• Title/Summary/Keyword: 메탄 배출가스

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Closed Static Chamber Methods for Measurement of Methane Fluxes from a Rice Paddy: A Review (벼논 메탄 플럭스 측정용 폐쇄형 정적 챔버법: 고찰)

  • Ju, Okjung;Kang, Namgoo;Lim, Gapjune
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.22 no.2
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    • pp.79-91
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    • 2020
  • Accurate assessment of greenhouse gas emissions is a cornerstone of every climate change response study, and reliable assessment of greenhouse gas emission data is being used as a practical basis for the entire climate change prediction and modeling studies. Essential, fundamental technologies for estimating greenhouse gas emissions include an on-site monitoring technology, an evaluation methodology of uncertainty in emission factors, and a verification technology for reductions. The closed chamber method is being commonly used to measure gas fluxes between soil-vegetation and atmosphere. This method has the advantages of being simple, easily available and economical. This study presented the technical bases of the closed chamber method for measuring methane fluxes from a rice paddy. The methane fluxes from rice paddies occupy the largest portion of a single source of greenhouse gas in the agricultural field. We reviewed the international and the domestic studies on automated chamber monitoring systems that have been developed from manually operated chambers. Based on this review, we discussed scientific concerns on chamber methods with a particular focus on quality control for improving measurement reliability of field data.

Energy Balance and Methane Production of Hanwoo Cows Fed Various Kind of Roughage (다양한 조사료 급여조건에서 한우 암소 경산우의 에너지분배 및 메탄배출량)

  • Oh, Young Kyoon;Kim, Do Hyung;Moon, Sang Ho;Park, Jae Hyun;Nam, In Sik;Arokiyaraj, Selvaraj;Kim, Kyoung Hoon
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.34 no.4
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    • pp.283-287
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    • 2014
  • This experiment was conducted to determine methane production and emission factors for a range of roughage diets fed to Hanwoo cows at a level of maintenance energy requirement. Seven cows were fed mixed hay only, 12 cows were fed mixed hay containing 30~50% rice straw and 6 cows were fed a mixed hay diet supplemented with 1.0 kg of wheat bran. Each cow was placed in a metabolic crate for 10 consecutive days, including last 7 days for sampling of feces and urine. At the end of the sampling period, the cows were transferred to an open-circuit respiration chamber for 24 consecutive hours. Methane conversion rate (5.5~6.2%, mean value = 5.8%) and emission factor (33.6~38.6 kg/head/year, mean value = 35.2) were not significantly affected by the diets although the mixed hay only diet resulted in 11 and 15% higher respective rates than the other two. However, in light of the many assumptions that forage with good quality might reduce methane production, additional experiments should be required for participation in the greenhouse gas emission trading system.

Emission of Greenhouse Gases from Upland Rice and Soybean (밭벼와 콩 재배지의 온실가스 배출)

  • Shin, Yong-Kwang;Ahn, Jong-Woong;Koh, Mun-Hwan;Shim, Jae-Chun
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.4
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    • pp.256-262
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    • 2003
  • The emission of methane and nitrous oxide was measured from fields of upland rice and soybean. Rice cultivar, Daejinbyeo, was seeded in a row of 30 cm space in upland soil on April 28, 2001. The fields were irrigated with sprinkler irrigation or natural precipitation. Three soybean cultivars Jangyeobkong, Taekwangkong and Hwangkeumkong, were sown with seeding space of $60{\times}15cm$ on June 16, 2001. Gas samples were collected twice a week during the growth period, and methane and nitrous oxide were analyzed. Methane emission from upland rice field of sprinkler irrigation was $3.5kg\;CH_4\;ha^{-1}$. However, negative emission of methane, $-1.7kg\;CH_4\;ha^{-1}$, was observed in upland rice field of natural precipitation. Total nitrous oxide emission from upland rice field of sprinkler irrigation was $50.8kg\;N_2O\;ha^{-1}$, while the emission in the field of natural precipitation was $8.3kg\;N_2O\;ha^{-1}$. Global warming potentials (GWP) in the upland rice fields of sprinkler irrigation and natural precipitation were 15,822 and $2,216kg\;CO_2\;ha^{-1}$, respectively. Methane emissions from fields of soybean cultivars Jangyeobkong, Taekwangkong and Hwangkeumkong were -14.7, -4.3 and $4.8kg\;CH_4\;ha^{-1}$, respectively. Total nitrous oxide emissions from fields of soybean cultivars Jangyeobkong, Taekwangkong and Hwangkeumkong were 4.7, 4.6 and $3.0kg\;N_2O\;ha^{-1}$, respectively. Total GWPs for soybean cultivars Jangyeobkong, Taekwangkong and Hwangkeumkong were 1152, 1323 and $1027kg\;CO_2\;ha^{-1}$, respectively.

Estimation of Biomass Loss and Greenhouse Gases Emissions from Surface Layer Burned by Forest Fire (산불로 인한 지표층 연소량 및 온실가스 배출량 추정)

  • Lee, Byungdoo;Youn, Ho Jung;Koo, Kyosang;Kim, Kyongha
    • Journal of Korean Society of Forest Science
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    • v.101 no.2
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    • pp.286-290
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    • 2012
  • Globally, the forest fires are a significant contributor of carbon dioxide and other greenhouse gases in the atmosphere. In this study, fuel load consumed by forest fire and emission of green house gases were analysed in the surface layer. For this, remaining fuel was collected and weighed with the species (Japanese red pine, deciduous) and the forest fire types (surface fire, crown fire) in the 51 forest fires. 8,361 kg/ha fuel load was consumed in deciduous forest damaged by surface fire, and 8,055 kg/ha, 12,333 kg/ha in Japanese red pine burned by surface fire and crown fire. The combustion ratios were 78, 59, and 90%, respectively. 15,856 kg/ha the green house gases such as $CO_2$, $CH_4$, $CH_4$ in deciduous forest burned by surface fire was emitted and 14,834 kg/ha, 22,709 kg/ha in Japanese red pine burned by surface fire and crown fire.

Improvement Method for the Post-Management End System of a Landfill by Applying Total Pollutant Load Concept (오염총량 개념을 적용한 매립장 사후관리종료제도 개선 방안)

  • Chun, Seung-Kyu;Sim, Nak-Jong;Jeon, Eun-Jeong;Ryu, Don-Sik
    • Journal of the Korean GEO-environmental Society
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    • v.22 no.2
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    • pp.15-23
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    • 2021
  • A method of improving the post-management end system of a landfill that reflected total pollutant load was applied to the SUDOKWON 1st Landfill Site. Modeling results showed that the ratio of remaining methane, when compared to the total maximum potential of 2,521 × 106 Nm3, was estimated to be 8.8% in 2020, 7.0% in 2030, and 6.5% in 2040. If the average oxidation rate of 89.1% in 2005-2019 was applied, the ratio decreased by 1.01% in 2020, 0.76% in 2030, and 0.70% in 2040. This suggests that if the amount of methane generated is all emitted from the surface of the landfill after 2025, the real amount emitted to the atmosphere is less than that in 2019; therefore, the post-management end is possible. According to the results of trend analysis of the quality of leachate water, effluent criteria for Biochemical Oxygen Demand (BOD) can be satisfied in 2024, while those for Chemical Oxygen Demand (COD) and Total Nitrogen (T-N) can be satisfied in 2047 and 2117, respectively. If the post-management end system changed based on total pollutant load, the post-management can be terminated BOD today and COD within a few years; however, the fact that T-N could be terminated only after 2041 shows the need to fundamentally change management methods.

Simultaneous Reduction of CH4 and NOx of NGOC/LNT Catalysts for CNG buses (CNG 버스용 NGOC/LNT 촉매의 CH4와 NOx의 동시 저감)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.6
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    • pp.167-175
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    • 2018
  • Natural gas is a clean fuel that discharges almost no air-contaminating substances. This study examined the simultaneous reduction of $CH_4$ and NOx of NGOC/LNT catalysts for CNG buses related to the improvement of the $de-CH_4/NOx$ performance, focusing mainly on identifying the additive catalysts, loading of the washcoat, stirring time, and types of substrates. The 3wt. % Ni-loaded NGOC generally exhibited superior $CH_4$ reduction performance through $CH_4$ conversion, because Ni is an alkaline, toxic oxide, and exerts a reducing effect on $CH_4$. A excessively small loading resulted in insufficient adsorption capacity of harmful gases, whereasa too high loading of washcoat caused clogging of the substrate cells. In addition, with the economic feasibility of catalysts considered, the appropriate amount of catalyst washcoat loading was estimated to be 124g/L. The NOx conversion rate of the NGOC/LNT catalysts stirred from $200^{\circ}C$ to $550^{\circ}C$ for 5 hours showed 10-15% better performance than the NGOC/LNT catalysts mixed for 2 hours over the entire temperature range. The NGOC/LNT catalysts exhibitedapproximately 20% higher $de-CH_4$ performance on the ceramic substrates than on the metal substrates.

A Study on the Production Well Spacing Design Considering Coalbed Depth in Coalbed Methane Reservoirs (석탄층 메탄가스 저류층에서 탄층 심도를 고려한 생산정 간격 설계 연구)

  • Chayoung Song;Dongjin Lee;Jeonghwan Lee
    • Journal of the Korean Institute of Gas
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    • v.27 no.3
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    • pp.98-107
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    • 2023
  • This study presents a well spacing design for coalbed methane(CBM) reservoirs using the experimental results of methane gas adsorption measurement of coal samples obtained from North Kalimantan Island, Indonesia. The gas productivity analysis shows that the cumulative gas production increases as the Langmuir volume increases. This indicates that the maximum gas adsorption directly affects the gas production. In addition, the maximum gas production increases with the increase of reservoir permeability, and the dewatering period is shortened. In particular, the cumulative gas production increases as the production influence area increases. However, when comparing productivity per unit well, the maximum cumulative gas production is found between 2,000 ft of depth and 80-160 acres of the influence area. When reservoir depth and production influence area are considered simultaneously, the results of the appropriate well depth and spacing calculations show that gas productivity is highest between 600-2,000 ft. In this case, it is appropriate to design well spacing in the range of 80-160 acres. Therefore, well spacing design considering coalbed depth in undeveloped CBM reservoirs can be accomplished using gas sorption test results from coal samples.

A Performance Analysis of a Spark Ignition Engine Using Gasoline, Methanol and M90 by the Thermodynamic Second Law (가솔린, 메탄올, M90 연료를 사용한 전기점화기관에서의 열역학 제 2법칙적 성능해석)

  • Kim, S.S.
    • Journal of Power System Engineering
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    • v.13 no.6
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    • pp.22-28
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    • 2009
  • 열역학 제 2법칙의 관점의 열역학적 가용에너지인 엑서지 해석법을 적용하여 가솔린, 메탄올, M90 연료를 사용한 전기점화 기관의 성능해석을 수행하였다. 열역학적 사이클 해석을 위하여 사이클을 구성하는 각 과정은 열역학적 모델로 단순화하였고, 크랭크 각도에 따른 실린더의 압력과 작동유체를 구성하는 연료, 공기 및 연소생성물의 열역학적 물성 값들을 이용하여 각 과정에서의 엑서지와 손실 일을 계산하였다. 실험데이터는 단기통 전기점화기관을 가솔린, 메탄올과 M90(메탄을 90%+부탄 10%의 혼합연료)을 연료로 WOT(Wide Open Throttle), MBT(Minimum advanced spark timing for Best Torque), 2500rpm 조건으로 운전하여 측정하였다. 계산에 이용한 자료는 실험으로 측정한 크랭크 각도에 따른 연소실의 압력, 흡입공기와 연료유량, 흡입공기 온도, 냉각수 온도와 배출가스 온도 등이다. 이를 이용하여 각 과정에서의 엑서지와 손실 일을 계산하였으며 각 과정에서의 손실 일은 연소과정에서 가장 크며 팽창과정, 배출과정, 압축과정 및 흡입과정 순으로 크게 나타났다.

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Measurements of Gases Emissions from Agricultural Soils and Their Characteristics with Chamber Technique : Emission of NO and $N_{2}O$ (챔버를 이용한 농작지로부터의 기체배출량 측정과 배출특성 연구 : 일산화질소(NO)와 아질산가스($N_{2}O$)의 배출량산정)

  • 김득수;오진만;고현석;두강진
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.225-228
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    • 2000
  • 대류권내에 존재하는 질소산화물(NO$_{y}$ )은 지구대기의 대기화학변화에 매우 중요한 역할을 한다. NO$_{x}$는 대류권 하층에서 광화학 과정에 관여하여 탄화수소와 함께 오존(O$_3$)을 포함한 광화학스모그를 발생시키는 역할을 한다. 또한 질소산화물 중 아산화질소($N_2$O)는 매우 안정한 기체로서 NO$_{x}$처럼 대류권내에서 활발한 화학 반응에 관여하지는 않지만, 메탄(CH$_4$), 이산화탄소($CO_2$), 오존(O$_3$) 등과 함께 지구온난화에 기여하는 온실기체로서 지구기후변화와 밀접하게 연관되어 있다. (중략)

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Evaluation of Mitigation Technologies and Footprint of Carbon in Unhulled Rice Production (벼 생산 단계에서 탄소발생량과 감축요소 평가)

  • Lee, Deog Bae;Jung, Soon Chul;So, Kyu Ho;Jeong, Jae Woo;Jung, Hyun Chul;Kim, Gun Yeob;Shim, Gyo Moon
    • Journal of Climate Change Research
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    • v.3 no.2
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    • pp.129-142
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    • 2012
  • This study was carried out to evaluate carbon footprint during unhulled rice production and to compare mitigation technologies of methane, main carbon source during rice production, Carbon footprint of unhulled rice was a sum of $CO_2$ emission of agri-materials manufacture, rice cultivation and waste treatment. It was emitted 1.40 kg $CO_2$ during unhulled rice production, its distribution was 71.1% by $CH_4$ emission of rice cultivation, 11.8% of $N_2O$ emission by nitrogen application and 7.6% of complex fertilizer manufacture. $CH_4$ emission could be mitigated by some technologies; cultivation of the early maturing rice variety emitted lower by 44.4% than the mid maturing variety, intermittent drainage of submerged water by 43.8% than the continuous flooding condition, direct seeding by 32.0% than transplanting cultivation, no-ploughing by 20.9% than ploughing cultivation. It means that LCA on Global Warming Potential and the statistical data on innovated technical practice are key tools to systemize Measurable-Reportable-Verifiable (MRV) system for carbon footprint and carbon emission trade in the farm base.