• Economic and Environmental Geology
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• v.57 no.5
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• pp.563-575
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• 2024

In Korea, talc, vermiculite, sepiolite, and serpentine were designated as minerals likely to contain asbestos (MLCA) according to the Ministry of Environment (Asbestos Safety Management Act). The asbestos content in commercial products made of MLCA must not exceed 0.1 %. In this study, mineralogical analyses using PLM, XRD, and TEM-EDS were used to characterize the presence, content, and morphological characteristics of asbestos in MLCA-containing commercial products. A total of 28 samples were analyzed, including 18 cosmetics containing talc, 5 fertilizers containing vermiculite, 2 pet sanitary products containing sepiolite, and 3 accessories containing serpentine. All samples were heated at 450 ℃ for 6 hours to remove organic matter prior to XRD and PLM analyses according to the Ministry of Environment guidelines. Additionally, the presence and morphology of elongated mineral particles (EMPs) were investigated using TEM-EDS analysis according to the recently revised asbestos analysis method (FDA-2020-N-0025) by the US FDA. The analyses showed that no asbestos was detected in both talc-containing cosmetics and sepiolite-containing products, but actinolite asbestos was found (<0.25 %) in vermiculite-containing fertilizers and chrysotile was found (<0.25 %) in decorative serpentine stones. In TEM-EDS analysis, multiple columnar/fibrous particles measuring 0.5 ㎛ or more in length were observed in talc-containing products, and short chrysotile fibers were observed in bracelets containing serpentine. Therefore, these results indicated that the MLCA-containing products that come into direct contact with the human body would require management through precise inspection and continuous monitoring considering EMPs of 5 ㎛ or less. Furthermore, TEM-EDS for asbestos analysis indicated that it could overcome the detection limits of XRD and PLM analyses for short or thin asbestos fibers, thereby improving the precision and accuracy of asbestos analysis.