• Title/Summary/Keyword: 네오디움

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Polarograms of Uranium(VI) and Rare Earth(III) Metal Complexes with Macrocyclic Ligands in Dimethylsulfoxide Solvent (디메틸술폭시드 용매중에서 거대고리리간드를 포함한 우라늄(VI)과 희토류(III) 금속 착물의 폴라로그램)

  • Hak Jin Jung;Oh Jin Jung;Chilnam Choi
    • Journal of the Korean Chemical Society
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    • v.32 no.3
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    • pp.233-242
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    • 1988
  • The uranium(VI) complexes with new unsaturated macrocyclic ligands of cryptand types and the neodymium(III) complexes with cryptand 222 and DBC ligands have been investigated polarographically in dimethylsulfoxide solvent. The reduction states, electron numbers involved in the reduction process, effects of the added acid on the polarograms of complexes, and the mechanisms of the reduction electrode reactions have been examined. The stability constants and mole-ratio of new complexes were also obtained by polarographic method. The reaction of ligands was controlled by the diffusion in the reduction with four electrons at a step, whereas the redox reaction with six electrons at three steps in $UO_2\;^{2+}$ complexes with macrocyclic ligands and the redox reaction with one electron at a step in $Nd^{3+}$ complexes with cryptand 222 and DBC have been observed. The imine ligands formed stable complexes with uranium(VI) above pH 7.0, and the neodymium(III) complexes with cryptand 222 and DBC ligands were stable above pH 4.0.

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New and renewable Energy and Critical Raw Materials (신재생에너지와 Critical Raw Materials)

  • Kim, Yujeong
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.155-155
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    • 2011
  • 신재생에너지 수요가 확대됨에 따라 신재생에너지 관련 제품에 소요되는 물질에 대한 관심이 확대되고 있다. 이들 물질은 공급리스크가 존재하는 희유금속이 주를 이루고 있다. 본 연구에서는 신재생에너지 등의 high tech 기술 확대로 인한 희유금속의 수요 및 공급을 전망하고 있는 미국의 critical raw material 관리 전략을 살펴보고자 한다. 미국은 2010년 12월 미국 에너지성(DOE : Department of Energy)에서 위기 물질 전략(Critical Materials Strategy)에 관한 리포트를 공표하였다. 클린 에너지 기술 4개 분야(영구자석, 선진 전지, 태양전지 박막, 형광 물질)에서 핵심이 되는 물질(희유금속 등)의 수급 불균형이 일어날 가능성에 대해 조사를 실시하여 리스크 평가하여 단기, 중단기로 구분하여 위기물질을 선정하였다. 클린 에너지 기술 4개 분야에서 핵심이 되는 물질(네오디움, 디스프로슘, 코발트, 리튬, 랜턴, 세륨, 테룰, 인듐, 갈륨, 유로피움, 테르비움, 이트륨)의 12광종 수급을 2025년까지 전망한 결과 전체적으로 단기(2010년~2015년)보다 중기(2015년~2025년)에 공급 부족이 확대한다고 예측되었다. 단기적으로는 인듐이 약간 부족하는 것 외에 디스프로슘과 이트륨에 관해서도 공급 부족할 것으로 예측되었다. 중기적으로는 코발트(전지 기술에 사용)와 유로피움(고효율 조명용의 형광 물질에 사용) 외 대상이 된 다른 모든 물질은 공급 부족이 발생할 것으로 전망되었다. 이를 종합하여 단기적으로는 디스프리슘, 유로피움, 인듐, 테르븀, 네오디움, 이트륨 등이, 중기적으로는 디스프리슘, 유로피움, 테르븀, 네오디움, 이트륨 등이 위기물질(Critical Material)로 분석되었다. 에너지성은 위기물질을 공급원다각화, 대체물질개발, 리유즈, 리사이클링 등을 국제적 파트너와 함께 추진하여 리스크를 관리할 것이며, 2011년까지 최신정보를 구축하여 위기물질 전략을 재설정할 예정이다. 체계적인 위기물질 선정 및 관리전략 등을 참조하고, 신재생에너지기술 변화에 따른 원재료의 중요성 및 리스크 관리현황을 기초로 우리나라에 적합한 위기관리 물질 선정 및 관리가 필요할 것이다.

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Design of Neodymium Permanent Magnetic Core using FEM (유한요소법을 이용한 네오디움 영구자석의 코어 설계)

  • Hur, Kwan-Do;Ye, Sang-Don
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.13 no.5
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    • pp.70-75
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    • 2014
  • Permanent magnets have recently been considered as device that can be used to control the behavior of mechanical systems. Neodymium magnets, a type of permanent magnet, have been used in numerous mechanical devices. These are permanent magnets made from an alloy of neodymium, iron, and boron to form the Nd2Fe14B tetragonal crystalline structure. The magnetic selection, magnet core design and mechanical errors of the magnetic component can affect the performance of the magnetic force. In this study, the coercive force, residual induction, and the dimensions of the design parameters of the magnet core are optimized. The design parameters of magnet core are defined as the gap between the magnet and the core, the upper contact radius, and the lower thickness of the core. The force exercised on a permanent magnet in a non-uniform field is dependent on the magnetization orientation of the magnet. Non-uniformity of the polarization direction of the magnetic has been assumed to be caused by the angular error in the polarization direction. The variation in the magnetic performance is considered according to the center distance, the tilt of the magnetic components, and the polarization direction. The finite element method is used to analyze the magnetic force of an optimized cylindrical magnet.

Design of Ring type PMSM for aircraft propulsion system (항공기 추진용 Ring-type PMSM 설계)

  • Lee, Jae Kwang;Lee, Ki-Doek;Jung, Jae Woong;Lee, Ju
    • Proceedings of the KIEE Conference
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    • 2015.07a
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    • pp.908-909
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    • 2015
  • 본 논문은 항공기 추진용 전동기에 대한 논문으로 전동기 내부에 블레이드가 삽입되는 특징으로 인해 매우 얇은 요크폭과 항공기 시스템 효율을 위해 가볍게 설계해야 한다는 점을 제약조건으로 갖는 Ring-type PMSM 설계에 관한 논문이다. 본 논문에 언급되는 전동기의 경우 내부에 삽입되는 블레이드로 인해 내부 요크 폭이 매우 얇다는 제약조건에서 어떠한 전동기 타입이 적절한지 검토하였고, 네오디움(NdFeB) 자석을 사용하여 높은 자속밀도로 고출력을 얻는 동시에 높은 도전율과 얇고 넓은 자석 형상에 따라 발생하는 손실을 저감하기 위한 설계를 진행하였고 유한요소해석을 통해 감자를 고려하여 전자기적 성능을 확인하였다.

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Nd Model Age and Nd Isotopic Evidence of Granitoid Rocks in the Gwangju-Naju Area, Korea (광주-나주지역 화강암류에 대한 네오디움 표본연령 및 동위원소 특성연구)

  • Park, Young Seog
    • Economic and Environmental Geology
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    • v.30 no.2
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    • pp.153-161
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    • 1997
  • Diagrams of $^{87}Sr/^{86}Sr$ versus Ba/Nb and MgO/FeO are scattered, and $^{87}Sr/^{86}Sr$ variation with the increase of $SiO_2$ are scattered in Gwangju granitoid. Diagrams of $(^{87}Sr/^{86}Sr)$i versus $(^{143}Nd/^{144}Nd)$i and ${\varepsilon}Nd$ versus 1/Nd variation are also scattered in Gwangju granitoid. It shows that the source magma of Gwangju granitoid are derived from partial melting materials of heterogeneous upper crust. Very low ${\varepsilon}Nd$ values (-15.19~-19.49) and very high ${\varepsilon}Sr$ values (92.72~308.85) mean that the source magma of Gwangju granitoid is derived from sedimentary substance melting. According to $(^{87}Sr/^{86}Sr)$ 180Ma, and the plot of ${\varepsilon}Sr$ versus ${\varepsilon}Nd$, the Gwangju granitoid shows that the source magma is derived from upper crust materials. Nd model ages of Gwangju granitoid (1.82~2.42G.A.) are older than meta-sediments of Okcheon formation (1.15~1.60G.A.) and similar or close to Pre-Cambrian gneiss complex of Ryoungnam massif (2.17~2.47G.A.or 2.11~2.38G.A.).Therefore, the source magma of the Gwangju granitoid could be derived from the partial melting of Pre-Cambrian gneiss complex of Ryoungnam massif.

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Development of Cutting Jig using Separation of PCB component (PCB소자 분리용 컷팅지그 개발)

  • Lee, Seung-Chul;Park, Suk-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.5
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    • pp.2567-2572
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    • 2014
  • In the present study, we aimed to obtain multi jig that PCB sheet with several PCB component can cut in a short time as to the Separation of PCB component. PCB supporter designed safely at the base frame and each model can be separable. it completed the neodium magnet for the fixing of the upper part laser transmission hole of the both. One of the development, the cutting working with one base frame which PCB component of various standard, fixing of module and bridge connected to PCB component could be possible. and it reduced the inconvenience which has to replace the base frame and PCB sheet fixed member. It compared to other press up about 70% of accuracy and a reduction in investment cost was about 400%.

Design of Axial Flux Permanent Magnetic Motor Using Soft Magnetic Composite Core (연자성 분말코어를 적용한 축방향 영구 자속형 전동기 설계)

  • Choi, Myung-Wook;Yang, Seung-Jin;Moon, Chae-Joo
    • The Journal of the Korea institute of electronic communication sciences
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    • v.17 no.4
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    • pp.607-616
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    • 2022
  • A new axial flux permanent magnet machine with soft magnetic composited cores is proposed for electric vehicle application in this paper. The windings and soft magnetic composited cores can be designed to form a very compact structure, and; thus, the torque density can be improved greatly. To obtain the a good flux concentrating ability, two toroidally wound internal stator machines are designed and analyzed, and the designed motor is with NdFeB magnet for high-performance electric vehicle application. The 3-D finite-element method is used to analyze the electromagnetic parameter and performance, for performance comparison, a commercial axial flux permanent magnet machine is used. The proposed motor reduced weight about 5.8%, produced torque higher than about 8Nm for existing motor.

A Study on the Development of Mobile Robot for Inspection of Hull Surface (선체 외부 검사용 모바일 로봇 개발에 관한 연구)

  • Kim, Jin-Man;Kim, Heon-Hui;Nam, Taek-Kun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.21 no.6
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    • pp.744-750
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    • 2015
  • In this paper, development of mobile robot for the inspection of hull surface was mentioned. In the sea, it is difficult to proceed with the visual inspection of hull side and thus mobile robot for checking the status could be run with strap-on its surface. To do this, permanent magnet module to generate magnetic force between hull surface and mobile robot, and structure to minimize variance of the force under curvature circumstance were considered on the design. Based on the design, mobile robot with four NdFeB, four driving wheels and image aquisition module was applied. Load experiment to check the adhesive force, slip test during stop state and driving test to measure driving speed were executed. From the experiments 13 Kgf adhesive force was obtained and slip was not happened until 8 Kgf load on the inclined plate. Driving speed of mobile robot was measured at 0.82 m/s corresponding to 6.5 ampere. We confirmed the effectiveness of developed mobile robot by experiments to check its characteristics.