• Title/Summary/Keyword: 대구대학교

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Effect of Uncoordinated Tertiary Nitrogen Atoms in Hexaaza Macrocyclic Nickel(II) Complexes on Axial Binding of Anions and Water in Acidic Solutions

  • 김성진;최장식;강실걸;김창수;백서병현
    • Bulletin of the Korean Chemical Society
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    • v.16 no.3
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    • pp.217-221
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    • 1995
  • Axial coordination of anions or water to the square-planar nickel(Ⅱ) complexes of the hexaaza macrocyclic ligands 1, 2, and 3, which contain two extra uncoordinated tertiary nitrogens, have been investigated in aqueous solutions containing HX (X=Cl-, Br-, NO3-, or ClO4-) and/or NaX. The nickel(Ⅱ) complexes exist in the acidic solutions as equilibrium mixtures of the square-planar [Ni(L)]2+ (L=1, 2, and 3) and octahedral species [Ni(H2L)X2]2+ (H2L=diprotonated form of L). Some octahedral complexes have been isolated and characterized. The solution behaviors of the complexes indicate that the formation of the octahedral complexes are significantly promoted by the protonation of the uncoordinated tertiary amines. The proportion of the octahedral complexes depends on the type of acid, and increases in the order of HBr < HNO3 < HCl.

In-door Location-based Service Platform with WPAN for Electric Wheelchairs (WPAN을 이용한 전기 휠체어용 실내 위치 기반 서비스 플랫폼)

  • Nam, Young Jin;Park, Young Kyun;Kang, Sin Jae;Jung, Ju Seok;Kim, Beom Joon;Choi, Byeong Jun
    • Proceedings of the Korea Information Processing Society Conference
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    • 2010.04a
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    • pp.123-126
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    • 2010
  • 장애인 및 노인인구의 증가로 이동성의 확보를 위해 일반 휠체어를 포함한 전기휠체어 사용자가 증가하고 있다. 본 논문에서는 실내에서 장애인 및 노약자가 휠체어를 사용 시 대처하기 어려운 갑작스러운 위험 등에 대해 보다 효율적인 관제 및 관리를 위한 위치 기반 서비스 플랫폼을 제시하며, 실험을 통해 기능 및 성능을 검증한다. 제안하는 플랫폼은 단순 관제, 관리뿐만 아니라 사용자가 원하는 목적지까지 경로를 안내하며 사용자의 스케줄에 따라 목적지를 알려주는 등 생활 전반에 도움이 될 수 있다.

Development of industrial wireless temperature System (산업용 무선온도측정 시스템 개발)

  • Ryu, Jeong-Tak;Cha, Bu-Sang;Kim, Yeon-Bo;Moon, Byung-Hyun
    • Journal of Korea Society of Industrial Information Systems
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    • v.14 no.1
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    • pp.90-94
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    • 2009
  • In this parer, we give attention to a wireless temperature measurement system using in industrial site. Therefore, we developed and designed the remote measurement system for an industrial environment. To examine an application possibility of a industrial environment, we analyzed a temperature characteristic of wireless temperature system according to a measurement distance, and discussed about a performance difference according to an antenna change.