• Journal of the Korea Organic Resources Recycling Association
• /
• v.12 no.2
• /
• pp.82-90
• /
• 2004

This study was conducted to evaluate in situ soil flushing and coagulation for naphtalenes-contaminated soil remediation. Mixed-surfactant of 1% POE12 and 1% SDS (1 : 1 by volume basis) was used as a flushing solution. When 5 pore volumes of mixed -surfactant were added to soil column, the flushing efficiencies of 2-methylnaphtalene and 1,5-dimethylnaphtalene with about 1,500 mg/kg(dry soil) were approximately 80% and 60% respectively. In adding 13 pore volumes of mixed-surfactant, the flushing efficiencies of 2-methylnaphtalene and 1,5-dimethylnaphtalene were 90% and 82%. However, considering in situ soil flushing with distilled water, about 42% and 71% were flushed for 2-methylnaphtalene and 1,5-dimethylnaphtalene by surfactant-only. For about 10,000 mg/kg(dry soil) diesel-contaminated soil, 40% and 70% of TPH were flushed-out in 5 pore volumes and 13 pore volumes addition. However, for naphtalenes in diesel TPH, 90% of flushing efficiency was discovered in adding only 5 pore volumes of flushing solution. There was not discovered significant difference among coagulation efficiencies of 6 kinds of polymers, and the coagulation efficiencies were near 50%.

• Proceedings of the Korean Environmental Sciences Society Conference
• /
• 2006.11a
• /
• pp.88-91
• /
• 2006

• Proceedings of the Korean Fiber Society Conference
• /
• 1998.10a
• /
• pp.215-218
• /
• 1998

Poly(ethylene-2,6-naphthalene dicarboxylate)(PEN)의 분자구조는 주사슬내에 PET의 벤젠환 자리에 나프탈렌환으로 치환된 구조로서, 분자자체의 특성상 강직성을 가지며 PET에 비하여 고탄성률과 고융점을 가짐으로써 산업용 재료로써 주목되고 있음은 잘 알려진 사실이다. (중략)

• Proceedings of the Korean Fiber Society Conference
• /
• 1994.10a
• /
• pp.48-49
• /
• 1994

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.26 no.8
• /
• pp.1077-1087
• /
• 2002

The heat (mass) transfer characteristics on the blade surface of a high-turning first-stage turbine rotor for power generation has been investigated by employing the naphthalene sublimation technique. A four-axis profile measurement system is developed successfully for the measurements of local sublimation depth on the curved surface In the leading edge region, there is a good agreement between the present heat (mass) transfer data and the previous result on a turbine blade with a moderate turning angle, but some discrepancies are found in the mid-chord heat (mass) transfer between the two results. The local heat (mass) transfer on the present suction surface is greatly enhanced due to an earlier boundary transition, compared with that on a turbine blade with a moderate turning angle, meanwhile there is only a slight change in the pressure-side heat (mass) transfer between the two different turbine rotors. In general, the heat (mass) transfer augmentation by the endwall vortices is found much higher on the suction surface than on the pressure surface.

• Journal of the Korean Chemical Society
• /
• v.27 no.1
• /
• pp.1-8
• /
• 1983

Solvent effects on nucleophilic substitution reaction of naphthalene sulfonyl chlorides with pyridine in protic and aprotic solvent have been studied by means of conductometry. Results showed that the rate constants increased with dielectric constants for protic solvents, while they decreased with dielectric constants for aprotic solvents, except for acetonitrile which has a higher dielectric constant but had also greater rate constant. The rate constants were shown to be more susceptible to polarity-polarizability parameter, , than to hydrogen bond donor acidity parameter, ${\alpha}$, indicating that the pulling effect of hydrogen bonding solvent.

• Transactions of the Korean hydrogen and new energy society
• /
• v.29 no.4
• /
• pp.331-338
• /
• 2018

In this study, sulfonated PAES block copolymers have been synthesized via nucleophilic substitution reaction. Hydrophobic oligomer was prepared using 2,6-dihydroxynaphthalene and bis(4-chlorophenyl) sulfone, whereas hydrophilic oligomer was prepared using sulfonated bis(4-chlorophenyl) sulfone and bis(4-hydroxyphenyl) sulfone. The chemical structure of polymers was analyzed by $^1H$ NMR, FT-IR and GPC. The thermal properties of polymers were measured by TGA and DSC. The oxidative stability of membranes was investigated by Fenton's test. Furthermore, the proton conductivity of membrane was found to be 26 mS/cm at $90^{\circ}C$. All physiochemical properties suggest that fabricated membrane have a great potential for applications in PEMFC.

• Journal of Energy Engineering
• /
• v.5 no.1
• /
• pp.80-86
• /
• 1996

Naphthalene hydrogenation reaction was performed as a model reaction for coal liquefaction. Product distributions of tetralin and decalin are sensitive to reaction temperature and hydrogen pressure. At 380$^{\circ}C$, hydrogenation reaction using sulfided pellet catalysts gives poor reproducibility and several experimental methods are tried to examine its cause. It was inferred that H$_2$S had, most possibly, a great effect on this phenomena and the effect of H$_2$S was systematically investigated at 250$^{\circ}C$. It is possible that the intermediate hydroaromatic compound (tetralin) is maximized by changing the partial pressure of H$_2$S. It was identified that the partial pressure of H$_2$S could be another important factor in addition to the reaction time and temperature in coal liquefaction using sulfided catalysts.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.25 no.3
• /
• pp.356-365
• /
• 2001

Heat (mass) transfer characteristics have been investigated on the endwall of a large-scale linear turbine cascade. Its profile is based on the mid-span of the first-stage rotor blade in a industrial gas turbine. By using the naphthalene sublimation technique, local heat (mass) transfer coefficients are measured for two different free-stream turbulence intensities of 1.3% and 4.7%. The results show that local heat (mass) transfer Stanton number is widely varied on the endwall, and its distribution depends strongly on the three-dimensional vortical flows such as horseshoe vortices, passage vortex, and corner vortices. From this experiment, severe heat loads are found on the endwall near the blade suction side as well as near the leading and trailing edges of the blade. In addition, the effect of the free-stream turbulence on the heat (mass) transfer is also discussed in detail.

• Applied Chemistry for Engineering
• /
• v.26 no.2
• /
• pp.234-238
• /
• 2015

The separation of nitrogen heterocyclic compound (NHC) contained in a model coal tar fraction was compared by the methanol and formamide extraction. The model coal tar fraction comprising four kinds of NHC (NHCs : quinoline, iso-quinoline, indole, quinaldine) and three kinds of bicyclic aromatic compound (BACs : 1-methylnaphthalene, 2-methylnaphthalene, dimethylnaphthalene), biphenyl and phenyl ether was used as a raw material. The aqueous solution of methanol and formamide were used as solvents. A batch-stirred tank was used as the raw material - a solvent contact unit of this work. Independent of the solvent used, the distribution coefficient of NHCs sharply increased by decreasing the initial volume ratio of water to the solvent and increasing the equilibrium operation temperature, whereas, the selectivity of NHCs in reference to BACs decreased. Decreasing the initial volume ratio of solvent to feed resulted in deteriorating distribution coefficients, but the selectivity of NHCs in reference to BAC was almost the constant. The distribution coefficient of NHCs by the methanol extraction was 3~5 times higher than that of NHCs by the formamide extraction, inversely, the selectivity of NHCs based on BACs by the formamide extraction was 3~7 times higher than that of NHCs by the methanol extraction. Furthermore, two different solvent extraction methods by adding the extraction processing speed to the balance between solvency and selectivity of NHCs were compared.