• Title/Summary/Keyword: 냉각과 희석

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열유도 상분리 공정 및 연신 공정을 이용한 중공사막의 제조

  • 유종범;김진호;김성수
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.79-80
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    • 1997
  • 1. 서론 : 열유도 상분리법(TIPS)은 일반적으로 상온에서 적정용매가 없는 고분자 소재를 아용하여 고분자-희석제 2성분계의 혼합물을 적절한 냉각 속도로 상분리 온도 이하로 급냉시켜 연속상과 분산상의 상분리를 일으킨 후 matrix전체에 다공성을 부여하여 분리막을 제조하는 공정이다. 폴리올레핀계 고분자를 중심으로 나일론11. 폴리카보네이트, PVC, ABS 수지 등을 소재로 plasmapheresis, 인공심폐기, breathing wear 등의 용도로 많이 응용되어 왔으며 현재 한외여과나 정밀여과 등 수투과 공정 및 battery separator 등으로의 응용이 활발하게 연구되고 있다. TIPS공정에 의해 제조된 고분자 분리막은 기존의 분리막에 비해 내열성 및 내약품성이 우수하며 여러 가지 다양한 변수로 부터 막의 미세구조를 조절할 수 있어 기공의 크기 및 모양이 조절 가능하다. 본 연구에서는 TIPS 공정을 이용한 고분자 분리막의 제조시 take-up speed와 air gap 등을 변화시켜 이에 따른 영향을 조사하였고 또한 cold stretching에 의한 구조변화를 알아보았다.

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스티렌-디비닐벤젠 고분자담체의 물성에 따른 촉매 특성

  • 강희석;이한ㅅ;정흥석;국일현;송명재;손순환
    • Nuclear Engineering and Technology
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    • v.27 no.4
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    • pp.626-634
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    • 1995
  • 소수성 고운자촉매는 중수형 원자력발전소의 감속재 및 냉각재로 사용되는 중수의 제조, 그리고 발전소의 가동에 따라 중수중에 축적되는 삼중수소의 제거공정 둥에 이용된다. 여러 소수성 담체중 하나인 소수성 고분자담체를 제조하기 위하여 스티렌-디비닐벤젠의 제조 특성을 실험하였다. 제조된 담체에 백금 금속을 담지시켜 촉매를 완성한 후 삼중수소제거 실증실험을 통하여 촉매성능을 확인하였다. 스티렌-디비닐벤젠 고분자담체의 제조시 담체의 기공 특성 및 비표면적에 대한 용매의 영향을 실험하였다. 또한 용매비를 변화시킨 경우에는 solvating power 값을 계산하여 거시기공 형태의 담체 형성기준을 정하였고 여기에 따른 기공 특성 및 비표면적 변화를 부인하였다. 담체의 제조 후 후처리 방법을 변화시켜 기공 특성 및 비표면적 변화를 확인하였고, 이의 결과를 통하여 적절한 후처리 방법을 정하였다. 담체의 입자크기를 조절하기 위해 중합반응 과정중의 교반속도를 변화시켜 담체의 크기 변화를 실험하였다. 제조된 담체에 백금 금속을 담지시켜 촉매를 완성한 후 삼중수소제거 반응실험을 통해 촉매의 활성을 확인하였다.

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Installation and Performance Test of Cooling System for the KEPCO HTS Power Cable (한전 초전도 전력케이블 냉각시스템 설치 및 시험)

  • Yang, H.S.;Kim, D.L.;Lee, B.S.;Choi, Y.S.;Ryoo, H.S.;Sohn, S.H.;Lim, J.H.;Hwang, S.D.
    • Progress in Superconductivity and Cryogenics
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    • v.9 no.1
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    • pp.82-85
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    • 2007
  • A cooling system for a 22.9kV, 1.25kA 100m HTS power cable has been installed and tested. The cooling system consists of decompression cooling system with the cooling capacity of 3kW and a closed circulation system of subcooled liquid nitrogen. This paper describes the outline of the installed cooling system and performance test results.

The Effect of Cold Shock on Function and Morphology of Dog Epididymal Spermatozoa (개에서 cold shock이 정소상체유래의 정자의 기능과 형태에 미치는 영향)

  • Yu Il-jeoung
    • Journal of Veterinary Clinics
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    • v.21 no.4
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    • pp.329-335
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    • 2004
  • Dog spermatozoa were recovered from the caudae epididymides of 23 domestic dogs which were 11 pure breed and 12 mix-breed dogs ranging in age from 0.6 to 3 years. The experimental designs were as follows: 1) the effect of chilling to 0. 10 or 37$^{\circ}C$. 2) the kinetics of chilling injury at 0 or 4$^{\circ}C$, and 3) the effect of sugars at $0^{\circ}C$. Viable spermatozoa were recovered by percoll gradient separation and adjusted to 5${\times}$10$^{7}$ spermatozoa/ml. In experiment 1, spermatozoa were diluted with 0.33 M glucose supplemented with 3% BSA (G-BSA) at 1:2 dilution. Spermatozoa were loaded into straws and exposed at 0, 10 or 37$^{\circ}C$ for 30 min. In experiment 2, spermatozoa were prepared as the experiment 1 and exposed for 0.5, 5, 15, or 30 min at 0 or 4$^{\circ}C$. In experiment 3, spermatozoa were diluted with different sugars (0.33 M galactose, glucose, fructose, mannitol, lactose, sucrose, raffinose) and cooled to $0^{\circ}C$ for 30 min. Sperm membrane integrity, motility and acrosome integrity were assayed after rewarming at 37$^{\circ}C$ for 5 min. Sperm motility and membrane integrity abruptly decreased with decreasing temperature but acrosome integrity gradually decreased (P<0.05). Sperm motility was more sensitive to cold shock than membrane integrity and acrosome integrity. Spermatozoa cooled to $0^{\circ}C$ were more damaged than those at 4$^{\circ}C$. Sperm motility was not different among exposed times at both. 0 and 4$^{\circ}C$. However, membrane integrity of spermatozoa exposed for 30 min at both 0 and 4$^{\circ}C$ was significantly lower (P<0.05). Spermatozoa diluted in 0.33 M fructose or galactose showed lower motility and higher morphological abnormality with coiled tail at $0^{\circ}C$. These sperm characteristics were strongly related. These results indicate that dog epididymal spermatozoa are relatively sensitive to rapid cooling and higher morphological abnormality at $0^{\circ}C$ was shown in spermatozoa diluted in fructose and galactose.

Use of Undiluted Potassium Solution in Intermittent Antegrade Warm Blood Cardioplegia (IAWBC) (간헐적 전방온혈심정지액에서 희석되지 않은 고농도 포타슘의 사용)

  • 백완기;손국희;김영삼;윤용한;김혜숙;임현경;이춘수;김광호;김정택
    • Journal of Chest Surgery
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    • v.37 no.8
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    • pp.660-664
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    • 2004
  • Background: Dilution of blood cardioplegia is not needed in IAWBC as it is in cold blood cardioplegia because it does not aggregate red blood cells on normal body temperature and does not compromise micro coronary circulation. This study was designed to evaluate the safety and efficacy of undiluted potassium solution in IAWBC. Material and Method: Thirty patients who underwent CABG with IAWBC were grouped into dilutedplegia (n=14) and microplegia (n=16). Potassium was delivered conventionally with 4 : 1 delivery kit in the dilutedplegia group. The undiluted potassium was directly connected on the blood of oxygenator in the microplegia group. Result: There were no differences in sex, age, left ventricular ejection fraction, number of grafts, aortic cross clamping time, and the value of perioperative myocardial enzyme between the two groups. There were no perioperative myocardial infarction and hospital mortality. The amount of crystalloid cardioplegia was 1346$\pm$597 mL in dilutedplegia (mean$\pm$standard deviation, and 28$\pm$9 mL in microplegia (p<0.0001). The hematocrit during cardiopulmonary bypass was 21$\pm$4% in dilutedplegia and 24$\pm$3% in microplegia (p>0.05). 11 patients in dilultedplegia received blood transfusion, but 4 patients in microplegia received blood transfusion (p<0.05). The amount of urine and hemofiltration during the operation were more in dilutedplegia (1250$\pm$810 mL, 1689$\pm$548 mL) than in microplegia (959$\pm$410 mL, 1461$\pm$784 mL; p<0.05). Conclusion: The undiluted potassium of IAWBC in CABG operation is a safe, effective technique for myocardial protection to prevent fluid overload, and blood transfusion. There is no need to use the delivery kit.

Analysis of Nuclear Power Plant Load Follow Operation by Temperature Reduction Method (냉각재 온도 감소 장식에 의한 원자력발전소 부하 추종 운전 해석)

  • Park, Sang-Yoon;Park, Goon-Cherl;Lee, Un-Cherl;Kang, Chang-Sun;Kim, Chang-Hyo;Chung, Chang-Hyun
    • Nuclear Engineering and Technology
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    • v.18 no.3
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    • pp.209-217
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    • 1986
  • The inlet coolant temperature reduction technique has been used to extend the load follow operation further in the end-of-cycle-life(EOL). In order to simulate the technique and calculate the nuclear characteristics of a PWR core according to the load follow operation, the three dimensional computing system has been established. The analysis was performed in both MINB and SPINR modes of typical 12-3-6-3 locad follow operation for the EOL of KNU-1 plant. Moreover, the capability of return-to-power has been also tested for those two modes with the system analysis by the RETRAN-02 code. The results show that it has no difficulty to extend the load follow operation further in the EOL by applying the inlet coolant temprature reduction, and also the spinning reserve capacity(SRC) increases by 13% in MINB mode and 14% in SPINR mode Bore that used by control rods only, for 14$^{\circ}$ F drop in the inlet temperature.

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Application of Water Mist System for a Power Transformer Room - Fire Extinguishment(Part 1) (변압기실 화재에 대한 미분무수 소화시스템의 적용 - 소화특성을 중심으로(Part 1))

  • Han Yong-Shik;Choi Byung-Il;Kim Myung-Bae
    • Fire Science and Engineering
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    • v.19 no.4 s.60
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    • pp.32-36
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    • 2005
  • A water mist system was considered as a possible alternative to a gaseous suppression system that can not prevent re-ignition after fire extinguishment for a power transformer room. This study deals with the fire suppression capability of the water mist systems. High-and low-pressure water mist systems were examined to compare efficiency of both systems. The power transformer examined in this study occupied about $7\%$ of a $10m\times10m\times$ transformer room. Full-scale suppression tests were performed for six different fire scenarios: two spray fires, three pool fires and one cascade fire. The fire suppression test results demonstrated that the high-pressure system was superior to the low-pressure system, especially considering oxygen depletion and the ambient temperature distribution.

Effects of Equilibration Time, Precooling and Straw Loading Method on Survival of Mouse Embryos Frozen by Vitrification (생쥐 수정란의 유리화 동결보존에 있어서 동결전 처리방법에 관한 연구)

  • Gong, Il-Geun;Lee, Eun-Bong;Gang, Dae-Jin;Park, Chung-Saeng
    • Korean Journal of Animal Reproduction
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    • v.15 no.1
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    • pp.49-57
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    • 1991
  • This study was carried out to investigate the effect of equilibration time, precooling and straw loading method on the post-thaw survival rates of mouse embryos cryopreserved by vitrification method. The effect of the vitrification procedure on the damage of the embryos was also examined by the straining of nuclei using Hoechst 33342. The results obtained were summarized as follows; 1. The equilibration in Medium-1 for 10 minutes was considered to be the optimum equilibration time. Embryos equilibrated in Medium-1 for 10 minutes(81.0%) showed significantly(P<0.05) higher survival rates than those equilibrated for 5 minutes(40.0%) or 15 minutes(74.1%). 2. The survival rate of embryos cryopreserved using the double Medium-2 column(81.0%) was significantly(P<0.01) higher than that using the single Medium-2 column, whish was considered to be due to the double Medium-2 column method being more reliable for preventing contamination of diluent solution of 1M sucrose. 3. The survival rate of compacted morula stage embryos cryopreserved with the precooled and non-precooled Medium-2 was not significantly(P<0.05) different. 4. The number of blastomeres of embryos at late blastocyst stage after culture of mouse morulae for 24 to 28hours was significantly(P<0.05) decreased by freezing embryos using vitrification(53.3${\pm}$1.6 vs 41.4${\pm}$1.5), which was considered to be due to the damage of embryos during vitrification and the delay of embryo development by handling in vitro. 5. The vitrification procedure is considered to be a very simple and efficient method for cryopreservation of embryos at early developmental stage.

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Performance Test of Cooling System for the KEPCO HTS Power Cable (한전 초전도전력케이블 냉각시스템 성능시험)

  • Yang, H.S.;Kim, D.L.;Sohn, S.H.;Lim, J.H.;Choi, H.O.;Lee, B.S.;Choi, Y.S.;Ryoo, H.S.;Hwang, S.D.
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2206-2210
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    • 2007
  • As a power transmission line supplying power to a densely populated city, the high temperature superconducting (HTS) cable is expected to one of the most effective cables with a compact size because of its high current density. The verification of HTS power cable system have been progressed by KEPRI. A cooling system for a 3-phase 100m HTS power cable with 22.9kV/1.25kA was installed and tested at KEPCO's Gochang power testing center in Korea. The system consists of a liquid nitrogen decompression cooling system with a cooling capacity of 3kW and a closed circulation system of subcooled liquid nitrogen. Several performance tests of the cable system with respect to the cooling such as cooling capacity, heat load and temperature stability, were performed at several temperatures. Thermal cycle test, cool-down to liquid nitrogen temperature and warm-up to room temperature, was also performed to investigate thermal cycle influences. The outline of the installed cooling system and performance test results are presented in this paper.

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A Study on the Characteristics of HTS Cable System Operation and Cooling Load in a Load Unbalance (불평형 부하에서의 초전도케이블 운전 및 냉각부하 특성에 관한 연구)

  • Sohn, S.H.;Lim, J.H.;Yang, H.S.;Choi, H.O.;Ma, Y.H.;Kim, D.L.;Ryoo, H.S.;Ryu, K.W.;Hwang, S.D.
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.397_398
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    • 2009
  • Demonstrations to deploy high temperature superconducting (HTS) cable to the real gird are actively carried out throughout the world. Power utilities have an interest in the inherent advantage of the HTS cable system, and achieve the expected results from the series of verification test. To embody the reliability in the phenomenon occurred commonly in three-phase system, we simulate the load unbalance. A 22.9 kV large scale HTS cable system with the specification of 100 m-long, 50 MVA capacity has been tested with up to 30% unbalance rate. To evaluate the effect of AC loss increase due to the unbalanced load, the cooling loads are measured by the calorimetry method. In this paper, the correlation between AC loss and load unbalance is described and investigated precisely.

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