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The distribution characteristics of trace elements of fine ambient particulate in Korea

  • Lim, Jong-Myoung;Lee, Jin-Hong;Kim, Ki-Hyun
    • Analytical Science and Technology
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    • v.18 no.3
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    • pp.241-249
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    • 2005
  • In this study, instrumental neutron activation analysis was used to measure the concentrations of about 30 trace elements in airborne particulate (PM2.5) samples at urban area of Daejeon city located in the southwestern region of Korea. An inspection of the measurement data indicates that the distribution patterns of trace elements could clearly distinguish the elements with their concentrations ranging over five orders of magnitude. The mean values for Lu and Dy were found to be the lowest at values of 0.01 and $0.04ng/m^3$, while those for K and Fe showed the highest value of 671 and $653ng/m^3$, respectively. The results of correlation analysis showed that PM2.5 concentrations can exhibit much more enhanced correlations with the elements of earth crustal components. The results of factor analysis further indicated that there are no more than six factors with statistical significance, which may exert dominant roles in regulating the elemental concentration levels in the study area. Enrichment factor analysis supports explicit interpretation of results found by this factor analysis.

Distribution Rate of Particles Exiting Jinju Bay in the Namgang Dam Freshwater Discharge (남강댐 담수 방류시 진주만을 빠져나가는 입자들의 수로별 분배율 평가)

  • Namyoun No;Minsun Kwon;Hyeryeon Kwon;Jonggu Kim
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.29 no.6
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    • pp.576-586
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    • 2023
  • In this study, a numerical particle tracking experiment was conducted to assess the distribution characteristics of freshwater exclusion resulting from the discharge of Gahwa Stream into Sacheon, Jinju, and Gangjin bays, located downstream of the Namgang Dam. The number of particles discharged into Noryang Channel, Daebang Channel, and Changseon Strait was compared by releasing 1000 particles through Gahwa Stream under three discharge conditions: no discharge, discharge during rainfall, and discharge during flood. Evidently, the percentage of particles in the Noryang Channel increased, whereas that in the Daebang Channel decreased as the discharge from the Gahwa Stream increased. Approximately 95% of the material located downstream of the Gahwa Stream generally escaped through the Daebang Channel. However, as the discharge from the Namgang Dam increased due to rainfall, the percentage of particles in the Noryang Channel increased, reaching 45.5% during floods.

Characteristics of Collected Sediments from Road Sweeping and Reduction in the Nonpoint Source Pollutants Loading (도로청소 수거퇴적물의 특성과 비점오염물질 저감효과)

  • Jeong, Kwon;Kang, Hee-Man;Ko, Seok-Oh
    • International Journal of Highway Engineering
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    • v.13 no.2
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    • pp.187-193
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    • 2011
  • The stormwater runoff from road or expressway is known as one of important nonpoint pollution sources. To reduce the pollutants discharge from road or expressway, many best management practices(BMPs) have been applied and planned. Among the BMPs, road sweeping can be effective way to prevent pollutant washoff to environment. This study is performed to evaluate the characteristics of particles collected from the road by sweeping car. Size distribution and pollutant concentration of particles were analyzed. Based on the pollutant concentration and the specification of road such as length, width, and unit for pollutant generation, total amount of pollutant to be removed by road sweeping was estimated. Most of sediments collected by road sweeping was classified into sandy soil and fraction of fine grained soil was low. Although the concentrations of pollutants such as heavy metals in road sediments did not exceed the soil contamination criteria, washout of pollutants during sweeping work by spraying water might cause leaching of pollutants contained in sediments and thus resulted in low pollutant concentrations. Reduced amounts of pollutant by road sweeping showed 31.4% TSS reduction for ${\bigcirc}{\bigcirc}$ region and 7.7% TSS for ${\triangle}{\triangle}$ region. Other pollutants showed low reduction rate, because of their leaching by water spraying. Results from this study indicate that detailed and well-planned investigation for the road sweeping is necessary for the accurate estimation of pollutant reduction from road or expressway.

Utilizability of Waste Concrete Powder as a Material for Soil Pavement (흙도로포장용 재료로서 폐콘크리트 미분말의 활용성 연구)

  • Kim, Yong-Jic;Choi, Yun-Wang;Kim, Young-Jin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.3
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    • pp.277-282
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    • 2015
  • This study is conducted to utilize waste concrete powder (WCP) made as a by-product manufacturing high quality recycled aggregate. The blaine fineness of the used waste concrete powder was $928cm^2/g$. As the main characteristic of waste concrete powder, it showed an angular type similar to cement, but hydrated products were attached on the surface of particles. In addition, the size of the particles of waste concrete powder was larger than OPC and in terms of chemical components it had higher $SiO_2$ contents. For using WCP in soil cement-based pavement, the qualities, physical and chemical properties, of WCP should be researched. In the first step, the specified compressive strength of mortar for two types of clay sand soil and clay soil respectively was experimented to be 15 MPa and then optimum mixing ratio of chemical solidification agent were decided in the range of 1.5 - 3.0% in the replacement with cement weight content. In the second step, based on the prior experimental results, recycling possibility of WCP in soil cement-based pavement was studied. In the result of experiment the mixing ratio of WCP were 5, 10, 15 and 20% in the replacement with soil weight and the compressive strength of mortar was somewhat decreased according to the increase of the mixing ratio of WCP.

Analysis of pollutant behavior in sediments in a Rain Garden through long-term monitoring (레인가든 내 장기모니터링을 통한 오염물질 거동분석)

  • Jeon, Minsu;Choi, Hyeseon;Reyes, N.J. DG.;Kim, Leehyung
    • Proceedings of the Korea Water Resources Association Conference
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    • 2020.06a
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    • pp.339-339
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    • 2020
  • 도시화로 인한 불투수면적의 증가와 기후 변화로 인한 강우패턴의 변화 자연적 물순환 체계에 악영향을 미치며. 이를 해결하기 위하여 국내에서는 도시 내 빗물관리 및 비점오염원 저감이 가능한 저영향개발(Low Impact Development, LID)를 적용하고 있다. 건기시 도로, 주차장등 차량통행 및 유동인구가 많은 지역에서는 입자상 물질들이 많이 발생되어 노면에 축적되어 있다가 강우시 강우유출수를 통해 시설로 유입된다. 이로 인해 시설 내 오염물질 및 퇴적물이 축적되어 여재 공극막힘현상 및 침투율저하의 문제가 발생되어 시설 내 효율이 감소된다. 따라서, 레인가든의 장기 모니터링을 통해 시설 내 유입되는 오염물질의 성상 분석 및 시설 내부의 퇴적물 분석을 통해 LID시설 운영의 효율성 평가를 수행하였다. 모니터링은 강우시 모니터링과 건기시 집수구역, 침강지, 시설 상부, 중부, 하부 등 총 5곳에서 채취하여 분석을 수행하였다. 모니터링은 평균 선행건기 일수는 5.46±4.7 days, 평균 강우량은 14.31±11.4 mm, 평균 강우강도는 5.33±6.7 mm/hr의 강우사상에서 모니터링을 수행하였다. 시설 내 평균 유입수농도는 TSS 98.0 ± 32.7 mg / L, COD 133.6 ± 6.3 mg / L, TN 5.77 ± 4.05 mg, TP 0.54 ± 0.03 mg / L으로 분석되었다. 유입부 내 퇴적물 종류는 Sandy Clay Loam으로 나타났으며, Cr 0.36mg / kg, Cu 5.17 mg / kg and Pb 6.04 mg / kg으로 중금속의 함유량이 높은것으로 분석되었다. 퇴적물은 침강지 및 시설 유입부에서의 입자크기는 49-113㎛ 약 60%의 퇴적물이 축적되어 제거되는 것으로 나타났다. 시설 내 침강지에서 50㎛ 이상의 입자들이 여과, 흡착 및 침전으로 인하여 40% 이상의 입자들이 제거되는 것으로 분석되었으며, 50㎛ 미만의 입자들은 시설 내 중간부, 유출부에서 제거되는 것으로 분석되었다. 침강지에서 유입수 대부분의 입자상물질들이 흡착 및 여과로 인한 제거가 이루어지기에 침강지 여재부는 넓은 표면적, 우수한 흡착능 및 여과율을 고려하여 선정하영 하며, 잦은 교체를 위하여 중량성이 낮은 우드칩 등이 적당한 것으로 사료된다.

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The Caracteristics and concentration of PCDDs/ PCDFs in scatterable dust on the edges of highway (자동차 전용 도로변 비산 가능한 먼지 중 PCDDs/ PCDFs의 농도 특성)

  • 최용석;엄정훈;윤중섭;김민영
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.249-250
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    • 2003
  • 다이옥신류의 주된 생성원인은 쓰레기 소각장에서의 배출가스에 기인한다고 알려져 있다.$^{1,3,4)}$ 그 밖에 농약제조, pulp 제조과정에서 부산물로 생성되기도 하고, 자동차배가스도 다이옥신의 생성원인 중에 하나이다. Miyabara$^{5)}$ 등은 일본내 자동차 배출가스 입자중 다이옥신류의 농도는 4.2-242 pg I-TEQ/g이였으며, 일본에서 배출하는 다이옥신류의 약 0.3%에 달한다고 추정하였다. 도로변 퇴적물 둥에서의 다이옥신 농도는 자동차 배출가스 등으로부터 직ㆍ간접으로 많은 영향을 받고 있으며, 이들이 비산할 경우 운전자의 호흡기를 통해 건강에 직접적으로 영향을 미칠 수 있다.$^{2)}$ (중략)

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Simulation of Aggregate Slump Test Using Equivalent Sphere Particle in DEM (등가 구형입자를 이용한 DEM에서의 골재 슬럼프 실험 모사)

  • Yun, Tae Young;Ahn, Sang Hyeok;Nam, Jueong Hee;Yoo, Pyeong Jun
    • International Journal of Highway Engineering
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    • v.15 no.5
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    • pp.21-29
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    • 2013
  • PURPOSES: Simulation of aggregate slump test using equivalent sphere particle in DEM and its validity evaluation against lab aggregate slump test METHODS : In this research, aggregate slump tests are performed and compared with DEM simulation. To utilize spheric particles in YADE, equivalent sphere diameter concept is applied. As verification measures, the volume in slump cone filled with aggregate is used and it is compared with volume in slump cone filled with equivalent sphere particle. Slump height and diameter are also used to evaluate the suggested numerical method with equivalent concept RESULTS : Simulation test results show good agrement with lab test results in terms of loose packing volume, height and diameter of slumped particle clump. CONCLUSIONS : It is concluded that numerical simulation using DEM is applicable to evaluate the effect of aggregate morphological property in loose packing and optimum gradation determination based on the aggregate slump test simulation result.

Assessment of Metal Pollution of Road-Deposited Sediments and Marine Sediments Around Gwangyang Bay, Korea (광양만 내 도로축적퇴적물 및 해양퇴적물의 금속 오염 평가)

  • JEONG, HYERYEONG;CHOI, JIN YOUNG;RA, KONGTAE
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.25 no.2
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    • pp.42-53
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    • 2020
  • In this study, heavy metal in road-deposited sediments (RDS) and marine sediment around Gwangyang Bay area have been investigated to assess the pollution status of metals and to understand the environmental impact of RDS as a potential source of metal pollution. Zn concentration for <63 ㎛ size fraction was the highest (2,982 mg/kg), followed by Cr, Ni, Pb, Cu, As, Cd, and Hg. Metal concentrations in RDS increased with decreasing particle size and relatively higher concentrations were observed around the metal waste and recycling facilities. For particle size in RDS smaller than 125 ㎛, EF values indicated that Zn was very high enrichment and Cr, Cd, Pb were significant enrichment. The concentrations of metals in marine sediments were mostly below the TEL value of sediment quality guidelines of Korea. However, the Zn concentrations has increased by 30~40% compared to 2010 year. The amounts of Zn, Cd and Pb in less than 125 ㎛ fraction where heavy metals can be easily transported by stormwater runoff accounted for 54% of the total RDS. The study area was greatly affected by Zn pollution due to corrosion of Zn plating materials by traffic activity as well as artificial activities related to the container logistics at Gwangyang container terminal. The fine particles of RDS are not only easily resuspended by wind and vehicle movement, but are also transported to the surrounding environments by runoff. Therefore, further research is needed on the adverse effects on the environment and ecosystem.

Analysis on Erosional Properties of Fine-Cohesive Sediments In Kunsan Coast (군산해역 미세-점착성 퇴적물의 침식특성 해석)

  • 이현승;조용준;황규남
    • Proceedings of the Korean Society of Coastal and Ocean Engineers Conference
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    • 2003.08a
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    • pp.222-226
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    • 2003
  • 대부분의 경우에 하구의 미세-점착성 퇴적물은 보통 무기성 광물과 유기물 및 생화학물의 혼합체이며, 광물 입자들은 주로 점토와 실트로 구성되어 있다. 이러한 혼합체의 침식특성은 사질성 퇴적물과는 달리 입자간의 응집현상에 의한 의해 크게 영향을 받으며, 응집강도는 광물질 구성, 입경분포, 유기물 함량 등으로 묘사되는 퇴적물 자체의 물리ㆍ화학적 기본특성에 따라 크게 변화하고 (Mea, 1986), 특히 저면 퇴적물의 침식 여부는 흐름 전단응력에 의한 저면퇴적물의 저항력 즉, 저면전단강도의 상대적 크기의 차이에 좌우되므로, 그 침식 특성은 저면전단강도 흑은 저면밀도로 묘사되는 저면특성에 따라 크게 변화한다(황규남 등, 2003). 또한 각 해역마다 저면 퇴적물은 퇴적물 공급원, 수동학적 조건, 생태학적 조건 등이 모두 다른 상태에서 형성된 퇴적층이므로, 저면 퇴적물의 기본특성 및 저면특성은 "site- specific" 한 성격을 갖는다. (중략)

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Quality Control of Pluvio Snowfall Data Using Parsivel (광학우적계를 이용한 무게식 우량계 적설 자료 품질 관리)

  • Ro, Yonghun;Chung, Gunhui
    • Proceedings of the Korea Water Resources Association Conference
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    • 2018.05a
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    • pp.80-80
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    • 2018
  • 겨울철 대설 현상에 따른 도로 결빙과 항공기 운항 지연, 비닐하우스 및 가건물 붕괴와 같은 피해가 증가함에 따라 대처방안을 마련하는 일이 중요시 되고 있다. 이를 위해 정확한 적설 정보가 근본적으로 필요하지만, 문제는 적설량을 정량적으로 관측하는 일이 간단하지 않다는 점이다. 최근에는 무게식 우량계를 이용한 적설 관측이 수행되고 있지만, 강설량이 많을 경우 우량계가 눈에 덮이는 캐핑(capping) 현상으로 인해 제대로 관측하기 어려운 문제가 있다. 본 연구에서는 무게식 우량계의 이러한 한계를 보완하고 자료의 활용성을 높이기 위해 광학우적계(Parsivel)로 관측된 강설입자정보를 이용하여 적설량을 보정하는 방법을 제안하였다. 무게식 우량계 자료는 대관령 구름물리선도센터에 설치되어 있는 플루비오(Pluvio)의 적설 관측 자료를 이용하였다. 먼저, 관측된 플루비오 자료에서 단위 시간동안의 신적설을 산정한 후 과도한 관측값과 같은 노이즈를 제거하였다. 또한 플루비오와 동일 기간에 관측된 광학우적계 자료에 대해 강설 입자가 $10/m^3$ 초과로 나타나는 사상을 강수 기간으로 결정하고 두 자료가 모두 '0'인 경우 무강수로 나타냈다. 그 결과 강수 입자가 관측된 적설 기간에 플루비오가 우수하게 강설 사상을 관측하고 있음을 확인하였고, 부적합한 자료를 보정할 수 있었다. 이러한 방법으로 적설 자료를 개선할 경우 향후 레이더를 이용한 공간적 강설 추정의 정확도를 크게 개선할 수 있을 것으로 판단된다.

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