• Title/Summary/Keyword: 매립폐기물

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Feedstock Recycling Technology from Polyester Wastes (폴리에스터 폐자원의 화학 원료화 기술)

  • Jo, Sanghwan;Kim, Gunhyung;Cho, Minjeong;Han, Myungwan;Kang, Kyungsuk
    • Korean Chemical Engineering Research
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    • v.52 no.1
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    • pp.17-25
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    • 2014
  • Wide spread application and non-biodegradability of the poly(ethylene terephthalate) generate a huge amount of waste and disposal, posing serious environmental problems. Disposal of the PET wastes also can be thought as an economic loss of valuable chemical resources. We present various ways of feedstock recycling of PET waste to deal with environmental and economic problems. Feedstock recycling is one of promising technologies. It is based on the concept of depolymerizing the condensation polymer such as PET through solvolytic chain cleavage into low molecular products which can be purified and reused as raw materials for the production of high quality chemical products.

Magnetic Properties of NiZn-ferrite Synthesized from The Refined Waste Iron Oxide Catalyst (정제된 산화철 폐촉매로부터 합성된 NiZn-페라이트의 자기적 특성)

  • Park, Sang-Il;Lee, Hyo-Sook;Choi, Hyun-Seok;Hwang, Yeon
    • Korean Journal of Crystallography
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    • v.14 no.1
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    • pp.1-6
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    • 2003
  • NiZn-ferrites were synthesized from the waste catalysts. which were by product of styrene monomer process and buried underground as an industrial wastes, and their magnetic properties were investigated. Nickel oxide and zinc oxide powders were mixed with finely ground waste catalysts, and spinel type ferrite was obtained by calcination at 900℃ and sintering at 1325℃ for 5 hours. The initial permeabilities were measured and reflection losses were calculated from S-parameters for the composition of Ni/sub x/Zn/sub 1-x/Fe₂O₄(x=0.36, 0.50, 0.66) and (Ni/sub 0.5/Zn/sub 0.5)/sub 1-y/Fe/sub 2+y/O₄(y=-0.02, 0, 0.02).

Biological Evaluation for Characteristics of Leachate Toxicity from Municipal Solid Waste Landfill (생물학적 방법에 의한 도시생활폐기물 매립지의 침출수 독성특성 평가)

  • 황인영;류경무
    • Environmental Analysis Health and Toxicology
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    • v.11 no.1_2
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    • pp.31-39
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    • 1996
  • Leachate from municipal solid waste (MSW) landfill, effluent from leachate treatment plant, and ground water sample from a monitoring well near landfill site were tested for an acute toxicity. Microtox toxicity test was used for testing the acute toxicity of leachate and other samples. EC$_{50}$ values which a concentration of pollutant for reducing 50% light output from luminescent bacteria, Photobacterium phosphoreum were determined to assess the toxicity of pollutants as well as the relative toxicity. In addition, characteristics of leachate were studied and compared to those of phenol and pentachlorophenol (PCP) which are typical aquatic toxic pollutants. For leachate, EC$_{50}$ for 30 min incubation was 10.8%, while for phenol and PCP, 46 ppm and 1.2 ppm, respectively. the relative toxicity of treated leachate by in situ aeration with activated sludge was reduced to more than 75% of toxicity of the untreated leachate. Microtox toxicity test was failed to figure out EC$_{50}$ values for groundwater from a monitoring well since the relative toxicity of the unconcentrated sample was too low to estimate EC$_{50}$. Addition of activated carbon to leachate was reduced the relative toxicity. The reduction Pattern of the relative toxicity of leachate by mechanical aeration was similar to that of PCP, but different from that of phenol. These findings suggest that the toxicity of leachate may come from PCP-like toxic compounds rather than phenol-like one. In conclusion, the process of aeration with activated sludge might be very important to reduce the environmental toxicity of leachate. And Microtox test could be a reasonable bioassay for screening and monitoring the environmental toxicity of leachate from municipal solid waste landfill as well as for determining the reduction efficiency of the leachate toxicity by various treatment processes in leachate treatment plant.

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Mechanical Properties of Lightweight Mortar in Accordance with the Particle Size and Replacement Ratio of the Wasted Tire Chip (폐타이어 분말의 치환율과 입자크기에 따른 경량 모르타르의 역학적 특성)

  • Yang, Hun;Lee, Yong;Lee, Sang-Soo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.4
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    • pp.342-347
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    • 2015
  • This study is basic experiment which prevents indiscriminate reclamation and recycles the wasted tire in order to solve environmental pollution according to generation rate of the wasted tire from recently industrial development. By applying as the substitute material of the lightweight aggregate among the constructional materials in order to evaluate the lightness of the wasted tire chip and suggest the recycling plan of the wasted tire chip. The prior experiment did the replacement ratio of the wasted tire with 20%, 40%, 60%, 80%, 100%, etc. and made a study on the strength and density properties. Based on the prior experiment of wasted tire, the replacement ratio was fixed at 15, 20, 25%, particle size of wasted tire was fixed at 0.2, 0.8, 1~2, 3~5, 5~7(mm). As a result, it is supposed that the best replacement ratio and particle size are 15% and 1~2mm, respectively.

An Experimental Study on High Strength Concrete Using the LCD Waste Glass Powder (LCD 폐유리 미분말을 사용한 고강도 콘크리트에 관한 실험적 연구)

  • Kim, Byung-Chul;Cha, Tae-Gweon;Jang, Pan-Ki;Kim, Chan-Woo;Jang, Il-Young
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.4
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    • pp.335-341
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    • 2015
  • Various display devices has been increasing also using waste LCD glass in accordance with the used developed, because circumstances that are most landfill or incineration, are needed research on recycling measure of the using waste LCD glass. Therefore, in this study, to try to assess the basic mechanical properties of concrete mixed with using waste LCD glass micropowder through the room mixed test. According to the study results, the more replacement rate increases, the characteristics of the concrete showed a tendency to decrease slightly. However, according to the small value, it is expected to improve the advanced experimental values by refining the grain size of the materials used to be processed into spheres.

Analysis on Contaminant Transport according to the Embedded Depth of Vertical Barrier of Offshore Landfill (해상 폐기물매립지 연직차수벽체 근입심도에 따른 오염물질 이동특성 분석)

  • Park, Haeyong;Oh, Myounghak;Kwon, Osoon
    • Journal of the Korean GEO-environmental Society
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    • v.17 no.8
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    • pp.29-37
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    • 2016
  • In order to prevent leakage of contaminants in offshore landfill, vertical barrier should be installed. Vertical barrier should be installed at designed depth of seabed to prevent the horizontal transport of contaminant in the subsurface. In this study, the seepage and contaminant transport in the subsurface according to embedded depth of vertical barrier were analyzed by using 2-D finite element analysis program SEEP/W and 3-D finite difference analysis program Visual Modflow. Numerical modelling results show that seepage flux and contaminant transport in seabed was greatly reduced when vertical barrier was installed at certain depth of low permeable layer. Therefore, the determination of minimum embedded depth for preventing contaminant leakage is helpful to design the economical vertical barrier.

Magnetic Properties of NiZn-ferrite Synthesized from Waste Iron Oxide Catalyst (산화철 폐촉매로부터 합성된 NiZn- 페라이트의 자기적 특성)

  • Hwang, Yeon;Kwon, Soon-Kil;Lee, Hyo-Sook;Je, Hae-June;Park, Sang-Il
    • Journal of the Korean Ceramic Society
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    • v.38 no.12
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    • pp.1162-1166
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    • 2001
  • NiZn-ferrite was synthesized from waste catalysts, which were produced from styrene monomer process and buried underground as an industrial wastes, and its magnetic properties were investigated. Nickel oxide and zinc oxide powders were mixed with finely ground waste catalysts, and spinel type ferrite was obtained by calcination at 900$\^{C}$ and sintering at 1230$\^{C}$ for 5 hours. The intial permeability was measured and reflection loss was calculated from S-parameters for the composition of Ni$\_$x/Zn$\_$1-x/Fe$_2$O$_4$(x=0.36, 0.50, 0.66). NiZn-ferrite synthesized from waste iron oxide catalyst showed a feasibility for the use as electromagnetic wave absorber in X-band.

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Long-Term Performance of Geomembranes by Oxidative Induction Time

  • Jeon, Han-Yong;Kim, Hong-Kwan;Keum, Jae-Ho;Jang, Yong-Chea;Lyoo, Won-Seok;Ghim, Han-Do
    • Journal of the Korean Geosynthetics Society
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    • v.2 no.3
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    • pp.19-24
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    • 2003
  • Long-term performance of smooth and textured type HDPE geomembranes which were used to the liner and slope systems of waste landfills was examined. Artificial surface defects were added to the surface of geomembranes by scratch addition apparatus specially designed. The mechanical and frictional properties, chemical and ultra violet light resistances and oxidative induction time(OIT) of geomembranes were examined for the cases of defective/non-defective surfaces. Frictional properties of textured type geomembranes showed more excellent than those of smooth type geomembranes. Finally, it was known that the long-term performance of non-defective and textured geomembranes was better than that of defective geomembranes through chemical and UV resistance and OIT tests etc.

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On the Generation and Processing of the Sludge Containing Heavy Metals in Korea (우리나라 重金屬 함유 汚泥의 發生과 處理)

  • On, Jae-Hyun;Kim, Mi-Sung;Shin, Hee-Duck
    • Resources Recycling
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    • v.13 no.5
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    • pp.3-16
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    • 2004
  • There are over 190,000 tons per year of the sludge containing heavy metals (SHM) generated from industries in Korea. The SHM is so hazardous waste, it needs proper intermediate treatment before final disposal. At present, the common intermediate treatment and final disposal technologies of SHM are solidification and landfill. However, the future treatment and disposal technologies of SHM will be carry out to fulfill in both the environmental aspect and resource recycling. Thus, how to reduce the generation of SHM and recycle the valuable metal from SHM become the major subjects in the global world. In this article, in order to prospect the effective processing of SHM, the generation and processing of the sludge from plating wastewater, the research and development of valuable metal recycling technology and problems were summarized.

Assessment of Hydraulic Conductivity of Modified Bentonite and Local Soil Mixture under Salt Water Condition (개량 벤토나이트와 현장토 혼합 차수층의 염수조건하에서의 투수성 평가)

  • Xu, Xin;Oh, Myounghak;Park, Junboum
    • Journal of the Korean Geotechnical Society
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    • v.33 no.11
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    • pp.97-104
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    • 2017
  • A bentonite mixing with local soil widely used as liner layer for landfill should have low permeability less than $1{\times}10^{-7}cm/s$. But there are several limitations of bentonite used as liner layer, such as drying shrinkage cracking, ineffective waterproof ability under salt water condition like flocculation under sea water. The purpose of this research is the development of a salt resistance bentonite by mixing sepiolite and guar gum to overcome the weak points of bentonite to get high water resistance capacity and permeability coefficient below $1{\times}10^{-7}cm/s$ under salt water condition. After having performed drying shrinkage cracking test, swelling index test, compaction test, and hydraulic conductivity test we confirmed the optimal mixing ratio of materials and evaluated the performance of materials.