• Title/Summary/Keyword: 내산화성

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Characteristics of CrZrON coatings Synthesized by Cr-Zr Segment Target (Cr-Zr Segmet Target을 이용한 CrZrON 박막 합성 및 특성 연구)

  • Kim, Dong-Jun;Lee, Yu-Jin;Ra, Jeong-Hyeon;Kim, Seong-Min;Lee, Sang-Yul
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.11a
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    • pp.99-99
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    • 2012
  • CrZrN의 3원계 박막은 상온에서 매우 우수한 기계적 특성을 나타내지만, 고온에서는 Zr의 산화로 인하여 기계적 특성이 저하되게 된다. 따라서 본 연구에서는 CrZrN 박막의 고온 특성을 개선하기 위해서 내산화성이 향상에 영향을 미치는 표면 산화물을 만들기 위한 산소 원소를 첨가하여 CrZrON 4원계 박막을 segment target을 이용해 합성하였고, 박막의 특성을 분석하였다.

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상전이법에 의한 Carboxylated poly(phenylene oxide) 역삼투 분리막의 제조 및 투과 특성

  • 김제영;이제흔;김성철
    • Proceedings of the Membrane Society of Korea Conference
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    • 1994.10a
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    • pp.64-65
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    • 1994
  • 근래 환경 문제의 중요성이 크게 대두되면서 여러 제조 공정에서 방출되는 폐수등을 처리하는데 필요한 내구성이나, 내미생물성, 내약품성이 우수한 분리막 재료에 대한 연구가 진행되고 있다. 내구성이 우수한 역삼투막 재료를 얻기 위한 방법의 하나로 엔지니어링 플라스틱을 친수화시키는 방법이 개발되어 왔다. 특히 PPO (poly(2-6-dimethyl-1,4-phenylene oxide))로 만들어진 분리막은 내산화성이 우수하고 내구성이 뛰어나다고 알려져왔고 본 연구에서는 PPO에 carboxyl기를 도입하여 친수성을 부여하고, 상전이법을 이용하여 얇은 표피층이 선택성을 높이고 다공성 구조가 표피층을 지지하도록 만든 비대칭성 구조의 분리막을 제조하고 그 투과특성을 살펴보았다.

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Effect of CaO on the high-temperature oxidation of AZ21 and AZ31 magnesium alloys. (AZ21, AZ31 마그네슘 합금의 고온산화에 미치는 CaO 첨가효과)

  • Park, Sun-Yong;Ji, Gwon-Yong;Yadav, Poonam;Park, Sang-Hwan;Jeong, Seung-Bu;Lee, Dong-Bok
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.05a
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    • pp.98-99
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    • 2015
  • Mg합금은 지극히 열악한 내산화성을 갖는 MgO로 산화되기 때문에, 모든 Mg합금은 고온에서는 쉽게 산화되고 발화된다. 그러나, CaO를 첨가하면 CaO가 시편의 노출면적을 줄이고, 산소의 내부확산을 억제함으로써 시편 표면에 얇고 균일한 보호피막을 형성하여 Mg합금의 산화 저항성을 증가시켰다.

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Effect of CaO on the high-temperature oxidation of AZ31 magnesium alloys. (AZ31 마그네슘 합금의 고온산화에 미치는 CaO 첨가효과)

  • Won, Seong-Bin;Xu, Chunyu;Kim, Seul-Gi;Kim, Min-Jeong;Lee, Dong-Bok
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.172-172
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    • 2012
  • Mg합금은 지극히 열악한 내산화성을 갖는 MgO로 산화되기 때문에, 모든 Mg합금은 고온에서는 쉽게 산화되고 발화된다. 그러나, CaO를 첨가하면 CaO가 시편의 노출면적을 줄이고, 산소의 내부확산을 억제함으로써 시편 표면에 얇고 균일한 보호피막을 형성하여 Mg합금의 산화 저항성을 증가시켰다.

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Perspective of Technology for Liquid Rocket Engines (액체로켓엔진 기술 전망)

  • Cho, Won Kook;Ha, Sung Up;Moon, Insang;Jung, Eun Whan;Kim, Jin Han
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.44 no.8
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    • pp.675-685
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    • 2016
  • A research area on liquid rocket engine has been suggested. Downsizing through combustion pressure rise and low price are major issues to gas generator cycle engines. A very high pressure turbopump and material against oxidizer rich environment may be necessary technologies for staged combustion cycle engines. Integrated analysis saving computing time is the trend of rocket engine systems analysis area. Other important research topics are the methane engine for reusable booster to reduce the cost, 3D printing and materials for high temperature or oxidizer rich environment.

Influence of Oxidation Inhibitor on Carbon-Carbon Composites: 5. Studies on Anti-oxidation Properties of the Composites (산화억제제 첨가에 의한 탄소/탄소 복합재료의 물성에 관한 연구: 5. 탄소/탄소 복합재료의 내산화성 연구)

  • 박수진;서민강;조민석;이재락
    • Polymer(Korea)
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    • v.24 no.2
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    • pp.237-244
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    • 2000
  • Phenolic resin used as a precursor of carbonized matrix for carbon-carbon composites was modified by addition of molybdenum disilicide (MoSi$_2$) in various concentrations of 0, 4, 12 and 20% by weight to improve the anti-oxidation properties of the composites. The green body was manufactured by a prepreg method and was submitted to carbonization up to 110$0^{\circ}C$. In this work, the oxidation behavior of carbon-carbon composites with MoSi$_2$ as an oxidation inhibitor was investigated at the temperature range of 600-100$0^{\circ}C$ in an air environment. The carbon-carbon composites with MoSi$_2$ showed a significantly improved oxidation resistance due to both the reduction of the porosity formation and the formation of mobile diffusion barrier for oxygen when compared to those without MoSi$_2$. Carbon active sites should be blocked, decreasing the oxidation rate of carbon. This is probably due to the effect of the inherent MoSi$_2$ properties, resulted from a formation of the protective layer against oxygen attack in the composites studied.

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Enhanced Flame Resistant Properties of Aluminum Hydroxide Addition on Electrospun Polyurethane Nanofibers (전기방사법에 의해 제조된 폴리우레탄 나노섬유의 수산화알루미늄 내첨에 의한 내염화 특성 향상)

  • Kim, Hyeong Gi
    • Fire Science and Engineering
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    • v.30 no.6
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    • pp.9-13
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    • 2016
  • Anti-oxidation and flame resistant polyurethane nanofibers were prepared by electrospinning and aluminum hydroxide addition. Electrospinning was carried out under the following procedure conditions; applied voltage, 20 kV; polymer solution feeding rate, 1.2 ml/h; collector rolling speed, 120 rpm; and tip to collector distance, 15 cm. Aluminum hydroxide was added to the prepared polymer solution for electrospinning to enhance the oxidation and flame resistant properties. The thermal properties were investigated by thermogravimetric analysis to determine the polymer decomposition temperature, integral procedure decomposition temperature, final decomposition temperature, and remaining amount after thermal decomposition. The activated energy for polymer degradation was also investigated using the Horowitz-Metzger equation. The activation energy increased to more than 50%. The thermal properties of the polyurethane nanofibers were improved by a hydration reaction during the thermal decomposition of aluminum hydroxide around $300{\sim}500^{\circ}C$.

Investigation of Characteristics for Cooling Parameters of a Combustor in Liquid Rocket Combustors (재생냉각 연소기의 냉각기구에 따른 특성 파악)

  • Kim, Hong-Jip;Choi, Hwan-Seok
    • Journal of the Korean Society of Propulsion Engineers
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    • v.14 no.5
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    • pp.45-50
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    • 2010
  • Thermal analyses have been performed to study the effect of location of fuel ring and thermal barrier coatings in regenerative cooling channels in a full-scale combustor. For the effective cooling, the fuel ring has better be installed near axial location of the low expansion ratio and low heat flux, and branching of cooling channels is preferable. Also, the radiative cooled nozzle extension is thought to be reasonable for the cooling of combustor walls. Among the possible coatings, $Y_2O_3$ stabilized $ZrO_2$ coating and Ni/Cr coating have been adopted. Compared with Ni/Cr coating which has high oxidation resistance, $Y_2O_3$ stabilized $ZrO_2$ coating, one of ceramic coatings is found to be much effective to sustain the thermal survivability of combustion walls.