• 제목/요약/키워드: 노말 헵탄

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탄화수소계 연료의 축소반응모텔과 노말-헵탄(n-Heptane)의 자발화 현상 (Simplified Reaction Scheme of Hydrocarbon Fuels and Its Application to Autoignition of n-Heptane)

  • 여진구
    • 한국자동차공학회논문집
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    • 제10권1호
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    • pp.76-83
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    • 2002
  • Mathematically and chemically simplified reaction scheme for n(heptane that simulates autoignitions of the end gases in spark ignition engines has been developed and studied computationally. The five(equation model is described, to predict the essential features of hydrocarbon oxidation. This scheme has been calibrated against autoignition delay times measured in rapid compression machines. The rate constants, activation temperatures, Ta, Arrhenius pre-exponential constants, A, and heats of reaction for stoichiometric nheptane/air has all been optimized. Comparisons between computed and experimental autoignition delay times have validated the present simplified reaction scheme. The influences of heat loss and concentration of chain carrier at the beginning of compression upon autoignition delay times have been computationally investigated.

고온 고압에서 혼합연료의 층류화염속도 예측 모델에 대한 연구 (Laminar Flame Speed Model of Fuel Blends at Elevated Temperatures and Pressures)

  • 변정주
    • 한국연소학회지
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    • 제17권2호
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    • pp.9-16
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    • 2012
  • Iso-octane, n-heptane and their blends were tested in a constant volume combustion chamber to measure laminar flame speeds. The experimental apparatus was automatically controlled to enhance the accuracy and data acquisition speed. A large database of laminar flame speeds at elevated temperatures and pressures was established. From this database, laminar flame speeds of iso-octane, n-heptane and their blends were investigated and analysed to derive new correlation to predict laminar flame speeds at any blending ratio. The new flame speed model was successfully applied to these fuels with limited range of errors.

급속압축장치를 이용한 노말헵탄.이소옥탄 혼합연료의 HCCI 연소특성에 대한 연구 (Experimental Study on HCCI Combustion Characteristics of n-heptane and iso-octane Fuel/air Mixture by using a Rapid Compression Machine)

  • 임옥택
    • 한국분무공학회지
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    • 제16권4호
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    • pp.167-175
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    • 2011
  • The HCCI engines have been known with high efficiency and low pollution and can be actualized as the new internal combustion engines. However, As for(??) the ignition and combustion depend strongly on the oxidation reaction of the fuel, so it is difficult to control auto-ignition timing and combustion duration. Purpose of this paper is creating the database for development of multi-dimensional simulation and investigating the influence of different molecular structure. In this research, the effect of n-heptane mole ratio in fuel (XnH) on the ignition delay from homogeneous charge compression ignition(HCCI) has been investigated experimentally. By varying the XnH, it was possible to ascertain whether or not XnH is the main resource of ignition delay. Additionally, the information on equivalence ratio for varying XnH was obtained. The tests were performed on a RCM (Rapid Compression Machine) fueled with n-heptane and iso-octane. The results showed that decreasing XnH (100, 30, 20, 10,0), the ignition delays of low temperature reaction (tL) and high temperature reaction (tH) is longer. And the temperature of reaction increases by about 30K. n-heptane partial equivalence ratio (fnH) affect on tL.and TL. When ${\phi}$nH was increased as a certain value, tL was decreased and TL was increased.

분사율을 이용한 직접 분사식 다공 가솔린 인젝터의 분사특성 연구 (Study on the Injection Characteristics using Injection Rate in a Direct-injection Gasoline Injector with Multi-hole)

  • 박정현;신달호;박수한
    • 한국분무공학회지
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    • 제21권1호
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    • pp.20-28
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    • 2016
  • This paper presents an experimental study on the GDI injector with Bosch method. The injection characteristics, such as the injection quantity, the injection rate, the maximum velocity of the nozzle exit and the injection delay were studied through the change of the injection pressure, the tube pressure and energizing duration in injection rate measurement device using nheptane. The injection quantity is increased by increasing injection pressure, decreasing tube pressure or increasing energizing duration. As the difference of the injection quantity changed, the shape of injection rate was moved with a constant form. The maximum velocity of the nozzle exit showed a tendency to increase as the injection pressure is increased. However, tube pressure did not affect. Overall, it was confirmed that the closing delay is longer than the opening delay in all conditions. As the injection pressure increased, the result has a tendency to decrease the closing delay, it did not affect the opening delay. Reduction of the closing delay showed the reduction of the injection duration. the tube pressure and energizing duration did not affect the injection delay (opening delay, closing delay).

디테트라하이드로퍼퓨릴프로판과 용매를 포함하는 이성분계의 상평형 연구 (Study on the Phase Equilibria of Binary Systems Containing Ditetrahydrofurfurylpropane and Solvents)

  • 빈영욱;노경호;박소진;박종기
    • 공업화학
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    • 제22권4호
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    • pp.390-394
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    • 2011
  • 디테트라하이드로퍼퓨릴프로판(Ditetrahydrofurfurylpropane, DTHFP, ($CH_2CH_2CH_2OCH)_2C(CH_3)_2$)과 용매인 사이클로헥산(Cyclohexane), 노말헵탄(n-Heptane), 테트라하이드로퓨란(Tetrahydrofuran), 그리고 물을 포함하는 각 이성분계의 기액상평형을 측정하였다. 기액 상평형 측정은 DTHFP의 농도가 낮은 영역에 대하여 실시하였다. NRTL 모델을 이용하여 기액 상평형을 해석하였으며 측정된 실험자료를 이용하여 NRTL 모델의 이성분계 상호작용 매개변수를 회귀분석하였다.