• The Korean Journal of Pesticide Science
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• v.7 no.4
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• pp.264-270
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• 2003

To control effectively and safely Phytophthora root rot caused by Phytophthora capsici on tomato in hydroponic culture, tank-mixing method was considered with two pesticides, metalaxyl copper oxychloride 50% WP and dimethomorph dithianon 38% WP. Forty days after transplanting of tomato seedlings, 4 mL of sporangia of P. capsici (about 25 sporangi/mL) per plot was inoculated around tomato plant roots, and at 5 days after inoculation, the pesticides tank-mixed at three dilution levels, 12,500, 25,000 and 50,000, were drenched 1, 2 or 3 times per plot on the culture cube every 15 days for metalaxyl copper oxychloride 50% WP and every 10 days for dimethomorph dithianon 38% WP. During the drenching period, the residue levels of metalaxyl and dimethomorph in hydroponic culture solution were similar to the initial levels but the level of dithianon was drastically decreased from one day after tank-mixing. In tomato drenched with metalaxyl copper oxychloride 50% WP, metalaxyl was detected $0.02\sim0.04$ mg/kg in all diluted plots. Dimethomorph was detected $0.012\sim0.021$, $0.001\sim0.006$ and $0.001\sim0.003$ mg/kg in 12,500, 25,000 and 50,000 times diluted plots, respectively, while dithianon was detected 0.005, 0.003 mg/kg in 12,500 and 50,000 times diluted plots, respectively. The detection levels of three pesticides were far below compared with the levels of Korean MRLs. Incidences of Phytophthora root rot were not found in all the plots, but phytotoxic responses were recognized in the 12,500 times diluted plots of both pesticides. Based on the above results, the drenching of the culture solution tank-mixed with these pesticides could be recommended as a very safe and effective method to control Phytophthora root rot in tomato in hydroponic culture.

• The Korean Journal of Pesticide Science
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• v.7 no.3
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• pp.182-187
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• 2003

In order to elucidate a degradation characteristics of herbicide mefenacet in soil, the persistence in soils was studied under laboratory conditions for $90\sim120$ days at $28^{\circ}C$. Mefenacet residues were determined from the two soils which pre-treated by sterilization and flooding, respectively. Non-sterilized upland soil was used as a control. When 70 days elapsed from application time, $55\sim63%$ of mefenacet applied were dissipated in control soils. However, $32\sim33%$ of mefenacet applied were dissipated in the sterilized soils and $33\sim35%$ was dissipated in the flooded soils. 까 lese results indicated that the degradation of mefenacet was assumed to be due to microorganism, especially aerobic microbes. In order to elucidate the influence of water content on the persistence of mefenacet in soil, water content in soils was adjusted to 20, 50, and 80% of the water-holding capacity(Field capacity, WHC). The half-life of mefenacet in soil containing 20% and 50% of WHC were 82 and 73 days, respectively, after incubation for 90 days. However, the half-life in soil containing 80% of WHC was shortened to 61 days. These results indicated that degradation of mefenacet in soil was influenced by the activity of soil microorganism, organic matter content and water content.

• The Korean Journal of Pesticide Science
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• v.7 no.3
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• pp.169-175
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• 2003

For safe and easy disposal of prochloraz wastewaters after used as rice seed disinfectant in Korean farms, this experiment was carried out. By addition of several agricultural materials commonly utilizing in farmers, removal effect of prochloraz from waste solution was also investigated. When rice seeds after soaking in diluted prochloraz solution were rinsed with water several times, prochloraz was removed $9.2\sim10.6%$ at the first rinse and less than 3 % at the fourth rinse. A half life of prochloraz was $4\sim5$ days in aqueous system. Hydrolysis of prochloraz was more rapidly in alkali solution than neutral and acidic one at $25^{\circ}C$ and $35^{\circ}C$. By the irradiation under $5530J/cm^2$ using xenone lamp, prochloraz was photo-degraded to 87.7% in aqueous system. The removal efficiency of prochloraz by addition of several agricultural materials were as follows: 93.6% by lime, 90.7% by composed pig manure, 89.4% by activated charcoal, 78.0% by straw ash, 70.3% by sandy loam soil, 47.0% by zeolite and 24.1 % by rice straw. When prochloraz solution was sprayed on the field soil, it was dissipated upto 90% within 35 days.

• Proceedings of the Plant Resources Society of Korea Conference
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• 2011.10a
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• pp.3-3
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• 2011

국내 주요 인삼재배 산지 기반을 가진 전북 진안지역의 인삼 홍삼산업은, 재배농가 895호, 재배면적 402ha, 생산량 1,628톤, 홍삼가공업체 80개소, 판매업소 50개소로 지역경제의 25% 이상을 차지한다. 그러나 재배농가의 계열화 미흡(22%), 산지수집상(포전매매)에 의한 인근 유사 도매시장으로 재배물량과 부가가치 유출(78%), 가공시설의 노후화, 가공업체의 영세성(매출규모 연평균 2억11백만원)과 함께 중국, 캐나다, 미국 등의 국제 가격경쟁과 국내의 대기업 및 인삼산업 주요지역과의 경쟁이라는 상황에 직면하고 있다. 이러한 상황을 극복하고 지역특화명품산업으로 발전할 수 있는 방안으로, 인삼재배산지로서 원료공급지를 기반으로 하는 재배, 유통, 가공, 품질관리, 시설분야에 이르는 발전방안을 연구하였다. 산업원료 확보를 위해서는 인삼계열화 확대를 통해 원물 확보력을 강화하여야 한다. 재배분야의 경우에는 친환경재배 확대와 GAP 확대를 통해 원물의 품질경쟁력 뿐만 아니라 시장수요에 따른 브랜드마케팅 요인으로 특성화해야 한다. 유통분야는 계열화 확대를 통한 원물확보라는 산업경쟁력을 바탕으로 원료중심의 수취, 매취, 보관, 가공, 대형거래, 도소매 등 유통활성화와 유통규격포장 및 선별등급표준화를 통한 유통표준화를 추진하여야 한다. 가공의 경우, 원료홍삼 공급기능을 중심으로 가공산업을 선택 육성해야한다. 품질관리는 원물중심관리(성분, 잔류농약, 식품위생), 유통중심관리(연근, 등급), 경작중심관리(재배지, 재배자, 경작), 프로세스중심관리(재배 유통 가공 판매정보)로 구체화해야한다. 시설분야는 유통시설(대규모 집하시설, 보관시설 등 종합유통처리시설)과 가공시설(가공설비현대화, 가공공장 공인규격화;ISO, GMP, HACCP)의 지속적인 시설개선과 현대화를 추진하여야 한다.

• Proceedings of the Korea Water Resources Association Conference
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• 2011.05a
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• pp.465-465
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• 2011

강우가 발생하거나 관개를 함에 따라 농경지의 토양침식물, 잔류 비료나 농약 등의 비점오염원은 지표 및 지하 유출과 함께 거동함으로써 지표수 뿐 아니라 지하수 수질에도 영향을 미칠 수 있다. 특히, 최근 고부가가치 농산물 수요의 증가로 전국적으로 시설재배 농업이 확대되고 있으나 시설재배 내에서의 비점오염원 유출특성에 관한 연구는 미흡하다. 따라서 시설재배 농업과 관행농업의 비점오염원의 거동 및 지하침투 오염부하를 비교 평가하고 비점오염원을 저감하기 위한 적절한 방안 마련이 필요하다. 따라서 본 연구에서는 시설 및 관행재배 지역의 지하침투 오염부하량을 평가하기 위하여 주변 영향이 배제되어 시설재배와 관행재배의 비교 평가 가능한 포장 및 광역 단위 시험포장을 선정하고 모니터링 시스템을 구축하였다. 먼저 필지 단위와 광역 단위 단위에서의 모니터링 시스템을 설계하고, 수문 및 수질 분석 항목을 설정하였다. 이를 바탕으로 관행재배지에서의 물수지 모니터링을 위하여 기상 및 강우량, 지하수위, 토양수분, 관개 및 배수량을 측정하기 위한 장비를 설치하고, 토양수 및 지하수의 물질 수지 분석을 분석하기 위한 토양수, 지하수, 논담수 등의 수질 샘플망을 구축하였다. 또한 시설재배지에서의 물수지 모니터링을 위하여 기상, 지하수위, 토양수분 및 관개량을 측정하기 위한 장비를 설치하고, 토양수 및 지하수의 물질 수지 분석을 분석하기 위한 토양수, 지하수, 관개용수 등의 수질 샘플망을 구축하였다. 향후 본 시험 포장에 대한 지속적인 모니터링과 샘플링 실시하여 다양한 항목에 대한 조사 및 분석이 이루어진 다면 시설재배지 비점오염원 모니터링 및 정량화 기술개발을 통해 시설재배지에서의 비점오염에 대한 정량적 자료구축이 가능할 것으로 판단되며, 기초적인 자료를 제공함으로써 국내 농업비점오염총량 추정 기술에 기여할 수 있을 것으로 판단된다.

• Ocean and Polar Research
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• v.28 no.3
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• pp.317-329
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• 2006

To assess the contamination status of organochlorine pesticides in the marine environment of Saemangeum, surface seawater and sediments were collected and analyzed. Organochlorine pesticides were widely distributed in the Saemangeum environment, with DDT, HCH and endosulfan II contamination being particularly prevalent. The overall concentrations of DDTs, HCHs, and endosulfan II in surface seawater were in the rage of 0.03-0.65ng/l (mean value: 0.36ng/l), 1.31-4.54ng/l (2.63 ng/l), and not detected (ND)-0.96ng/l (0.49ng/l), respectively. Among the target organochlorine pesticides, endosulfan II showed the hi띤est level at the river mouth flowing into the Saemangeum. Additionally, its negative gradient from the rivers to the outside and a good correlation with $NO_3^-$ indicate that endosulfan ll inflows to the Saemangeum through the river; this conclusion is also supported by the elevated levels of endosulfan II in sediments at the river mouth. In sediment, the concentration of DDTs, HCHs, CHLs, and endosulfan II were in the range of 0.05-1.96 ng/g, 0.03-0.31ng/g, 0.01-0.13ng/g, and ND-0.62ng/g, respectively. Levels of contamination in Saemangeum are relatively lower than the median concentrations previously observed at the Korean coastal regions and sediment quality guidelines suggested by NOAA (Long et at. 1995).

• Korean Journal of Environmental Agriculture
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• v.39 no.4
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• pp.305-311
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• 2020

BACKGROUND: The healthy food trend has encouraged the consumption of natural products, including berries. This trend is expected to increase the strawberry consumption. There has been a concern about the exposure of pesticides approved for use on strawberry. In this study, the dissipation patterns of systemic and non-systemic pesticides were evaluated in strawberry under plastic-covered greenhouse conditions. METHODS AND RESULTS: Cyflumetofen and dimethomorph were applied on strawberry in the critical GAP (Good Agricultural Practices). Strawberries were harvested at 0, 1, 2, 3, 5, 7 and 10 days after final application of the pesticides. The analyses of the residual pesticides were performed by HPLC-DAD with C18 column. The limits of quantitation (LOQ) of cyflumetofen and dimethomorph were 0.04 and 0.02 mg/kg, respectively. The recovery of cyflumetofen and dimethomorph were 88.1 ~ 103.3% and 79.0 ~ 110.2% for the spiked two levels (LOQ and 10LOQ), respectively. The biological half-lives of cyflumetofen and dimethomorph werer 7.5 and 8.9 days, respectively. The dissipation rates in strawberry were calculated by the statistics method at a 95% confidence level. The distribution showed that pesticides with low log Pow were indicated by the decreased dissipation rate and pesticides with similar log Pow and low solubility also showed the decreased dissipation rate. CONCLUSION: The residues of cyflumetofen and dimethomorph in strawberry at time 0 after the final application were below the established MRL in Korea. The dissipation behavior of systemic and non-systemic pesticides in strawberry is affected by their log Pow and water solubility values.

• Korean Journal of Medicinal Crop Science
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• v.28 no.6
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• pp.435-444
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• 2020

Background: As the Positive List System (PLS) is implemented in broad application to agricultural products, attention to the correct use of pesticides is also needed in the production of mulberry leaves and fruit. In this regard, three types of pesticides against mulberry popcorn disease were applied 2 - 3 times both in the field and greenhouses to prepare safety standards. Residual pesticide analysis was conducted on mulberry fruits and leaves. Methods and results: Three pesticieds, thiophanate-methyl, thiophanate-methyl·triflumizole and fluopyram registered as PLS pesticides for mulberry popcorn disease, were sprayed in the Wanju and in Buan regions, after which residual pesticide analysis was conducted using high-performance liquid chromatography (HPLC). As three pesticieds were either undetected or below the permissible level in mulberry fruit, demonstrating that they were suitable for safe spraying. However, 5.6 mg/kg of thiophanate-methyl was detected in the greenhouse after three application, which was slightly above maximum residue limit (MRL). Furthermore the level of thiophanate-methyl·triflumizole was higher than 0.2 mg/kg ("Gwasang No. 2" variety, spraying twice) or similar to 0.09 mg/kg ("Daesim" variety, spraying thrice) the permissible level (0.1T mg/kg) as the thiophanate-methyl was detected in mulberry leaves in the greenhouse. Conclusions: The spraying frequency for controlling mulberry popcorn disease in greenhouses should be limited to two times or less, especially when mulberry leaves are treated with thiophanate-methyl·triflumizole careful consideration is required if the leaves are to be used as food materials.

• Korean Journal of Environmental Agriculture
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• v.11 no.1
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• pp.1-8
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• 1992

New formulation of diazinon as granule preparing with piperonyl butoxide(PBO) and triphenyl phosphate(TPP) known as the inhibitor of monooxygenase(mo) and esterase was tested with the mortality of rice leaf hopper. Also, the mixed formulation of diazinon with tricyclazole, carbofuran and EPN were investigated about the residual pattern of diazinon in submerged soil condition at $30{\pm}2^{\circ}C$. Although the mortality about rice leaf hopper was higher only 10% on new formulation of diazinon than commercial at recommended dose but was 30-60% at half dose. Half life of diazinon in the formulation with 0.1% of PBO+TPP was 4.53 days in sterilized soil and 2.33 days in non-sterilized soil, and it was delayed about 0.74 and 0.45 respectively in contrast with the commercial granule. Also, half life of the new formulation with 1% PBO and PBO+TPP was delayed 0.44(PBO) and 0.65day(PBO+TPP) in non-sterilized soil condition, respectively. Half life of mixed formulation with tricyclazole, carbofuran, EPN or EPN+Carbofuran was delayed 2.61, 1.04, 0.43 or 2.7 days, respectively. As a result, the persistence rate of new formulation and mixed formulation was increased by inhibition of two enzymes affecting to the dgradation of diazinon in submerged soil.

• Korean Journal of Materials Research
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• v.8 no.7
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• pp.621-627
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• 1998

The formation of Co-silicide between Co/Zr bilayer on the amorphous and crystalline Si substrates has been investigated. The films of Zr(50$\AA$) and Co(l50$\AA$) were deposited with e-beam evaporation system and were heattreated with the rapid thermal annealing system at the temperatures between 50$0^{\circ}C$ and 80$0^{\circ}C$ with 10$0^{\circ}C$ increments for 30 seconds. The phase identification of Co-silicide was carried out by XRD and the chemical analysis was examined by AES and RBS. The interface morphologies of Co/Zr bilayer films were investigated by cross sectional TEM and HRTEM. $CoSi_2$ was formed epitaxially on the crystalline Si substrate above $700^{\circ}C$ while polycrystalline $CoSi_2$ was grown on the amorphous Si substrate. The formation temperature of Co-silicide on the amorphous Si substrate was about 100 C lower than that on the crystalline Si. The COzSi phase was not identified on the both Si substrates. The formation temperature of first phase of Co-silicide on ColZr bilayer was higher than that on Co mono layer. CoSizlayer formed on the amorphous Si substrate exhibits better uniformity compared to the CoSiz formed on the crystalline substrate. The sheet resistance of CoSiz layer on crystalline Si was lower than that on the amorphous Si at high temperatures.tures.