• Title/Summary/Keyword: 메탄 배출가스

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Numerical Study of Combustion Characteristics and NO Emission in Swirl Premixed Burner (스월 예혼합 버너의 연소 특성 및 NO 배출에 관한 수치적 연구)

  • Baek, Gwang Min;Cho, Cheon Hyeon;Cho, Ju Hyeong;Kim, Han Seok;Sohn, Chae Hoon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.10
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    • pp.911-918
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    • 2013
  • The combustion characteristics of an EV (Environmental Vortex) burner (double-cone burner) adopted in a gas turbines are numerically investigated. The mixing of fuel and air is analyzed for reduction of NO emission. To predict the correlation between NO emission and fuel-air mixedness, 1-step and 2-step chemistry models are adopted. The results calculated by 1-step chemistry showed that NO emissions increased by 2% in the case of degraded mixedness and by 169% in the case of improved mixedness, where the temperature in the flame zone was overestimated upstream of the cone. However, the corresponding results calculated by 2-step chemistry showed that NO emission increased by 3% and decreased by 5%, where the flame zone was not formed inside the cone. The latter results agree well with the experimental ones indicating an increase of 63% and decrease of 11% in the respective cases. Despite quantitative errors, NO emissions can be predicted reasonably by the application of the 2-step chemistry model adopted here and design modification of burner for NO reduction can be proposed based on the numerical data.

Hydrogen Sulfide Removal of Biogas from Sewage Treatment Plant with Micro-bubble Generation System (마이크로버블 장치를 이용한 하수처리장 바이오가스의 황화수소 제거)

  • Jung, Jae-Ouk;Jung, Yong-Jun
    • Journal of Wetlands Research
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    • v.22 no.4
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    • pp.239-244
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    • 2020
  • Prior to utilization of energy and power generation, the biogas from anaerobic digestion of sewage treatment plant(46,000㎡/d) should be purified particularly hydrogen sulfide among the various kinds of impurities. This study has focused on the methane decreasing rate and the removal of both hydrogen sulfide and carbon dioxide. In the case of partial circulation, 59.7% of methane gas was decreased to 57.4% in spite of oxidation process with micro-bubble. Carbon dioxide was removed from 38% to 32% and 76.1% of hydrogen sulfide was removed where 1,400ppm was introduced to the DIWS system, which indicated that DIWS system can be of use for the hydrogen sulfide removal of biogas from sewage treatment plant.

LCA on Lettuce Cropping System by Top-down Method in Protected Cultivation (시설상추 생산체계에 대한 top-down 방식 전과정평가)

  • Ryu, Jong-Hee;Kim, Kye-Hoon;So, Kyu-Ho;Lee, Gil-Zae;Kim, Gun-Yeob;Lee, Deog-Bae
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1185-1194
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    • 2011
  • This study was carried out to estimate carbon emission using LCA (Life Cycle Assessment) and to establish LCI (Life Cycle inventory) DB for lettuce production system in protected cultivation. The results of data collection for establishing LCI DB showed that the amount of fertilizer input for 1 kg lettuce production was the highest. The amounts of organic and chemical fertilizer input for 1 kg lettuce production were 7.85E-01 kg and 4.42E-02 kg, respectively. Both inputs of fertilizer and energy accounted for the largest share. The amount of field emission for $CO_2$, $CH_4$ and $N_2O$ for 1 kg lettuce production was 3.23E-02 kg. The result of LCI analysis focused on GHG (Greenhouse gas) showed that the emission value to produce 1 kg of lettuce was 8.65E-01 kg $CO_2$. The emission values of $CH_4$ and $N_2O$ to produce 1 kg of lettuce were 8.59E-03 kg $CH_4$ and 2.90E-04 kg $N_2O$, respectively. Fertilizer production process contributed most to GHG emission. Whereas, the amount of emitted nitrous oxide was the most during lettuce cropping stage due to nitrogen fertilization. When GHG was calculated in $CO_2$-equivalents, the carbon footprint from GHG was 1.14E-+00 kg $CO_2$-eq. $kg^{-1}$. Here, $CO_2$ accounted for 76% of the total GHG emissions from lettuce production system. Methane and nitrous oxide held 16%, 8% of it, respectively. The results of LCIA (Life Cycle Impact assessment) showed that GWP (Global Warming Potential) and POCP (Photochemical Ozon Creation Potential) were 1.14E+00 kg $CO_2$-eq. $kg^{-1}$ and 9.45E-05 kg $C_2H_4$-eq. $kg^{-1}$, respectively. Fertilizer production is the greatest contributor to the environmental impact, followed by energy production and agricultural material production.

Observation of Methane Flux in Rice Paddies Using a Portable Gas Analyzer and an Automatic Opening/Closing Chamber (휴대용 기체분석기와 자동 개폐 챔버를 활용한 벼논에서의 메탄 플럭스 관측)

  • Sung-Won Choi;Minseok Kang;Jongho Kim;Seungwon Sohn;Sungsik Cho;Juhan Park
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.25 no.4
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    • pp.436-445
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    • 2023
  • Methane (CH4) emissions from rice paddies are mainly observed using the closed chamber method or the eddy covariance method. In this study, a new observation technique combining a portable gas analyzer (Model LI-7810, LI-COR, Inc., USA) and an automatic opening/closing chamber (Model Smart Chamber, LI-COR, Inc., USA) was introduced based on the strengths and weaknesses of the existing measurement methods. A cylindrical collar was manufactured according to the maximum growth height of rice and used as an auxiliary measurement tool. All types of measured data can be monitored in real time, and CH4 flux is also calculated simultaneously during the measurement. After the measurement is completed, all the related data can be checked using the software called 'SoilFluxPro'. The biggest advantage of the new observation technique is that time-series changes in greenhouse gas concentrations can be immediately confirmed in the field. It can also be applied to small areas with various treatment conditions, and it is simpler to use and requires less effort for installation and maintenance than the eddy covariance system. However, there are also disadvantages in that the observation system is still expensive, requires specialized knowledge to operate, and requires a lot of manpower to install multiple collars in various observation areas and travel around them to take measurements. It is expected that the new observation technique can make a significant contribution to understanding the CH4 emission pathways from rice paddies and quantifying the emissions from those pathways.

Countermeasures to the Introduction of Low Caloric Gas Fuel for Natural Gas Engine (저열량 가스 적용에 따른 천연가스엔진의 대응 방안 연구)

  • Park, Cheol-Woong;Kim, Chang-gi;Oh, Se-Chul;Lee, Jang-Hee
    • Journal of the Korean Institute of Gas
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    • v.25 no.2
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    • pp.34-41
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    • 2021
  • In order to cope with the problems that may occur when the natural gas used in Korea becomes low in calories, the problems that may have to the domestic industrial gas equipment must be identified in advance, and based on this, countermeasures for efficient use of energy must be preceded. In this study, in order to solve the problem of deterioration of engine output performance and efficiency due to the introduction of low calorific gas when using a lean-burning natural gas engine that complies with the EURO-6 regulation, specific control plans and results based on the experiment are intended to be presented. In order to identify the improvement effect by the control variable represented by the ignition timing under the full load condition at the engine speed of 1,400 rpm and 550 Nm, 2,100 rpm, which is the engine speed at the rated operation condition, the thermal efficiency and exhaust gas characteristics were identified and optimized by changing the ignition timing for each gas fuel. In the case of pure methane, which shows the lowest value based on the torque under the full load condition, if the ignition timing is advanced by about 2 CAD from the reference ignition timing, the torque can be compensated without a large increase in NOx emission.

A study on characteristics of SOFC/GT system for the supply gas flow rates (공급가스 유량에 따른 SOFC/GT 시스템 특성에 관한 연구)

  • Park, Sang-Kyun;Lee, Joo-Hee;Park, Geong-Dae;Choi, Jae-Hyuk
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.7
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    • pp.765-772
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    • 2015
  • In this research, the characteristics of SOFC/GT (Solid Oxide Fuel Cell/Gas Turbine) system temperature, stack power and system efficiency for flow rates of air, CH4 and water supplied to SOFC stack have been investigated. The temperature of the gas supplied to cathode and anode of SOFC stack in the SOFC/GT system are maintained by utilizing exhaust gas without the addition of external heat source. As a result, within the scope of this study, temperatures of gas supplied to cathode and anode of SOFC stack were maintained at 1000 (K) by utilizing the exhaust gas of the SOFC/GT system without the addition of external heat source. The system efficiency is increased with increase of air flow rate supplied to the stack and with decrease of $CH_4$ flow rate supplied to the stack. In addition, it can be found that the flow rate of the exhaust gas supplied to the turbine had a significant effect on the system efficiency. And the efficiencies of SOFC stack and SOFC/GT system depending upon various operating conditions of the SOFC/GT system is 51~57% and 57~73%, respectively.

A Study on Anaerobic Treatment and Energy Recovery Technology of Food Waste by Using Hybrid Anaerobic Reactor (Hybrid Anaerobic Reactor를 이용한 음식물쓰레기의 혐기성처리 및 에너지 회수에 관한 연구)

  • Yoon Young-Bong;Park Jin-Young;Ju Jin-Young;Kim Myung-Ho
    • Journal of environmental and Sanitary engineering
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    • v.20 no.1 s.55
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    • pp.64-75
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    • 2005
  • The total production of food waste was about 11,398ton/day('03) in Korea. Also, food waste was treated by landfill, incineration, reuse and anaerobic digestion. The method of food waste treatment depended primarily on landfill. However, the method of landfill causing social problems was prevented to treat food waste in the first of January 2005.12) Thus, anaerobic digestion is an important method to treat food waste because of possibility of energy recovery as methane gas. In this study, the possibility of food waste treatment containing high organic material and low pH in the one stage anaerobic reactor to save cost and time and energy recovery using $CH_{4}$ gas by the hybrid anaerobic reactor (HAR) was measured. The HAR was designed by combing the merits of the anaerobic filter (AF) to minimize the microorganism shock when food waste of very low pH was injected and up-flow anaerobic sludge blanket (UASB) to prevent from plugging and channeling phenomena by large suspended solids when semi solids were injected. Granule was packed in the section of HAR. The purpose of the BMP experiment was to measure the amount of methane generated when organic material was resolved under anaerobic conditions, to grasp bio resolution of organic material. Total accumulated methane production per VS amount was $0.471(m^{3}/\cal{kg}\;VS)$. So, the value was about $81.2\%$ of theoretical methane production which was $0.58(m^{3}/\cal{kg}\;VS)$ by elementary analysis and organic matter removal velocity (K) was $0.18(d^{-1})$. From these results, food waste was treated by anaerobic treatment. From this study, $CH_{4}$ generation from food waste (11,398 ton/day) could be estimated. By using an energy conversion factor of Braun's study, $5.97KWh/m^{3}\;CH4,\;60\%\;of\;CH_{4}$ gas generation, the amount of total energy producing food waste is to 6,727MWh/day. It could be confirmed that energy recovery using $CH_{4}$ gas was possible. Above these results, food waste containing organic matters of high concentration could be treated in HRT 30 days under an anaerobic condition, using the hybrid anaerobic reactor and reuse of $CH_{4}$ gas was possible.

A Study on Performance of Solid Oxide Fuel Cell Stack for Ship Applications (선박 전원용 고체산화물형 연료전지(SOFC) 스택 성능에 관한 연구)

  • Park, Sang-Kyun;Kim, Young-Jin;Roh, Gill-Tae;Kim, Mann-Eung
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.4
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    • pp.406-413
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    • 2011
  • Recently the fuel cell has been spotlighted as a technology to reduce greenhouse gases emission from a ship. In this research, internal reforming 500kW solid oxide fuel cell stacks fueled by methane for a ship were developed. Characteristics of power and efficiency depending on the number of cells in the stack, hydrogen conversion ratio, and active area of the cell are evaluated. Also the effects of air and methane supplying conditions on performance are analyzed. As a result, as the number of cells, hydrogen conversion ratio, active area of the cell, or supplied air flow rate increase, the stack power and efficiency increase. When the methane flow rate increases, the power increases. However the efficiency decreases. In addition, the case at the current of 976.4 A, voltage of 529.1 V, with corresponding power of 516.6 kW shows that the efficiency of fuel cell stack is 42.91%.

A Study to Increase Methane Ratio of Landfill Gas by Capturing Carbon Dioxide (매립지가스의 메탄 비율 증가를 위한 이산화탄소 포집 연구)

  • Bada Kim;Junghyun Park;Sungwoon Choi;Youngchul An;Daeyup Lee
    • Journal of the Korean Institute of Gas
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    • v.27 no.2
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    • pp.25-31
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    • 2023
  • The purpose of this study is to increase the thermal efficiency of a landfill gas (LFG) power generation engine by capturing carbon dioxide (CO2) from landfill gas (LFG) using monoethanolamine (MEA), which is widely used in the chemical CO2 absorption process. Since the use of LFG as an energy source can be a means of reducing greenhouse gas emissions, MEA can be used to reduce CO2 in LFG and increase the concentration of CH4 to improve the efficiency of power generation. In this study, experiments were conducted to measure the solubility of CO2 and CH4 in MEA solution, increase the solubility under different conditions, and analyse the dissolution characteristics. It was found that the CO2 absorption rate increased as the ratio of MEA to reaction gas increased. There is an optimum MEA concentration to maximise CO2 solubility, and even if the concentration is increased above this concentration, the solubility does not improve significantly. This study provided fundamental work to develop a more practical fuel by capturing CO2 from LFG and increasing the concentration of CH4 while reducing greenhouse gas emissions.

Emissions of Nitrous oxide from Wastewater Treatment Process by Floating Flux Chamber (Floating Flux Chmber에 의한 하.폐수처리시설에서의 아산화질소 발생특성)

  • 전의찬;장영기;최경식;김전희;서경애;박종호;이성호
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.11a
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    • pp.440-441
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    • 2002
  • 지구온난화를 유발하는 온실가스의 대표적인 성분으로는 이산화탄소, 메탄, 아산화질소, CFC 등을 들 수 있으며, 주요 온실기체들에 대한 대기 중 농도가 과거보다 현저하게 증가되었음이 확인되고 있다. $N_2$O은 대기 중의 농도는 낮으나 상대적으로 지구온난화에 기여하는 정도가 $CO_2$에 비해 질량기준으로 310배가 높고, 생체 발생량이 크기 때문에 지구규모수지에 있어서 신중하게 고려되어야 한다. 온실기체의 국가배출자료는 기후변화협약과 관련된 국제협상 및 국내 저감대책 수립에 없어서는 안될 중요한 기초자료이다. (중략)

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