• Title/Summary/Keyword: 농도계

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Effects of Compost Amendment on Petroleum Hydrocarbon Removal and ATP Concentration in Bioremediation of Diesel Contaminated Soil (디젤오염토앙의 생물학적 복원에 있어서 유기질비료의 첨가가 석유계 탄화수소의 분해 및 ATP 변화에 미치는 영향)

  • Lee, Joo-Heon;Jun, Kwan-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.7
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    • pp.721-730
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    • 2006
  • The effects of compost amendment on the removal of petroleum hydrocarbons and the activities of microorganisms in soil ecosystem have been studied in bioremediation of diesel contaminated soil. The relation between biological activities and removal of petroleun hydrocarbon was determined by ATP(Adenisine Triphosphate), n-alkanes and TPH concentration analysis. After 80 days of bioremediation, the removal of TPH in soil amended with compost increased more than 10% compared with control soil which was tilled in the same condition without compost addition. The biodegradations of n-alkanes having 12 to 20 moles of carbon were distinctive. As the soil was contaminated with more diesel, the ATP has decreased rapidly. When the TPH amounted to 80,000 mg diesel/kg, the ATP decreased to 4 ng/g from initial concentration of 65 ng/g. While the ATP in the compost amended soil increased to 112 ng/g after tilling for 6 days, the ATP in the control increased to merely 36 ng/g after tilling for 14 days. Also while the control soil showed a lag time in ATP increase, the compost amended soil did not show that but showed a rapid ATP increase within a short time. The patterns of changes in ATP concentration were similar to those in daily removals of TPH with time difference of about 7 days.

Changes in Planktonic Communities and Environmental Factors between Open Versus Closed Artificial Marine Microcosms (개방형 및 폐쇄형 인공해양소형생태계에서 미소생물상 및 수환경의 변화)

  • Jung, Seung Won;Kang, Don-Hyug
    • Korean Journal of Environmental Biology
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    • v.33 no.4
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    • pp.403-411
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    • 2015
  • To understand differences of environmental factors and planktonic communities in closed (CS) versus open (OS) enclosed experimental systems, we performed a study on a 100-L indoor-type artificial marine microcosm. For environmental factors, including water temperature, dissolved inorganic phosphorus, and dissolved silica, there were no significant differences between CS and OS; however, salinity was higher in CS than that of OS due to the evaporation effect. The concentration of dissolved oxygen and dissolved inorganic nitrogen was lower in CS than in OS. The abundance of phytoplankton was lower in CS than in OS. However, abundance of autotrophic nanoflagellates and heterotrophic bacteria varied inversely with that of phytoplankton abundances. In particular, the abundance of heterotrophic nanoflagellates and ciliates increased with bacterial growth after a time lag. Therefore, environmental factors and planktonic communities in CS gradually changed over time and characterized a different artificial ecosystem than in OS.

The Prediction of Solvent Mutual Diffusion Coefficient Using Vrentas-Duda's Self Diffusion Theory (Vrentas-Duda의 자기확산이론을 이용한 용매의 상호확산계수 예측)

  • 김종수;이광래;김기창
    • Membrane Journal
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    • v.10 no.1
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    • pp.19-29
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    • 2000
  • To estimatc mutual diffusion coefficient for the analysis of mass transfer phenomena in polymer/solvent system, two models are proposed and the equations are derived. The estimates of mutual diffusion coefficients are obtained by two models suggested in this work and compared with and experimental data and Vrentas-Duda's. Vrentas-Duda's self diffusion coefficient was used for the mutual diffusion coefficient. Derivative of chemical potential on solvent was derived and used using original UNIFAC-FV and modified UNIFAC-FV. However, Vrentas-Duda's equation for mutual diffusion coefficient contains Flory-Huggins parameter x. For the derivative of chemical potential term, Vrentas-Duda assumed that parameter x was constant and independent of temperatures and concentrations The assumption is one of shortcoming in vrentas-Duda's mutual diffusion coefficient. New methods proposed in this work do not have such assumptions and simplifications. For the solvent of cyclohexane, n-pentane, and n-hexane in PIB(polyisolbutylene) and PMS-BR (poly(p-methylstyrene-co-isobutylene), new methods well correlate the experimental data at various temperatures and concentrations, and predicted the experimental data much better than Vrentas-Duda's for the PIB/toluene system. It is shown that new methods are excellent tools for correlating mutual diffusion coefficient data in polymer/solvent system over wide ranges of temperature and concentration without any assumptions or simplifications.

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An experimental study on the characteristic times of viscoelastic fluids by falling ball viscometer (낙구식 점도계를 이용한 점탄성 유체의 특성시간에 관한 실험적 연구)

  • 전찬열;유상신
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.1
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    • pp.241-250
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    • 1990
  • Characteristic relaxation time and characteristic diffusion time of viscoelastic fluids are determined experimentally by measuring the zero-shear-rate viscosity by falling ball viscometer and the infinite-shear-rate viscosity by capillary tube viscometer. Fluids used in experiments are aqueous solutions of polyacrylamide Separan AP-273 and the polymer concentrations range from 300 to 2000 wppm. A newly designed laser beam and timer system is employed to overcome the difficulty in measuring terminal velocities of the low concentration solutions. Ball removal device is prepared to remove the dropped ball from the bottom of cylinder without disturbing the testing fluid. In order to measure the zero-shear-rate viscosity, densities of hollow aluminium balls are adjusted very close to the densities of testing fluids. Characteristic diffusion time, which is ball viscometer. However, terminal velocity of a needle by falling ball viscometer is not affected by the time interval of dropping needles and characteristic diffusion time is not measured with a dropping needle. Powell-Eyring model predicts the highest values of the characteristic relaxation times among models used for heat transfer experimental works for a given polymer solution. As degradation of a polymer solution continues, the zero-shear-rate viscosity decreases more seriously than the infinite-shear-rate viscosity. Characteristic relaxation times of polymer solutions decreases as degradation continues.

Process conditions of valuable compound for benign prostatic hyperplasia(BPH) from saw palmitto by supercritical CO2 (초임계 CO2를 이용한 Saw palmitto로부터 전립선 비대 유효 성분의 추출 조건)

  • 류병호;조경자
    • Journal of Life Science
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    • v.13 no.5
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    • pp.569-575
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    • 2003
  • Supercritical $CO_2$ extraction was applied to extraction of the valuable compound for benign prostatic hyperplasia from saw palmitto. Three levels of parameters, temperature $(35^{\circ}C,\; 60^<\circ}C)$, pressure 22∼30 Mpa and ethanol modified solvent concentration, were used as the independent variables of central composite to rotate the design. The extracting pressure and temperature interaction was significantly affected the extraction of valuable compounds. The ethanol was an efficient modifier to extract valuable compound by supercritical carbon dioxide. The optimal processing conditions were extracting pressure, 30 Mpa, extracting temperature, $60^<\circ}C$, ethanol modifier, 15% for extracts of the valuable compounds from saw palmitto. In conclusion, it was found that supercritical $CO_2$ extraction can successfully be applied to extract high quality extracts from saw palmitto.

VOCs Permeation Property of Composite Hollow Fiber Membranes (중공사 복합막을 이용한 다성분계 휘발성 유기 화합물 투과 특성)

  • Choi, Whee Moon;Cho, Soon Haing;Kim, Soon Tae;Lee, Chung Seop;Nam, Sang Yong
    • Membrane Journal
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    • v.23 no.2
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    • pp.176-184
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    • 2013
  • To investigate the performance of VOC separation, composite hollow fiber membrane was prepared which composed of poly (ether imide) support prepared by phase separation method and poly (dimethylsiloxane) coating active layer. The performances of the membranes for the application of recovery process in terms of their morphology, gas permeance test for $N_2$ and $O_2$ gases. Durability against benzene, toluene and xylene was also investigated. And permeation test for multi-component VOCS through the membrane with different feed concentration and stage-cut were investigated. Permeance of PEI supported membrane and the membranes coated with PDMS decreased from 45,000 GPU to 63 GPU and 49,450 to 30 GPU for $N_2$ and $O_2$, respectively. Recovery efficiency and concentration of VOCs in permeate increased with decreasing stage-cut. VOCs concentration in permeate proportionally increased with increasing feed concentration but concentration ratio and recovery efficiency showed any noticeable changes with feed concentration change.

Properties of Bubble According to Types and Concentrations of Concrete Foaming Agent (콘크리트용 기포제 종류 및 농도에 따른 기포의 특성)

  • Kim, Jin-Man;Kwak, Eun-Gu;Oh, Kwang-Chin;Kang, Cheol
    • Journal of the Korea Concrete Institute
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    • v.23 no.2
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    • pp.151-158
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    • 2011
  • Bubbles within the foamed concrete manufactured by pre-foaming method is the main factor which affects the physical properties of foamed concrete such as density, strength, and porosity. Although many researches on foamed concrete have been continuously carried out, insufficient number of researches on the properties related to bubbles in the foamed concrete has been performed except for chemical application related researches. In order to make an optimal foamed concrete, study on the bubble properties must be pursued. In order to effectively implement bubbles in the manufacturing of foamed concrete, the bubble properties must be estimated. In this study, in order to determine the bubble properties, examination of the bubble properties according to types and foaming agent concentration was performed. An foaming agent used for this test were anionic surfactant, rosin, and protein system with the foaming agent concentration range of 0.05~13%. Test parameters considered in the study were foaming rate, foam volume, drainage solution volume, and bubble size. The study results showed that, regardless of foaming agent type, higher concentration of foaming agent showed an increase in the foaming rate. Also, the results showed that concentration of foaming agent affected bubble size, drainage solution volume change, and bubble distributions. With respect to the stability of the bubble, protein foaming agent was better than anion surfactant or rosin foaming agent. With respect to the bubble shape, anion surfactant and rosin formed bubbles had polygon shape where as protein formed bubbles had spherical shape.

A numerical study on the optimum operation condition for axial oxygen concentration in 8 inch silicon growth by cusp MCZ (8인치 실리콘성장을 위한 커스프 MCZ계에서 축방향 산소분포에 대한 연구)

  • 이승철;윤종규
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.3
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    • pp.406-417
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    • 1997
  • A numerical study was conducted on the optimum magnetic field intensity and asymmetric factor for uniform axial oxygen concentration in 8 inch silicon single crystal growing process by magnetic Czochralski method. For constant shape of cusp field, a change of coil and crucible position were compared. In case of symmetric cusp field, magnetic field intensity variation shows concave downward with crystal growing for uniform, axial oxygen concentration. A numerical results show similar value of standard deviation of average oxygen concentration for uniform oxygen concentration between coil and crucible position change. In case of asymmetric cusp field. asymmetric factor is increased with crystal growing to have uniform oxygen concentration.

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Effects of Dietary Taurine on the Lipid Metabolism in Laying Hens (사료내 타우린 첨가가 산란계의 지방대사에 미치는 영향)

  • 박강희
    • Korean Journal of Poultry Science
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    • v.29 no.2
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    • pp.95-100
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    • 2002
  • Two experiments were conducted to investigate the effect of taurine supplementation on lipid metabolism in laying hens. In experiment 1, 19-wk-old laying hens were given one of four taurine supplemented diets (0 (control), 0.4, 0.8, and 1.2% taurine) fur 10 weeks. Abdominal fat weight was lower in the 1.2% diet by 29.2% compared to the control. Serum concentrations of triacylglycerol and HDL-cholesterol were not different among the treatments. However, seam concentration of total cholesterol was higher by 22.4% in the 1.2% diet compared to the control. Concentration of triacylglycerol or total cholesterol in the liver were decreased by 26.1% or 26.4% and 28.2% or 26.4%, respectively in the 0.8% and 1.2% diets compared to the control. The concentration of HDL-cholesterol in liver was also lower by 33.9% in the 1.2% diet compared to the control. In experiment 2, 81-wk-old laying hens were allocated to one of three taurine supplemented diets (0 (control), 1 and 2% taurine) fur 6 weeks. Abdominal fat weight was lower by 25% in 1% taurine supplementation compared to the control. Serum concentrations of triacylglycerol, total cholesterol and HDL-cholesterol of hens fed with 1% diet were not different from those of control group. However, sew concentrations of triacylglycerol and total cholesterol were lower by 44.0% and 19.8%, respectively in the 2% diet compared to the control. Furthermore, serum concentration of HDL -cholesterol in the 2% diet was higher by 75% compared to the control. Concentrations of triacylglycerol and total cholesterol in the liver in the 2% diet were decreased in the 1% diet by 36.8 and 23%, respectively, but increased by 78.4% and 70%, respectively, compared to the control. The concentration of HDL-cholesterol in the liver was not different between the 1% diet and the control, but higher by 62.8% in the 2% diet compared to the control. These results indicated that taurine supplementation decreased the fat storage in abdominal cavity, which was accompanied by the changes in triacylglycerol and cholesterol metabolisms of laying hens.

Concentration measurements of the premixed mixture by using a hot wire concentration probe (열선농도 프로우브를 이용한 여혼합기의 순간농도 측정에 관하여)

  • 박경석
    • Journal of the korean Society of Automotive Engineers
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    • v.7 no.1
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    • pp.12-17
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    • 1985
  • 주위기체와 다른 기체를 간헐적으로 또는 단발로 분사한 경우, 분류내의 분사체의 농도는 시간에 따라 급격히 변화한다. 수ms인 전자식기체 채취밸브를 이용해서 기체를 채취하고, 가스마토그 라프 등에 의해 가스분석을 행하는 방법이 있고 주로 피스톤식 내연기관의 연소실내 농도의 측 정에 이용되고 있다. 이 방법은 밸브 열립시간을 단축시켜도 약 1ms가 한도이고 시간분해능력도 1ms정도가 최단시간이다. 또 동일한 장소에서 농도의 시간경과를 얻는 데에는 각각의 시간에 대해서 기체의 채취와 분석을 행하지 않으면 안되어 실제시간의 농도측정이 불가능하다는 결점이 있다. 최근 레이저 응용기술의 진보에 의해 라만산란, 레리산란, CARS법 등의 농도순간측정이 가능해지고 있고, 점차 현실화되어가고 있다. 이들의 방법은 국소의 순간농도뿐만 아니라 온도의 동시측정도 가능하게 하는 특징을 갖고있다. 그러나 레이저에 의한 측정장치는 현시정에서는 아직 가격이 고가이고 광학계의 설치 등, 실험상의 조작이 복잡한 것 등의 결점을 갖고 있다. 본 고에서는 최근 진전이 현저하고 실용화에 대한 확신을 갖고 있는 열선농도Probe에 의한 순간농 도의 측정방법을 소개하고자 한다.

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