• Title/Summary/Keyword: 르 샤틀리에의 원리

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Hydrogen production by catalytic decomposition of methane over carbon black catalyst in a fluidized bed on pressurized bench-scale condition (가압유동층 반응기에서 카본블랙 촉매를 이용한 메탄의 촉매분해에 의한 수소제조)

  • Seo, Hyung-Jae;Lee, Seung-Chul;Lee, Gang-In;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.791-793
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    • 2009
  • Hydrogen has been recognized of the energy source for the future, in terms of the most environmentally acceptable energy source. A pressurized fluidized bed reactor made of carbon steel with 0.076 m I.D. and 1.0 m in height was employed for the thermocatalytic decomposition of methane to produce amount of $CO_2$ - free hydrogen with validity from a commercial point of view. The fluidized bed was proposed for withdrawing of product carbons from the reactor continuously. The methane decomposition rate with the carbon black N330 catalyst was rapidly reached a quasi-steady state and remained for several hour. The methane thermocatalytic decomposition reaction was carried out at the temperature range of 850 - 950 $^{\circ}C$, methane gas velocity of 2.0 $U_{mf}$ and the operating pressure of 1.0 -3.0 bar. Effect of operating parameters such as reaction temperature, pressure on the reaction rates was investigated and predicted the effect of a change in conditions on a chemical equilibrium thermodynamically, according to Le Chatelier's principle.

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