its inherent design flexibility and joint optimization capability.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
• /
• v.20 no.3
• /
• pp.230-239
• /
• 2009

In this paper, we propose a novel on-glass antenna for FM radio reception in a recreation vehicle(RV). We use a multi-loop structure that takes advantage of a broad matching bandwidth and a high vertical radiation gain by efficiently utilizing a given space of a quarter glass in spite of the simple planar structure. Transparency of the antenna is also improved by adjusting the stripline widths based on the induced current distributions. The proposed antenna is printed on a quarter glass of a commercial vehicle and antenna performances such as the return loss and the gain are measured in a semi-anechoic chamber. The result shows the average gain of -9.67 dBi along the bore-sight direction($\theta=90^{\circ}$, $\phi=270^{\circ}$) in the FM radio band(80$\sim$l10 MHz), which is higher than a commercial monopole typed on-glass antenna($G_{ave}$=-12.49 dBi) and micro-antenna($G_{ave}$=-19.24 dBi) mounted on the roof of the RV.

• Korean Journal of Food Science and Technology
• /
• v.29 no.6
• /
• pp.1131-1137
• /
• 1997

The production rates of leavening gases and textures of cookies were investigated with various chemical leavening agents(baking powders). The chemical leavening agents could be divided into three group of a fast-acting group such as potassium bicarbonate, tartaric acid, aluminium ammonium sulfate, and fumaric acid, a slow-acting group such as ammonium bicarbonate, sodium bicarbonate, $glucono-{\delta}-lactone$, and ammonium chloride. and a double-acting group such as anhydro monocalcium phosphate, disodium dihydrogenpyrophosphate, and aluminium potassium sulfate according to the different production rate of gases. The leavening rate of ammonium bicarbonate, which was the highest of all leavening agents used in this experiment, was 131.25%. But its after-taste in a cookie was not good due to the residual ammonia. $Glucono-{\delta}-lactone$ only had no after-taste. The higher leavening rate, the more peaks in texture profile graph. Ammonium bicarbonate showed the most peaks in this experiment. It was found that the number of peak had correlation with brittleness of cookies $(r^2=0.8176)$ and brittleness of cookies was different as to various chemical leavening agents.

• Journal of the Korea Institute of Information and Communication Engineering
• /
• v.18 no.2
• /
• pp.268-275
• /
• 2014

In this paper, a dual-band circular ring monopole antenna with stub and ground slot for WLAN(Wireless Local Area Networks)/WiMAX(World interoperability for Microwave Access) applications. The proposed antenna is based on a planar monopole design, and composed of one circular ring of radiating patch, cross strip in circular ring, modified feed line, and two rectangular slot in the ground plane for triple-band operation. To obtain the optimized parameters, we used the simulator, Ansoft's High Frequency Structure Simulator(HFSS) and found the parameters that greatly effect antenna characteristics. Using the obtained parameters, the antenna is fabricated. The numerical and experiment results demonstrated that the proposed antenna satisfied the -10 dB impedance bandwidth requirement while simultaneously covering the WLAN and WiMAX bands. And characteristics of gain and radiation patterns are determined for WLAN/WiMAX application.

• Journal of Navigation and Port Research
• /
• v.39 no.6
• /
• pp.473-478
• /
• 2015

In this paper, we suggest a flexible multiband antenna which can be equipped on an inflatable life-jacket. The antenna can send distress alert and location data of survivors to assist rescue operation when crew or people are in distress. The antenna operate in three frequency bands such as VHF-DSC band (156MHz), COSPAS-SARSAT band (406MHz) and GPS band (1,575MHz). The GPS band is implemented with a square ring-slot planar antenna, the COSPAS-SARSAT band and the VHF-DSC band antenna is implemented by monopole type. In order to give flexibility of substrate to be equipped on life-jacket, FR4-epoxy substrate of thickness 0.2mm is used to make antenna. The reflection coefficients of the fabricated antenna are -8.8dB, -20.4dB and -10.7dB at each bandwidth like VHF-DSC, COSPAS-SARSAT and GPS band, respectively, when people are wearing life-jacket integrated multiband antenna.