• Title/Summary/Keyword: 동전기

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Role of Electrode Reaction of Electrolyte in Electrokinetic-Fenton Process for Phenanthrene Removal (동전기-펜턴 공정에서 전해질의 전극반응이 처리효율에 미치는 영향)

  • Park Ji-Yeon;Kim Sang-Joon;Lee You-Jin;Yang Ji-Won
    • Journal of Soil and Groundwater Environment
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    • v.11 no.1
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    • pp.7-13
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    • 2006
  • The effects of electrolytes were investigated on the removal efficiency when several different electrolytes were used to change the electrode reaction in an electrokinetic (EK)-Fenton process to remediate phenanthrene-contaminated soil. Electrical potential gradient decreased initially due to the ion entrance into soil and then increased due to the ion extraction from soil under the electric field. Accumulated electroosmotic flow was $NaCl>KH_2PO_4>MgSO_4$ at the same concentration because the ionic strength of $MgSO_4$ was the highest and $Mg(OH)_2$ formed near the cathode reservoir plugged up soil pore to inhibit water flow. When hydrogen peroxide was contained in electrolyte solution, removal efficiency increased by Fenton reaction. When NaCl was used as an electrolyte compound, chlorine ($Cl_2$) was generated at the anode and dissolved to form hypochlorous acid (HClO), which increased phenanthrene removal. Therefore, the electrode reaction of electrolyte in the anode reservoir as well as its transport into soil should be considered to improve removal efficiency of EK-Fenton process.

Transfer System using Radial Electrodynamic Wheel over Conductive Track (래디얼 동전기 휠을 이용한 전도성 트랙 위에서의 이송 시스템)

  • Jung, Kwang Suk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.11
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    • pp.794-801
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    • 2017
  • When a radial wheel is placed so as to partially overlap a conductive plate and rotated, a lift force is generated on the wheel, a thrust force along the edge, and a lateral force which tends to reduce the overlap region. When several of these wheels are combined, it is possible to realize a system in which the stability of the remaining axes is ensured, except in the traveling direction. To validate the overall characteristics of the multi-wheel system, we propose a transfer system levitated magnetically using radial electrodynamic wheels. The proposed system is floated and propelled by four wheels and arranged in a structure that allows the thrusts generated by the front and rear wheels to offset each other. The dynamic stability of the wheel and the effect of the pole number on the three-axial forces are analyzed by the finite element method. At this time, the thrust and levitation force are strongly coupled, and the only factor affecting them is the wheel rotation speed. Therefore, in order to control these two forces independently, we make use of the fact that the ratio of the thrust to the levitation force is proportional to the velocity and is independent of the size of the gap. The in-plane and out-of-plane motion control of the system is achieved by this control method and compared with the simulation results. The experimental results show that the coupled degrees of freedom can be effectively controlled by the wheel speed alone.

Removal of Phenanthrene by Electrokinetic-Fenton Process in a 2-dimensional Soil System (동전기-펜턴 공정을 이용한 2차원 토양 정화장치에서의 phenanthrene 제거)

  • Park Ji-Yeon;Kim Sang-Joon;Lee You-Jin;Yang Ji-Won
    • Journal of Soil and Groundwater Environment
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    • v.10 no.5
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    • pp.11-17
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    • 2005
  • Characteristics of phenanthrene removal in the Electrokinetic (EK)-Fenton process were investigated in a 2-dimensional test cell in a viewpoint of the effect of gravity and electrosmotic flow (EOF). When the constant voltage of 100 V was applied to this system, the current decreased from 1,000 to 290 mA after 28 days, because soil resistance increased due to the exhaustion of ions in soil by electroosmosis and electromigration. Accumulated EOF in two cathode reservoirs was 10.3 L and the EOF rate was kept constant for 28 days. At the end of operation, the concentration of phenanthrene was observed to be very low near the anode and increased in the cathode region because hydrogen peroxide was supplied from anode to cathode region following the direction of EOP. Additionally, the concentration of phenanthrene decreased at the bottom of the test cell because the electrolyte solution containing hydrogen peroxide was largely transported toward the bottom due to a low capillary action in the soil with high porosity. Average removal efficiency of phenanthrene by EK-Fenton process was 81.4% for 28 days. In-situ EK-Fenton process would overcome the limitations of conventional remediation technologies and effectively remediate the contaminated sites.

Effects of pH Control Methods on Removal Efficiency in Electrokinetic Bioremediation of Phenanthrene-contaminated Soil (Phenanthrene-오염토양의 동전기 생물학적 복원에서 pH 조절방법이 제거효율에 미치는 영향)

  • Kim, Sang-Joon;Park, Ji-Yeon;Lee, You-Jin;Yang, Ji-Won
    • KSBB Journal
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    • v.21 no.3
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    • pp.181-187
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    • 2006
  • In this study, problems related with pH control in electrokinetic(EK) bioremediation of phenanthrene contaminated soil were observed, and the effects of pH control methods on the removal efficiency were investigated to search a further application strategy. In a preliminary experiment, it was found out by flask cultivation that a certain sulfate concentration was needed to degrade phenanthrene well using Sphingomonas sp. 3Y. However, when $MgSO_4$ was used as sulfate source in EK bioremediation, the bacterial activity reduced seriously due to the abrupt decrease of pHs in soil and bioreactor by the combination of magnesium and hydroxyl ions. When another strong buffering compound was used to control the pH problem, the good maintenance of the bacterial activity and pHs could be observed, but the removal efficiency decreased largely. When a low concentration of $MgSO_4$ was added, the removal efficiency decreased somewhat in spite of the good maintenance of neutral pHs. With the addition of NaOH as a neutralizing agent, the removal efficiency also decreased because of the increase of soil pH. Consequently the selection of electrolyte composition was a very important factor in EK bioremediation and some sulfate sources suitable for both bacterial activity and contaminant degradation should be investigated.

A Spatial Stability of the Conductive Rod Conveyed by Double Electrodynamic Wheels (이중 동전기 휠에 의해 반송되는 도전성 환봉의 공간 안정성)

  • Jung, Kwang-Suk
    • Journal of the Korean Society for Precision Engineering
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    • v.29 no.8
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    • pp.873-878
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    • 2012
  • Putting a conductive rod between rotating axial electrodynamic wheels composed of repetitive permanent magnets, three-axial magnetic forces generate on the conductive rod. It is possible to levitate and transfer the rod on space with the forces. However, the forces vary in direction and magnitude for a position of the rod between the electrodynamic wheels. Thus, the position influences the stability of the rod also. To guarantee the stability of a levitated object, the force acting on the object should have negative stiffness like a spring. So, we analyze the stable operating range of the conductive rod levitated by the axial wheels with the commercial finite element tool in this paper. Specially, as the pole number and the radial width of permanent magnets has much influence on the generated force and thereby the stable region, their sensitivities are analyzed also. The analytic result is compared with experimental result.

Design of an Electrodynamic Wheel for Transfer of Conductive Rod (전도성 환봉 이송용 동전기 차륜의 설계)

  • Park, Sung-Jun;Jung, Kwang-Suk
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.20 no.3
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    • pp.251-256
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    • 2011
  • Instead of multi-phase ac current, the magnetic field travels spatially through mechanical rotation of permanent magnets at the electrodynamic wheel (EDW). Traveling of magnetic field generally leads to a generation of inductive force in the traveling direction. In this paper, we suggest a spiral EDW to travel the magnetic field in the axial direction of the conductive rod. So, it is possible to levitate and transfer the rod through multi-axial forces by the spiral EDW. However, physical dimensions of permanent magnets constituting EDW influence relative ratios between three-axial forces generated on the rod. Therefore, the sensitivity analysis for design parameters is performed using FEM analysis. The stable operation is verified experimentally.

Electrophoretic Particle Movement in Suspension Considering the Gravitational Settling and Sedimentation of Clayey Soil (중금속으로 오염된 점성토의 동전기영동에 의한 침강 거동에 관한 연구)

  • Lee, Myung-Ho
    • Journal of Soil and Groundwater Environment
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    • v.12 no.3
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    • pp.44-52
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    • 2007
  • Contaminated sediments more than 30 million/$m^3$ is generated from dredging work for harbours and coastal maintenance in Korea. Approximately 300 million/$m^3$ of sediments is dredged to deepen harbours and shipping lanes in US and of which $3{\sim}12million/m^3$ is highly contaminated. Although much is known about technologies for the remediation of heavy metal contaminated soil, much less is known about the treatment of contaminated sediment. In general, negatively charged fine particles will migrate towards positively charged system of electrodes under the influence of electrophoresis. However, the electrically induced migration of colloidal particles contaminated with heavy metals may be hindered by the positively charged heavy metal contaminants adsorbed onto the soil surfaces depending on the contamination level. This paper demonstrates settling behaviour of clayey soil by comparison with electrophoretic particle movement under the effects of heavy metal contamination, applied electric field strength, and its polarity changed by the electrode configuration.