The major 81 tributaries in Chungcheongnam-do were monitored for flowrate and water quality in order to understand the characteristics of the watershed and to select the tributary catchment for improving water quality. The value of flowrate in the tributaries at Nonsancheon catchment at the Geum-River watershed and Gokgyocheon, Muhancheon, Sapgyocheon at the Sapgyo-Reservoir watershed, which is located in the southern and northern area in Chungcheongnam-do, was relatively greater than the other watersheds. The concentration of water pollutants regardless of water quality parameters in Nonsancheon catchment at the Geum-River watershed, Gokgyocheon catchment at the Sapgyo-Reservoir watershed and the Anseongcheon watershed, which have a dense source of pollution, were higher than the other watersheds. However, 64 percent of the tributaries at the Geum-River watershed, 45 percent of tributaries at the Sapgyo-Reservoir watershed, 26 percent of tributaries at the Geum-River watershed all satisfied the Class II regulations in the Framework Act on Environment Policy, but all of the tributaries located in the Anseongcheon watershed exceeded the Class II regulations. Therefore, the policy for improving the water quality of the tributary in Chungcheongnam-do should be established in the following order: Anseongcheon, Seohae, Sapgyo-Reservoir watersheds. Consequently, the tributary catchment for improving water quality, which has a large flowrate and a high concentration of water pollutants, was selected at Ganggyeongcheon, Geumcheon, Nonsancheon, Seokseongcheon, Seungcheoncheon, Jeongancheon, Jeungsancheon (so far Geum-River watershed), Gokgyocheon, Namwoncheon, Maegokcheon, Muhancheon, Sapgyocheon Oncheoncheon, Cheonancheon (so far Sapgyo-Reservoir watershed), Gwangcheoncheon, Dangjincheon, Daecheoncheon, Dodangcheon, Waryongcheon, Cheongjicheon, Pangyocheon, Heungincheon (so far Seohae watershed), Dunpocheon, Seonghwancheon, Ipjangcheon (so far Anseongcheon watershed). The plans as installation of environmental facilities to reduce the source of pollution for improving the water quality of these tributary catchments should be urgently established and implemented.