• Title/Summary/Keyword: 매염

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The Use of Chitosan and Mordanting in the Dyeing of Alkali Treated PET Fabrics with Wood of Caesalpinia Sappan (알칼리 처리한 PET 직물의 소목염색에서 키토산 및 매염제의 사용)

  • Koo, Kang;Kim, Sam-Soo;Choe, Jong-Deok;Yu, Jae-Young;Park, Young-Mi
    • Textile Coloration and Finishing
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    • v.18 no.1
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    • pp.1-9
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    • 2006
  • Treatment of PET fabrics with alkali, chitosan and Al-mordanting has been carried out and the role of the chitosan coating in the dyeing process was clarified. The pre-treatment was effectively evaluated differences in dyeing behavior between its treated and untreated PET fabrics using wood of Caesalpinia sappan. The pre-treated on PET fabrics has been examined by SEM and evidence for the presence of chitosan sought using a air permeability test. Similar colour fastness by computer color matching(CCM) obtained on both untreated and pre-treated PET fabrics. The pre-treated PET was found to be of a deeper hue to that of its dyed untreated PET and, despite of its better colour depth, the wash fastness of the pre-treated dyeing was comparable to that of its dyed untreated PR. The application of chitosan or mordanting reveled that pre-treatment imparted to the PET additional functional groups that were available for coordination with the Brazilin.

Optimum Dyeing Condition of Cotton by Fermented Grape By-products with Degraded Protein Mordant (발효 포도부산물의 단백질 분해물 매염제를 활용한 염색 최적조건에 관한 연구)

  • Yang, Hyuna;Park, Youngmi
    • Textile Coloration and Finishing
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    • v.27 no.3
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    • pp.202-209
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    • 2015
  • Many of the natural dyes used for natural dyeing are difficult to maintain colorfastness due to their complex structure and specific properties. Therefore, there is a need for developing of color sustainable ability for use as an advanced coloring agent for fabrics, which would eco benign or not. In this study, the natural dye extracted from the waste of grape fruits was used to dye cotton fabric. Thus, the present study aims at extraction of color from grape seeds, skin, and stem through fermentation and then employing the same in dyeing and mordanting of cotton. Dyeing experiments were done under different conditions of fermentation and protein type mordants which were treated before and after dyeing. Experimental fabrics were used with cotton after scouring. Color value of dyed fabrics and color fastness of cotton dyed fabrics to washing and light were measured. The fastness of dyed experimental fabrics was increased by mordanting of protein fermentation and the color of dyed cotton was light red purple. The color of dyed fabric found with the optimum mordant treatment when treated with pre milk-mordant at $40^{\circ}C$ for 30min and 3% grape seed extract. On the whole, reddish tone very slightly increased with the milk pre-mordant. The color fastness of dyed cotton fabrics to light and washing was increased after fermentation.

A Study on the Dyeing Properties of Yellow and Red Natural Dyes(1) (황색 및 적색계 천연염료의 염색성에 관한 연구(1))

  • Shin, Young-Joon
    • Journal of the Korea Fashion and Costume Design Association
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    • v.17 no.2
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    • pp.45-61
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    • 2015
  • In order to analysis on color difference of natural dyes, I have dyed Hanji, cotton, silk fabric and exposed them to carbon arc light. The results of experiment have been analysed by wavelength of maximum absorption, amounts of dye uptake, color difference, Hunter's value and Munsell's value. Gardenia Jasminoides is monogenetic dye, but it gained darker color by pre-mordanting method used Al mordant agent and greenish yellow color by Fe mordant agent. whereas Curcuma, an Amur cork, and bud of pagoda tree are shown as greenish yellow color, and A barberry root, Betel nut, and Rhubarb are shown as reddish yellow color. these gained khaki colored dyed fabric by Fe mordanting. In addition, Sappan wood showed great result in pre-mordanting. Especially, it gained dark red color by Al pre-mordanting. The pink color was shown by post-mordanting. and Logwood showed great dyeing result in Hanji and cotton better than silk. Specially pre-mordanting was effective. Hanji and cotton showed greenish blue color by Al pre-mordanting, and silk showed brown color.

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A Study on the Dyeing Properties of Yellow and Red Natural Dyes(2) (황색 및 적색계 천연염료의 염색성에 관한 연구(2))

  • Shin, Young-Joon
    • Journal of the Korea Fashion and Costume Design Association
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    • v.18 no.4
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    • pp.77-86
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    • 2016
  • In order to analysis on color difference of natural dyes, I have dyed Hanji, cotton, silk fabric and exposed them to carbon arc light. The results of experiment have been analysed by Munsell's value, and compared the difference of colors which were recognized visually. Gardenia Jasminoides is monogenetic dye, but it gained darker color by pre-mordanting method used aluminum mordant agent and greenish yellow color by ferric mordant agent. whereas Curcuma, an Amur cork, and bud of pagoda tree are shown as greenish yellow color, and A barberry root, Betel nut, and Rhubarb are shown as reddish yellow color. these gained khaki colored dyed fabric by ferric mordanting. In addition, Sappan wood showed great result in pre-mordanting. Especially, it gained dark red color by aluminum pre-mordanting. The pink color was shown by post-mordanting. and Logwood showed great dyeing result in Hanji and cotton better than silk. Specially pre-mordanting was effective. Hanji and cotton showed greenish blue color by aluminum pre-mordanting, and silk showed brown color. However the color, which was recognized visually, differed from colorimeter sometimes. Therefore, such color table might be necessary for the natural dyeing.

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Dyeability and Functionality of Bamboo Extracts (Part II) -Dyeing Properties of Protein Fiber- (대나무 추출물의 염색성과 기능성 (제2보) -단백질섬유에 대한 염색성-)

  • Jung, Go-Eun;Lee, Jung-Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.35 no.3
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    • pp.336-346
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    • 2011
  • Dyeing properties of protein fiber with bamboo colorants were studied by investigating the effect of dyeing conditions such as dye concentration, dyeing temperatures, times on dye uptakes, effect of mordants, and color change. The various colorfastness of dyed fabrics were evaluated for practical use. In addition, the antimicrobial ability, ultraviolet-cut ability, and deodorant ability were estimated. The dye uptake increased as the dyeing concentration increased. Bamboo colorants showed relatively good affinity to protein fiber and produced a yellow color. Dye uptake increased as the dyeing time and temperature increased. Post-mordanting was more effective than pre-mordanting. Mordants, Fe and N.Fe, were effective for increasing dye uptake. The color of fabric mordanted with Cu and N.Cu changed to GY. Colorfastness of dyed fabrics showed a relatively good rating, and mordanting had no significant effect on colorfastness. Dyed silk fabric showed very good antimicrobial abilities of 99.9%. Also, ultraviolet-cut ability and deodorant ability were improved in silk fabric dyed with bamboo extracts.

Effect of Chitosan and Mordant Treatments on the Color Change of Cotton and Nylon Fabrics Dyed using Japanese Pagoda Tree (면(棉)과 나일론 직물(織物)의 괴화 염색(槐花 染色)에서 Chitosan 처리(處理)와 매염(媒染)이 색상(色相)에 미치는 영향(影響))

  • Hwang, Hui-Youn;Choi, Jeong-Im;Jeon, Dong-Won
    • Journal of Fashion Business
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    • v.10 no.2
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    • pp.18-26
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    • 2006
  • In this study, the effects of chitosan pre-treatment on the mordanting effect and dyeability were investigated in the dyeing using Japanese pagoda tree. The chitosan treatment effects were evaluated mainly focused on the colors after dyeing of cotton and nylon fabrics which were treated with acidic aqueous solution of chitosan. In the case of chitosan untreated fabrics, the mordanting effects on the cotton and nylon were insignificant and the dyeability was very low. Regardless of the mordant types(Al, Sn, and Fe), the dyed fabrics exhibited almost identical yellowish colors. In the case of chitosan treated fabrics, dark colors were obtained compared to the case of chitosan untreated and ${\Delta}E$ values were increased significantly. In cotton fabrics, the most excellent result was obtained under the condition of unmordanted and chitosan treated fabrics. This verifies the fact that routin coloring matters establish direct linkages with the chitosan components, which exhibit cationic nature, easily. In nylon fabrics, the effects of mordanting treatment and chitosan treatment are so insignificant that the routin coloring matters are presumed to establish direct dyeing with the nylon molecular chains.

Effect of Chitosan and Mordant Treatments on the Air-permeability, Fastness and Antimicrobial Effect of Cotton and Nylon Fabrics Dyed using Japanese Pagoda Tree (면(棉)과 나일론 직물(織物)의 괴화 염색(槐花 染色)에서 Chitosan 처리(處理)와 매염(媒染)이 공기투과도(空氣透過度), 견뢰도(堅牢度) 및 항균성(抗菌性)에 미치는 영향(影響))

  • Hwang, Hui-Youn;Jeon, Dong-Won
    • Journal of Fashion Business
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    • v.10 no.2
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    • pp.27-39
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    • 2006
  • In this study, physical/chemical characteristics of the fabrics dyed using Japanese pagoda tree which is a yellowish dyestuff was investigated. We tried to estimate the dyeing mechanism among fiber macromolecules, mordants, chitosan, and dyestuffs by measuring the change of air-permeability according to the dyeing process. Also wash fastness and light fastness were measured in order to estimate the fastness according to the dyeing characteristics. When the chitosan pre-treatment was introduced, the wash fastness increased significantly in the cotton fabrics while the fastness did not change in the nylon fabrics significantly. The light fastness was not improved by the chitosan treatment. when the antibacterial activity was measured for the dyed cotton fabrics, Japanese pagoda tree itself did not exhibit antibacterial activity. However, chitosan treated dyed fabrics exhibited low antimicrobial activity.

Natural Dyeing of Sheep Leather with Amur Cork Tree (황백을 이용한 양피에의 천연염색)

  • Kim, Sangyool
    • Journal of Fashion Business
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    • v.20 no.5
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    • pp.76-86
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    • 2016
  • In this research, the dyeing properies of Amur cork tree on sheep leathers were evaluated. The proper dyeing conditions were identified with K/S values depending on the colorant concentration, dyeing time, dyeing temperature and dye bath pH. For the proper conditions, the changes of color for different mordants(Al, Cu and Fe) were observed as $L^*a^*b^*$ coordinates and H V/C values. The color fastnesses were also examined, and the antimicrobial properties were examined. The results were as follows: For the sheep leather, the optimized dyeing conditions were 300% o.w.f., 40 min., $40^{\circ}C$, and pH 5. The leather color was yellow in the dyeing and mordanting. Although the $L^*a^*b^*$ changed with the mordants and mordanting methods, the overall hue was yellow. The colorfastness to light was reduced compared to original(untreated) sheep leather. The rubbing fastness was generallry satisfactory as 4-5 rating. The dry-cleaning fastness(stain) of leathers were generally at the 4-5 level, but dry-cleaning fastness(fade) was a little reduced compared to original sheep leather. The dyed and pre-mordanted and dyed sheep leather showed excellent antimicrobial properties.

Chracteristics and Dyieing Properties of Green Tea Colorants(Part II) -Dyeing Properties of Silk with Green Tea Colorants- (녹차색소의 특성과 염색성(제2보) -견섬유에 대한 녹차색소의 염색성-)

  • Shin, Youn-sook;Choi, Hee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.23 no.3
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    • pp.385-390
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    • 1999
  • Dyeing properties of silk fabric with green tea colorants were studied by investigating the effect of dyeing conditions such as concentration pH dyeing temperature and time on dye uptakes and effect of mordants on color change and dye uptakes, And various colorfastnesses of dyed fabrics were evaluated for practical use. Green tea colorants showed relatively good affinity to silk fabric and produced yellowish red color. Langmuir adsoption isotherm was obtained. Therefore it is considered that ionic bondings between colorants and silk fibers are formed. Mordants did not improve dye uptakes and affect color of dyed fabrics significantly. But mordanting adversely affected lightfastness of dyed fabrics. Regardless of mordanting colorfastness to perspiration especially in alkaline condition of dyed fabrics showed low rating compared with other colorfastness. It is concluded that mordanting is not necessary for silk dyeing with green tea colorants.

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Effect of Chitosan Pretreatment on the Dyeing of Cotton and Silk Fabrics using Caesalpinia sappan - Effect of the Change in Chitosan Molecular Weight - (키토산 사전 처리가 면과 견직물의 소목 염색에 미치는 영향 - 키토산의 분자량 변화에 따른 효과 -)

  • Choi In-Ryu;Kim Jong-Jun;Jeon Dong-Won
    • The Research Journal of the Costume Culture
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    • v.13 no.4 s.57
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    • pp.576-588
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    • 2005
  • The effect of chitosan pretreatment on the dyeing of cotton fiber and silk fiber was investigated. However, it has been difficult to evaluate the effect of the chitosan precisely, since the characterization of the molecular weight and effect of the degree of deacetylation were not elucidated for the application. The treatment effect may change diversely since the chitosan solution viscosity differs a lot based on the chitosan molecular weight. In this study, three chitosan specimens, varying in molecular weight, were applied for the fabric pretreatment in order to investigate the effect of chitosan molecular weight. Also, in order to maximize the efficacy of the chitosan, highly deacetylated chitosan specimens, meeting the deacetylation degree of $100\%$, were selected far the application. The air-permeability change according to the chitosan molecular weight change, influence on the mordanting, color change, and wash fastness change were investigated.

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