• Title/Summary/Keyword: 단사정 $ZrO_2$

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The Study on the Improvement of the Strength and the Thermal Shock Resistance of $Al_2O_3-ZrO_2$ Composites ($Al_2O_3-ZrO_2$ 복합체의 강도 및 열충격 저항의 향상에 관한 연구)

  • Hwang, K.H.;Bae, W.T.;Choi, M.D.;Oh, K.D.;Kim, K.U.;Kim, H.
    • Journal of the Korean Ceramic Society
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    • v.25 no.3
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    • pp.225-230
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    • 1988
  • The strength and thermal shock resistance of $Al_2O_3-ZrO_2$ composites have been studied. The tetragonal $ZrO_2$ powder containing 1 mol.% $Y_2O_3$ and monoclinic $ZrO_2$ powder were prepared by coprecipitation method and subsequently mixed with $Al_2O_3$ powder and granulated by sieving. Duplex composites were prepared by dry mixing matrix agglomerate with 15 to 30 vol.% of dispersion agglomerate, followed by pressing and sintering at 1$600^{\circ}C$ for1 hr. These $Al_2O_3-ZrO_2$ 2 composites having heterogeneous structure showed improved thermal shock behaviors because of the microcracking and pores in dispersed granules, and compressive stresses around dispersed granules resulting from $ZrO_2$ transformation.

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(Effect of Monoclinic Zirconia and Tetragonal Zirconia Addition on Physical Properties and Electrical conductivity of $Al_2O_3$) ($Al_2O_3$의 물리적 성질 및 전기전도도에 미치는 단사정 지르코니아와 정방정 지르코니아의 첨가효과)

  • 박재성;어수해
    • Journal of the Institute of Electronics Engineers of Korea TE
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    • v.39 no.1
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    • pp.1-8
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    • 2002
  • The effects of the addition of either monoclinic $ZrO_2$($ZrO_2$(m)) or tetragonal $ZrO_2$($ZrO_2$(t)) containing 5.35wt% $Y_2O_3$ on the physical properties and electrical conductivity of TEX>$Al_2O_3$ were investigated. The addition of $ZrO_2$(m) and $ZrO_2$(t) increased sintered density of $Al_2O_3$. The Vickers hardness also increased as addition of >($ZrO_2$(t) increased going through a maximum at 20wt% and the hardness of the specimens was found to be dependent on the sintered density. The addition of $ZrO_2$(t) improved the hardness of $Al_2O_3$-$ZrO_2$ systems and the $ZrO_2$(m) addition showed the better effect on the thermal shock property of $Al_2O_3$-$ZrO_2$ systems than that of the $ZrO_2$(t) addition. Above 15wt% addition of $ZrO_2$(t), the electrical conductivity is gradually increased with increasing applied voltage but not effects by addition of $ZrO_2$(m).

Environmental Effect on Corrosion Behaviour of Zr-2.5Nb Alloy (Zr-2.5Nb 합금의 부식거동에 미치는 부식 매질 효과)

  • Ju, Gi-Nam;Gwon, Sang-Cheol;Kim, Yeong-Seok
    • Korean Journal of Materials Research
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    • v.8 no.1
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    • pp.3-9
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    • 1998
  • 40$0^{\circ}C$ H$_{2}$O, D$_{2}$O및 $O_{2}$분위기에서 Zr-2.5Nb합금의 부식거동을 분석하였다. Martensitic $\alpha$'-Zr상이나 $\alpha$-Zr과 $\beta$-Zr상의 Zr-2.5Nb합금인 경우, 부식분위기에 매우 민감하여, $O_{2}$속에서 가장 큰 부식속도를 보였다. 반면, $\alpha$-Zr나 $\beta$-Zr상의 경우, 부식 매질에 따른 별다른 차이없이 높은 부식저항성을 보였다. 이러한 Zr-2.5Nb 합금의 미세조직 및 부식 매질에 따른 부식거동변화는 Zr-2.5Nb 합금의 음극 지배 부식반응의 관점으로 해석되었으며, 이들 결과를 이용하여 CANDU 형및 RBMK 형 Zr-2.5Nb 압력관의 가동조건 차이를 설명할 수 있었다. Zr-2.5Nb 합금의 모든 조직에서 주로 단사정 ZrO$_{2}$산화물이 형성되었으며, 산화물내 정방정 ZrO$_{2}$비율은 산화물 두께가 증가함에 따라 감소하였다.

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Crack Formation and Propagation Behavior of $Al_2$$O_3$/$ZrO_2$Laminate Composites ($Al_2$$O_3$/$ZrO_2$적층복합체의 균열생성 및 전파거동)

  • 방희곤;박상엽
    • Journal of the Korean Ceramic Society
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    • v.37 no.11
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    • pp.1058-1064
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    • 2000
  • 연속슬립캐스팅 및 상압소결법으로 $Al_2$O$_3$/ZrO$_2$적층복합체를 제조하였으며, 적층복합체에서 ZrO$_2$층을 단사정, 정방정 및 입방정으로 각각 달리 적층하여 균열생성 및 전파 거동에 미치는 ZrO$_2$상의 영향을 고찰하였다. 균열 생성은 냉각시 $Al_2$O$_3$층과 ZrO$_2$층 간의 열팽창 계수의 차이에 의한 열적불일치응력이 가장 큰 요인으로 작용하였다. 적층체 내에 존재하는 균열은 tetra-ZrO$_2$의 경우 적층두께 조절로 가능하였으며, cubic-ZrO$_2$의 경우는 냉각속도 조절로 균열밀도로 크게 낮출 수 있었다. $Al_2$O$_3$/ZrO$_2$적층체를 구성하는 세가지 ZrO$_2$상(mono, tetra, cubic)들 중에서 cubic-ZrO$_2$가 포함된 적층체의 경우 $Al_2$O$_3$와 ZrO$_2$계면에 형성된 잔류압축응력으로 인한 균열굴절 효과를 얻을 수 있었다.

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A Study on the Alumina Ceramic Composite Dispersed With the Zirconia (지르코니아-알루미나 세라믹 복합재료에 관한 연구)

  • Park, Jae-Sung;Lee, Yeong-Sin
    • 전자공학회논문지 IE
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    • v.49 no.2
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    • pp.1-8
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    • 2012
  • The effects of the addition of either monoclinic $ZrO_2(pure)$ or tetragonal $ZrO_2$ containing 5.35wt% $Y_2O_3(Y-TZP)$ on the mechanical properties and thermal shock resistance of $Al_2O_3$ ceramics were investigated. The addition of $ZrO_2$(m) and Y-TZP increased sintered density of $Al_2O_3$. The Vickers hardness also increased as the volume fraction of Y-TZP increased going through a maximum at 20wt%. The hardness of the specimens was found to be dependent on the sintered density. The higher volume fraction of either $ZrO_2(m)$ or Y-TZP resulted in the higher fracture toughness of the composite was. This result may be taken as evidence that toughening of $Al_2O_3$ can be achieved by not only the transformation toughening but microcrack toughening of $ZrO_2$. The thermal shock property for $Al_2O_3-ZrO_2$ composites was improved by increasing the volume fraction of monoclinic $ZrO_2(pure)$. The grain size increased as the volume fraction of $ZrO_2$ did.

A Study of Crystallization and Fracture Toughness of Glass Ceramics in the ZrO2·SiO2 Systems Prepared by the Sol-Gel Method (졸-겔법으로 제조한 ZrO2·SiO2계 결정화 유리의 결정화 및 파괴인성에 관한 연구)

  • Shin, Dae-Yong;Han, Sang-Mok;Kang, Wie-Soo
    • Journal of Industrial Technology
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    • v.20 no.A
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    • pp.247-256
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    • 2000
  • Precursor gels with the composition of $xZrO_2{\cdot}(100-x)SiO_2$ systems (x=10, 20 and 30 mol%) were prepared by the sol-gel method. Kinetic parameters, such as activation energy, Avrami's exponent, n, and dimensionality crystal growth value, m, have been simultaneously calculated from the DTA data using Kissinger and Matusita equations. The crystallite size dependence on tetragonal to monoclinic transformation of $ZrO_2$ was investigated using XRD, in relation to the fracture toughness. The crystallization of tetragonal $ZrO_2$ occurred through 3-dimensional diffusion controlled growth(n=m=2) and the activation energy for crystallization was calculated using Kissinger and Matusita equations, as about $310{\sim}325{\pm}10kJ/mol$. The growth of $t-ZrO_2$, in proportion to the cube of radius, increased with increasing heating temperature and heat-treatment time. It was suggested that the diffusion of Zr4+ions by Ostwald ripening was rate-limiting process for the growth of $t-ZrO_2$ crystallite size. The fracture toughness of $xZrO_2{\cdot}(100-x)SiO_2$ systems glass ceramics increased with increasing crystallite size of $t-ZrO_2$. The fracture toughness of $30ZrO_2{\cdot}70SiO_2$ system glass ceramics heated at $1,100^{\circ}C$ for 5 h was $4.84Mpam^{1/2}$ at a critical crystaliite size of 40 nm.

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Fabrication and Physical Properties of ZrO2(m)-Al2O3ZrO2(t)-Al2O3 Structural Ceramics (ZrO2(m)-Al2O3ZrO2(t)-Al2O3 세라믹스의 제조와 물리적 특성)

  • Park, Jae-Sung;Park, Ju-Tae;Park, Jung-Rang
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.4
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    • pp.140-148
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    • 2010
  • The effects of the addition of either monoclinic $ZrO_2(ZrO_2(m))$ or tetragonal $ZrO_2(ZrO_2(t))$ containing 5.35[wt%] $Y_2O_3$ on the physical properties and electrical conductivity of $Al_2O_3$ were investigated. The addition of $ZrO_2$(m) and $ZrO_2$(t) increased sintered density of $Al_2O_3$. The Vickers hardness also increased as addition of $ZrO_2$(t) increased going through a maximum at 20[wt%] and the hardness of the specimens was found to be dependent on the sintered density. The addition of $ZrO_2$(t) improved the hardness of $Al_2O_3-ZrO_2$ systems and the $ZrO_2$(m) addition showed the better effect on the thermal shock property of $Al_2O_3-ZrO_2$ systems than that of the $ZrO_2$(t) addition. Above 15[wt%] addition of $ZrO_2$(t), the electrical conductivity is gradually increased with increasing applied voltage but not effects by addition of $ZrO_2$(m).

Fabrication of high purified zirconium dioxide (ZrO2) and stabilized zirconia (TZP: tetragonal zirconia polycrystal) powders (고순도 산화지르코늄(ZrO2) 및 안정화 지르코니아 (TZP: tetragonal zirconia polycrystal) 분말제조)

  • 최의석
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06b
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    • pp.55-85
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    • 1996
  • 지르코니아 분말은 ZrO2 결정상이 온도변화에 따라 부피변화를 수반하는 상전이변태를 나타낸다. 단사정 ZrO2가 110$0^{\circ}C$에서는 정방정으로, 2$700^{\circ}C$ 내외에서는 입방정으로 결정구조가 가역적으로 변한다. 이 ZrO2에 금속산화물을 고용시키면 형석 (CaF2:Florite)형의 입방정 결정구조가 실온에서도 안정하게 존재하게 된다. 안정화제 산화물은 caO, MgO등 2가 산화물외에 3가 또는 4가의 금속산화물로서 Sc2O3, Y2O3, Sm2O3, Nd2O3, Gd2O3, Y2O3, CeO2 등이며 이들은 금속이온의 원자가가 변하기 쉬운 희토류 산화물이다. 안정화 지르코니아는 형석형 결정구조이며 결정화학적으로 보면 금속양이온이 산소이온에 대해서 정육면체형의 8배위를 하고 있다. 이때 이온반경비(양이온/음이온)에 따라 Zr+4자리와 O-2자리의 격자위치와 모양이 형성되므로 비틀어진 정육면체구조이건 이상적인 정육면체 형석구조를 이룬다. 이는 지르코니아의 결정상의 2상-3상인 부분안정화 지르코니아다결정체(PSZ : partially stabilized zirconia)이거나 단일상-2상인 정방정 지르코니아다결정체(TZP : tetragonal zirconia polycrystal)의 결정구조를 가지는데 기인한다. PSZ는 주로 MgO, CaO를 안정화제로 고용시켜 입방정 영역에서 소결하고 이를 다시 입방정과 정방정의 상 영역에서 열처리하여 입방정 입자내부에 정방정을 석출 형성시킨 것이며 TZP는 Y2O3 및 CeO2를 고용시켜 PSZ와 다르게 일반적인 상압소결한 정방정 결정상의 미립자이다. 산화지르코늄 분말은 지르콘사에서 열분해시킨 지르코늄소결.융해괴(caustic fusion clinker)를 산처리하여얻어진 지르코늄산용액(zirconyl acid solution : cloride, sulfide, nitride 등)으로부터 제조된다. 고순도 산화지르코늄은 용액 결정석출법에 의해 ZrOCl2.8H2O, 5ZrO2.3SO3.15H2O, ZrO(NO3)2.xH2O 등의 지르코늄 수화물만을 재결정화시킨 것으로부터 얻을 수 있으며 이 지르코늄염 수용액으로부터 입자미세구조를 효과적으로 제어하여 산화지르코늄 및 안정화 지르코니아 분말제조가 가능하다. 안정화 지르코니아 분말은 ZrO2와 안정화산화물의 고용을위하여 가열처리를 필요로 하며 일정온도에서 최적상태로 숙성하므로서 2가지 상(phase) 이상의 고용체를 가지게 된다. 안정화 지르코니아 분말은 고용처리온도를 낮추고 효과적으로 생성시키기 위해서는 지르코늄 및 안정화제염을 혼합하고 습식 직접합성하여 저온에서 고용체의 합해진상 영역을 생성시키는 것이다. 이는 지르코니아 원료분말의 미세구조를 제어하므로서 가능하며 이때 화학성분조성과 크기형태가 균일하게 분포된 입자분말을 얻을 수 있다.

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Phase Transformation of 2 Components(CaO-, $Y_2O_3$-, MgO-$ZrO_2$) and 3 Components(MgO-$ZrO_2-Al_2O_3)$ Zirconia by X-ray Diffraction and Raman Spectroscopy (X-선회절과 Raman 분광분석을 이용한 2성분계(CaO-, $Y_2O_3$-, MgO-$ZrO_2$) 및 3성분계(MgO-$ZrO_2-Al_2O_3)$ Zirconia의 상전이연구)

  • 은희태;황진명
    • Journal of the Korean Ceramic Society
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    • v.34 no.2
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    • pp.145-156
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    • 1997
  • ZrO2 phase transformations depending on the type and amount of dopants and the sintering temperatures were studied for the 2 components (CaO-, Y2O3-, MgO-ZrO2) and the 3 components(MgO-ZrO2-Al2O3)ZrO2 powder by X-ray diffraction and Raman spectroscopy. In the CaO- and Y2O3-ZrO2 systems, as the CaO and Y2O3 contents increased to 6~15mol% and 3~15mol% respectively, we were not able to identify between tetragonal and cubic in the X-ray diffraction patterns. On the other hand, all Raman modes shifted to lower wavenumbers, decreasing in intensity and the number of bands, markedly. These phenomena were caused by tetragonallongrightarrowcubic phase transformation and interpreted by the breakdown of the wave vector selection rule(k=0) and the structural disorder associated with the formation of oxygen sublattice which was caused by the substitution between Zr4+ ion and Ca2+ or Y3+ ion in ZrO2 matrix. The monoclinic to cubic phase transformation occurred in 10mol% MgO-ZrO2 system. As the Al2O3 content increased from 0 to 20mol% in the MgO-ZrO2-Al2O3 systems, cubic phase transformed to monoclinic phase, this is because the MgO didn't play a role in a stabilizer because of the formation of the spinel(MgAl2O4) by the reaction between MgO and Al2O3, Also, the ZrO2 phase transformation was explained by the change of it's lattice parameters depending on the type and amount of dopants. Namely, as the amount of dopant increased to 10~13mol%, the axial ra-tio c/a came close to unity with increasing the lattice parameter a and decreasing the lattice parameter c. At that time, the tetragonallongrightarrowcubic phase transformation occurred.

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Characteristic and Adhesive Strength Change by Heat Treatment of the Plasma Sprayed $ZrO_{2}$- Thermal Barrier Coatings(TBC) (플라즈마 용사된 $ZrO_{2}$-단열 코팅층의 특성 및 열처리에 따른 접합강도변화)

  • Kim, Byoung-Hee;Suhr, Dong-Soo
    • Korean Journal of Materials Research
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    • v.8 no.6
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    • pp.505-512
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    • 1998
  • In this study, two-layer thermal barrier coatings composed of plasma sprayed 0.3mm $ZrO_2(8wt% Y_2o_3)$ ceramic coating layer and O.lmm $NiCrAlCoY_20_3$ bond coating layer on AISI 316 were investigated microstructure of the coating, oxidation of the metallic bond coating and adhesive strength to evaluate the durability of coating layer after cyclic and isothermal test at 90$0^{\circ}C$. And quantitative phase analysis of $ZrO_2(8wt% Y_2o_3)$ ceramic coating was performed as a function of thermal exposure time using XRD technique. The results showed that the amount of m - 2rO, phase in the coating was slightly increased with increasing thermal exposure time at 90$0^{\circ}C$. The c/a ratio of t' - $ZrO_2$ in the as-sprayed coating was 1.0099 and slightly increased to 1.0115 after 100 hours heat treatment. It was believed that $Y_2O_3$ in high yttria tetragonaJ(t') was transformed to low yttria tetragonaJ(t) by $Y_2O_3$ diffusion with increasing thermal exposure time. The adhesive strength was gradually decreased as thermal exposure time increased. After the isothermal test, the failure predominantly occured in ceramic coating layer. On the other hand. the specimens after cyclic thermal test were mostly failed at bond coating/ceramic coating interface. The failure was oeeured by decreasing the bond strength between bond coating and oxide scale which were formed by oxidation of the metallic elements within bond coating and by thermal stress due to thermal expansion mismatches between the oxide scale and ceramic coating.

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