• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2014.11a
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• pp.86-88
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• 2014

니켈도금폐액은 재자원화되지 못하고 대부분 외부로 위탁 폐수처리되고 있으며, 고가의 금속인 니켈을 회수되지 못하고 버려지고 있는 실정이다. 이에 니켈도금폐액으로부터 니켈을 회수하고, 회수된 니켈을 이용하여 니켈화합물을 제조하여 니켈도금폐액을 재자원하는 기술을 개발하였다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2015.11a
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• pp.312-313
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• 2015

무전해 도금은 석출응력이 낮고 작업하기가 용이하기 때문에 산업분야에 있어서 중요한 역할을 한다. 무전해 도금 공정에 있어서, 니켈금속은 차아인산염, 아미노보레인 혹은 수소화붕소 화합물($HBF_4$)에 의한 니켈이온의 화학적 환원에 의해 도금된다. 환원반응이 진행함에 따라서 도금액 중에서 니켈과 차아인산염 이온은 감소한다. 이에 이러한 이온을 보충하기 위하여 도금액 중에 황산니켈과 차아인산나트륨이 일반적으로 첨가된다. 하지만 축적된 인산염, 황산염, 나트륨과 이외의 물질이 전착 박막의 품질을 떨어뜨리고 도금액은 폐기되기도 한다. 니켈회수 속도는 종래의 50% 이하였던 것이 90%이상으로 향상되었다. 이온교환법은 니켈도금 폐액으로부터 니켈회수에 필요한 친환경적이고 원가절감의 기술이라고 사료된다. 특히, 갈탄이 저렴하고 양이온 교환성능이 뛰어나다. 이유는 -COOH, -OH 등의 기능성 그룹을 갖기 때문이다. Fe-P 화합물은 식물에 유용하지 못하고 마그네슘과 칼슘 기반의 석출물은 저렴하고 취급이 용이하며 비료와 같이 재활용이 가능하기 때문에 일반적인 인의 제거 수단이 될 수 있다. 본고에서는 니켈도금 폐액으로부터 인을 제거하는 데 $Ca(OH)_2$, $CaCl_2$와 $CaCO_3$를 채택하여 인이 제거되는 정도를 비교하였고 니켈회수율을 높이기 위하여 갈탄을 사용하였다.

• Resources Recycling
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• v.21 no.2
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• pp.41-46
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• 2012

An investigation on the recovery of nickel from spent electroless plating solutions has been performed using the electrowinning method. For this aim, nickel in spent electroless plating solutions was separated as nickel hydroxide through the addition of caustic soda. Nickel hydroxide was completely dissolved with sulfuric acid and an electrolysis was performed for electrowinning of nickel from nickel solutions. As a result, it was found that more than 99% of nickel in spent electroless plating solutions could be precipitated as nickel hydroxide above pH 10 with the addition of caustic soda. As far as the current efficiency in electrowinning of nickel was concerned, it was decreased with increase in the current density.

• Resources Recycling
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• v.25 no.4
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• pp.42-48
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• 2016

A research for the recovery of the metal with high purity from the waste tin plating solution was carried out. First, tin plating waste solution was tested to remove the organic substances and metallic impurities such as Fe, Zn, Na etc. using ion exchange resin having iminodiacetic functional groups (Lewatit TP 207). Second, the tin solution was purified to obtain the high purity tin solution using ion exchange resin having ethylhexyl-phosphate functional groups (Lewatit VPOC 1026). Finally, 99.98% of the high purity of tin metal can be recovered from the purified solution by cyclone type electrowinning method.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2015.11a
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• pp.219-220
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• 2015

주석도금폐액으로부터 이온교환수지를 이용하여 주석을 회수하는 연구를 하였다. 주석 흡착이 가능한 3종류의 이온교환수지를 사용하여 기초 실험한 결과 tertiary기능기를 가진 이온교환수지는 주석을 흡착하지 못하였고, iminodiacetic 기능기를 가진 이온교환수지는 주석의 흡착률은 높으나, 불순물 함량이 높았으며, ethylhexyl-phosphar의 기능기를 가진 이온교환수지는 주석의 흡착률은 낮으나 pH 조절에 따라 불순물의 제어가 가능하였다.

• Environmental engineer
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• s.179
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• pp.72-76
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• 2001

본 연구의 목적은 기존 혼합도금폐수 처리공정의 문제점(현재 도금폐수처리시 사용되고 있는 알칼리 염소법은 작업장내의 기기 부식, 작업환경 열악, 배출수 내의 활성염소 잔류 및 폐수처리 공정의 적정화 미흡)을 해결하고 폐수처리 공정에서 유해 물질을 즉시 분석할 수 있는 정량제를 국산화하여 국내의 도금폐수 처리공장에 보급하는 것이다. 개발한 기술은 기존 도금폐수 처리공정에서 사용하고 있는 과다한 차아염소산소다 사용법을 대체한 기술로 처리공정의 적용법이 간단하

• Resources Recycling
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• v.22 no.3
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• pp.91-99
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• 2013

Steel industry which has been accomplishes the base of our country economy, automobile and electronic industry are taking charge of the role, whose electroplating is important. Large amount of wastewater and various metal salts, including hazardous materials was generated from the electroplating pre-treatment, plating, washing and post-plating. Currently, the general wastewater follows in the environmental law and neutralization after controlling, sludge where the various metal is mixed reclaims below multiple regulative and trust it is controlling. The sludge which includes the gas price metal reclaims in the field and trust it controls. a reclamation price of land it is insufficient but and the control expense holds plentifully and it loses the gas price metal which is valuable. Consequently, The research regarding to recover a gas price metal actively from this waste water, it is advanced. A new method to recover valuable metals from electroplating wastewater synthesis of metal sulfides using topical methods utilizing iron oxidizing bacteria, reagent of sulfides and solvent extraction using an organic solvent, such as the development of the law to recover these metals and metal sulfides of wastewater using selective recovery have been studied. By using these wastewater treatment method under frequency above 95%, it has been obtained the valuable metal from the wastewater, where the metal ion of Fe, Cu, Zn and Ni complexes was mixed. As we discuss the wastewater, which has been discharged from electroplating process, it is important and will be applied to the resources of metal in the urban mine.

• Resources Recycling
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• v.24 no.3
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• pp.51-58
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• 2015

In order to recover tin from the waste tin plating solution, we used the ion exchange method using three types of ion exchange resins. The ion exchange resin with tertiary functional group(Lewatit TP 272) has not adsorption ratio of tin. The ion exchange resin with iminodiacetic functional group(Lewatit TP 207) has high adsorption ratio of tin, but impurity content in the recovered tin solution was relatively high. Whereas, in case of the ion exchange resin with functional group of ethylhexyl-phosphate(Lewatit VP OC 1026), adsorption ratio of tin was less than that of Lewatit TP 207. However, it was possible to remove impurities in the recovered tin solution by controlling the pH of the solution. High purity tin solution can be recovered by removing the organic materials with water washing process.

• Journal of the Korean institute of surface engineering
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• v.12 no.2
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• pp.123-128
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• 1979

本교는 原調査報文 Plating and Surface Finishing;Recovery Pay! Vol 66. No2. (1979) 45~48P을 번역한 것으로 도금폐수의 회수재생에 드는 비용과 장치비 그리고 미국에 있어서의 도금공장의 폐수 회수처리 현황을 알아보는데 참고가 되리라 믿는다.(역자주) Plating and Surface Finishing지의 조사결과는 폐액회수장치를 설치한 도금공장회사들이 화공약품을 절약할 수 있었고, 공장폐수 내에 중금속 함유량의 한계치를 넘지 않도록 하는데 화학처리 비용을 들이지 않거나 최소한 줄일 수 있었다는 사실을 나타내 주고 있다.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.1
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• pp.1-7
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• 2016

In order to treat electrolysis nickel plating pickling wastewater to meet the effluent limit less than 3.0 mg/L, the electrolysis process by using soluble and insoluble electrode were studied. Electrolysis using soluble electrodes has a characteristic of easy elution from the electrode which the insoluble electrodes close not release metal from the electrode. For these reasons, there exist different characteristics in nickel removal efficiency, purity of nickel sludge. With this connection, the feasibility test were concluded to develop optimal conditions for the treatment of pickling wastewater electrolysis by using soluble electrodes, insoluble electrodes. Optimal condition of current density, pH were derived from the pickling wastewater using insoluble electrodes. It was concluded the highest removal efficiency of nickel at the operation condition of at pH 9, current density of $15mA/cm^2$. At these conditions, 95.3% purity of nickel sludge was achieved, iron content was 2.9%. Optimal condition when using soluble electrodes was derived current density of $10mA/cm^2$, pH 9. Purity of nickel sludge was 77.3%, iron content was 21.0%. 50.7% and 24.2% of operating cost can be saved by the use of soluble electrodes and the use of insoluble electrodes, respectively.