• Journal of the Korean Society of Propulsion Engineers
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• v.19 no.4
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• pp.69-76
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• 2015

Recently, environmental sustainability of the transitional explosives and propellants is an issue of growing importance in energetic materials. For examples, ammonium perchlorate(AP) as an solid propellants oxidizer could create a poisonous gas and atmospheric pollutions, such as HCl. Among the several oxidizers, hydrazinium nitroformate(HNF) is an effective candidate substance for eco-friendly oxidizer, which has high density, pressure index, and less smog generating property during combustion for the Divert and Attitude Control System(DACS). This study was confirmed a synthesis through various conditions, was performed for the essential data of solubility the crystallization process. Also, crystallization process such as cooling, drowning-out and sonication were performed.

• Journal of the Korean Society of Propulsion Engineers
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• v.20 no.6
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• pp.76-82
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• 2016

Recently, environmental sustainability of the transitional explosives and propellants is an issue of growing importance in energetic materials. For examples, ammonium perchlorate(AP) as an solid propellants oxidizer could create a poisonous gas and atmospheric pollutions, such as HCl. Among the several oxidizers, hydrazinium nitroformate(HNF) is an effective candidate substance for eco-friendly oxidizer, which has high density, pressure index, and less smog generating property during combustion for the thrust control system. This study was controlled the size distribution and shapes through various conditions. Length and diameter ratio(L/D) of crystals has below 1 : 3, and the particle size was two types of $200{\mu}m$ and $50{\mu}m$.