• Title/Summary/Keyword: 납/비스무스

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Extraction and Separation of Ruthenium(III) from Hydrochloric Acid Solution Using TBP and Cyanex923 (염산용액(鹽酸溶液)에서 TBP 및 Cyanex923을 이용(利用)한 루테늄(III)의 유출(抽出).분리(分離)에 관한 연구(硏究))

  • Ahn, Jae-Woo;Lee, Ki-Woong
    • Resources Recycling
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    • v.20 no.2
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    • pp.60-66
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    • 2011
  • Solvent extraction experiments were carried out to recover and separate Ru(III) from aqueous hydrochloric acid media using TBP and Cyanex923. The efficiency of the extraction was studied under various experimental conditions, such as concentration of HCl and NaCl, concentration of extractant in the organic phase and temperature. The extraction behavior of metal impurities, such as Pt, Bi, Sn, Fe, Pb and Cu in mixed solutions was examined. From the experimental studies, it was found that the Cyanex923 resulted in higher extraction percentage of Ru than TBP. However TBP was more effective for the separation of Ru and Pt, Bi, Sn in mixed solutions than Cyanex923.

The Evaluation of Performance and Usability of Bismuth, Tungsten Based Shields (비스무스, 텅스텐 기반 차폐체의 성능 및 유용성 평가)

  • Park, Hoon-Hee
    • Journal of radiological science and technology
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    • v.41 no.6
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    • pp.611-616
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    • 2018
  • Lead apron is harmful to the human body because it is made at heavy metals, and when worn for long periods of time, it causes pain. Therefore, this paper intended to improve the defects of lead apron by using new material shields. For the comparative evaluation of lead and new material shieldes, the shielding rate and weight were measured and tested based on lead 0.5 mmPb. The rate of shielding was 97% based on lead at 0.5 mm thickness, while The new material shield T3 showed similar shielding rates as lead in 8 layers, and in T2 these values were measured in 11 layers. In addition, similar shielding rate was measured in 12 layers at B2, and 8 layers in BF, and 4 layers in $BF_2$. Comparing the weight of cases when commercialized with apron, T3, T2 and B2 were heavier than lead apron. But BF, $BF_2$ were lighter than the lead apron. Based on the results of the experiment, T3 and T2 can be used as an alternative to lead if human or environmental hazards are considered a priority. However, BF and $BF_2$ should be used if the reduction of external exposure is considered a priority.

The Evaluation of Eye Dose and Image Quality According to The New Tube Current Modulation and Shielding Techniques in Brain CT (두부 CT에서 차폐기법과 새로운 관전류변조기법에 따른 눈의 선량과 화질평가)

  • Kwon, Soonmu;Kim, Jungsu
    • Journal of the Korean Society of Radiology
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    • v.9 no.5
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    • pp.279-285
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    • 2015
  • The eye of human is a radiation sensitive organ and this organ should be shielded from radiation exposure during brain CT procedures. In the brain CT procedures, bismuth protector using to reduce the radiation exposure dose for eye. But protecting the bismuth always accompanies problem of the image quality reduction including artifact. This study aim is the eye radiation exposure dose and image quality evaluation of the new tube current modulation such as new organ based-tube current modulation, longitudinal-TCM, angular-TCM between shielding scan technique using bismuth and lead glasses. As a result, radiation dose of eye is reduced 25.88% in new OB TCM technique then reference scan technique and SNR new OB TCM is 6.05 higher than bismuth shielding scan technique and lower than reference scan technique. In clinical brain CT, new OB TCM technique will contribute to reduction of radiation dose for eye without decrease of image quality.

Reliability Verification of FLUKA Transport Code for Double Layered X-ray Protective Sheet Design (이중 구조의 X선 차폐시트 설계를 위한 FLUKA 수송코드의 신뢰성 검증)

  • Kang, Sang Sik;Heo, Seung Wook;Choi, Il Hong;Jun, Jae Hoon;Yang, Sung Woo;Kim, Kyo Tae;Heo, Ye Ji;Park, Ji Koon
    • Journal of the Korean Society of Radiology
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    • v.11 no.7
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    • pp.547-553
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    • 2017
  • In the current medical field, lead is widely used as a radiation shield. However, the lead weight is very heavy, so wearing protective clothing such as apron is difficult to wear for long periods of time and there is a problem with the danger of lethal toxicity in humans. Recently, many studies have been conducted to develop substitute materials of lead to resolve these problems. As a substitute materials for lead, barium(Ba) and iodine(I) have excellent shielding ability. But, It has characteristics emitting characteristic X-rays from the energy area near 30 keV. For patients or radiation workers, shielding materials is often made into contact with the human body. Therefore, the characteristic X-rays generated by the shielding material are directly exposured in the human body, which increases the risk of increasing radiation absorbed dose. In this study, we have developed the FLUKA transport code, one of the most suitable elements of radiation transport codes, to remove the characteristic X-rays generated by barium or iodine. We have verified the reliability of the shielding fraction of the structure of the structure shielding by comparing with the MCPDX simulations conducted as a prior study. Using the MCNPX and FLUKA, the double layer shielding structures with the various thickness combination consisting of barium sulphate ($BaSO_4$) and bismuth oxide($Bi_2O_3$) are designed. The accuracy of the type shown in IEC 61331-1 was geometrically identical to the simulation. In addition, the transmission spectrum and absorbed dose of the shielding material for the successive x-rays of 120 kVp spectra were compared with lead. In results, $0.3mm-BaSO_4/0.3mm-Bi_2O_3$ and $0.1mm-BaSO_4/0.5mm-Bi_2O_3$ structures have been absorbed in both 33 keV and 37 keV characteristic X-rays. In addition, for high-energy X-rays greater than 90 keV, the shielding efficiency was shown close to lead. Also, the transport code of the FLUKA's photon transport code was showed cut-off on low-energy X-rays(below 33keV) and is limited to computerized X-rays of the low-energy X-rays. But, In high-energy areas above 40 keV, the relative error with MCNPX was found to be highly reliable within 6 %.

Monte Carlo Simulation for Radiation Protection Sheets of Pb-Free (무연 방사선 차폐 시트에 대한 몬테카를로 전산모사)

  • Chon, Kwon Su
    • Journal of the Korean Society of Radiology
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    • v.11 no.4
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    • pp.189-195
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    • 2017
  • Radiation protection equipment has widely used to protect human body from radiations, for example X-ray and gamma ray. The material of the radiation protection equipment is mainly lead (Pb) which has brought out lead poisoning and pollution when the equipment is fallen into disuse. This problem makes research and development find new Pb-free materials for use of radiation protection. Manufacturing and evaluation processes for developing those material were carried out repletely until obtaining the performance of protection rate. In this study, combination possibility of shielding material was studied using Geant4 monte carlo simulation. X-ray tube under the same condition in the real measurement of the protection rate was simulated, and X-ray tube spectrum was obtained. The X-ray tube spectrum was applied to study on the protection rate and lead equivalent. The porosity effect was simulated, and was one of key factors to determine protection rate or lead equivalent in radiation protection sheet of Pb-free.