• Proceedings of the Materials Research Society of Korea Conference
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• 2003.11a
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• pp.197-197
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• 2003

현재 PDP(Plasma Display Panel) 투명유전체층은 PbO 계열을 사용하고 있으나 제조공정 시 다량의 중금속 페기물이 방출됨에 따라 환경오염을 야기시킴으로 무연조성이며 저온소성이 가능한 저융점유리인 인산염계 유리에 대한 열적, 화학적, 광학적 특성에 대해 체계적인 연구가 진행되었다. 광학적 특성을 위 한 승온속도, 소성온도, 유지시간의 변화 그리고, 프릿 입도에 따른 광 투광성, 기포의 형성, 그리고 기포의 분포특성을 연구하였다. 열적특성은 DTA와 TMA를 이용하여 유리전이점(Tg) 및 선팽창계수(CTE)와 Littleton softning point (Ts)가 측정되었다. 광학적특성은 스크린프린팅법으로 후막 제조 후 소성하여 UV-visible spectrometer을 이용하여 300~800nm영역에서 투광성을 측정하였으며, FEG-SEM, AFM을 이용해 표면을 관찰하였다. 결과로써, Tg는 440-46$0^{\circ}C$ 와 CTE는 7~8.5$\times$$10^{-6}$K값을 보였고 높은 화학적 내구성과 60-80%의 광투과율을 나타내었다. 프릿의 미세화, 숭온속도의 감소는 기포의 생성을 줄이는데 효과를 보였으며, 그 결과 양호한 광투과율을 얻을 수 있었다. 이러한 결과에 따르면, P$_2$O$_{5}$-ZnO-RO 조성은 PDP용 투명유전체 조성으로써 기존의 PbO계열을 대체할만한 새로운 조성으로 고려된다.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.6
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• pp.447-452
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• 2011

In this study, the polymeric membrane module is used as a diffuser and an image analysis technique based on visual information is applied to get bubble characteristics. The bubble size generated passed through polymeric membrane module was smaller from 30 to 64% than that of air stone, and bubble volume over 70% was ranged from 0.2 to 0.82 mm. But over 80% the bubbles from air stone diffuser ranged from 0.77 to 1.08 mm. The air stone and polymeric membrane module used as diffuser for a flotation system. The floc size inside the flotation reactor using air stone diffuser was bigger than that of the polymeric membrane module, which means that the micro-bubbles generated from polymeric membrane module could provide better opportunities for collisions between colloidal particles than those from air stone diffuser. Therefore, there is a possibility to apply the polymeric membrane module as a diffuser to increase the removal efficiency in the flotation process. Also, the image analysis technique used in this study could be applied as a useful analytical tool for acquisition of an information about the bubble characteristic.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.10
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• pp.144-149
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• 2020

Bubble reduction devices are intended to solve problems related to the quantitative supply of oil. Therefore, in this study, numerical analysis was conducted to verify the flow characteristics of bubble particles during the operation of a bubble reduction device. As a result of the basic analysis, the area where the rise and fall of bubbles were most active was found, and numerical calculations were performed focusing on the points. Before the numerical calculations, a non-dimensional derivation was performed to secure homogeneity among the variables. Based on the data obtained from non-dimension derivation, 25 variable conditions for each particle size and fluid velocity were set. Through separate calculations, the equation for bubble rise and fall was derived. By calculating the ratio of drag and buoyancy for each variable, if the drag force acting on the bubble was greater than buoyancy, the bubble falls, and bubbles are not reduced. If the buoyancy is larger than drag, the bubble rises, and the bubble is reduced. Through the analysis, the rise and fall of the bubble were confirmed, and the results were consistent with the separate numerical calculations.

• Polymer(Korea)
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• v.26 no.2
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• pp.218-226
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• 2002

For the preparation of high resilience polyurethane (PU) foams with polyether type cell openers which have different ethylene oxide (EO) content, molecular weight and chain structure, the influences of tell opener structure on the kinetics, rheology, structural stability, open cell content and mechanical properties of the obtained foam were investigated. It was observed that urea formation reaction was delayed with the increase of EO content and incorporation of ester linkage in cell opener molecule and was relatively independent on the molecular weight. With the rheological studies, the decreases of viscosity and storage modulus were confirmed for the increase of EO content and molecular weight, so that the resulted foam had low structural stability and high open cell content. The cell opener having ester linkage in molecule exhibited the lowest values of viscosity and storage modulus and the obtained foam has high open cell content. However, the structural stability increased due to the larger intermolecular interaction of ester linkage. The hardness, tensile strength, tear strength and elongation of foam were deteriorated with increase of EO content and molecular weight of tell opener. On the other hand, the cell opener having ester linkage in molecule improved the values of tensile strength, tear strength and elongation.

• Composites Research
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• v.18 no.3
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• pp.47-52
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• 2005

Pultrusion process of phenolic foam composite is investigated. Phenolic foam composites provide heat and flame resistance with less weight. When made into foam, a variety of properties can be obtained with different bubble size and number density. In this study, effect of process variables on the foaming characteristics of phenolic resin composites during pultrusion process has been studied experimentally. The process variables considered are the heating temperature and the pulling speed as well as the mass fraction of blowing agent. Experiments were performed using a laboratory scale pultrusion apparatus. Optimal process condition was found by observing the micro-morphology.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.2 no.2
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• pp.1-1
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• 1992

YIG(Yttrium Iron Garnet) single crystals were grown by FZ(Floating Zone) method. Since YIG melts incongruently, TSFZ(Traveling Solvent Floating Zone) method which was modified FZ was applied to grow YIG single crystals. The optimum growth condition were growth rate Imm/hr, counter-rotation 30rpm and oxidized atmosphere was necessary to sintering and growth process. The quality of grown crystals depended on the degree of sintering. The voids were generated by the reaction of Fe ions with oxygen and the density of voids was increased with the growth rate increased. When the growth rate was more than 1.5mm/hr, the cellular growth occured and the density of dislocation was increased at the periphery of crystals. Also, secondary phases of orthoferrite(YFe$O_3$)compost ion were observed in the grown crystal.

• Korean Chemical Engineering Research
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• v.50 no.3
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• pp.505-510
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• 2012

The gas hold-up has a strong relationship with the size distribution and rising velocities of bubbles in a bubble column. Therefore, many previous researchers have studied on the hydrodynamics focusing on the bubble size variation in bubble column. In this study, the bubble behavior was influenced by partitioning porous plates installed at a certain height in a trayed bubble column. The gas hold-up was increased in non-sparging region (H/D > 5) as well as sparging region. We identified the effect of the partitioning porous plate using three trayed bubble columns with different reactor geometries. Furthermore, the bubble break-up frequency and size distribution were observed before and after individual bubbles penetrated through the plate. The arrangement of the plates was also investigated using a 0.15-m-in-diameter bubble column. Based on the result, we applied this design concept to a 0.36-m-in-diameter, 22 m tall trayed bubble column and identified the effect of the partitioning porous plate on the gas hold-up increase.

• Journal of the Korean Geotechnical Society
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• v.26 no.2
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• pp.23-32
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• 2010

This study was especially conducted to find out the characteristics of the lightweight air-mixed soil (slurry density 10 kN/$m^3$) containing silt related to water. Compression strength, permeability, and capillary height of the lightweight air-mixed soil were studied, and also to support these studies, the structure of that soil was analyzed in detail. Air bubbles of various sizes are inside the lightweight air-mixed soil, and its distribution in a location is almost constant. A numerous tiny pores are inside the air bubbles so that the lightweight air-mixed soil can be saturated with water. Porosity is also estimated through the image analysis. Peak strength of the lightweight air-mixed soil is not dependent on water, but behavior of stress-strain is affected by the water. Permeability is about $4.857{\times}10^{-6}cm/sec$, which is a little bit higher than the clay's permeability. Capillary rise occurs rapidly at the beginning of the test until the lapse of 100 minutes and then its increase rate becomes slow. The capillary rise causes the increase of the density of the lightweight air-mixed soil, and thus it is required to pay attention to this phenomenon during structure design and maintenance of the lightweight air-mixed soil.

• Korean Journal of Food Science and Technology
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• v.19 no.3
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• pp.220-224
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• 1987

The concentration ranges forming surface excess of bovine serum albumin(BSA) and ovalbumin solutions were determined, and the factors affecting the foam separation of BSA were investigated. The surface tension of BSA solution decreased from 72 to 61 dynelcm, when the concentration changed from $5{\times}10^{-3}$ to $3{\times}10^{-2}%$, and the critical micelle concentration was appeared to be at 0.03% of BSA. At the isoelectric point (pH 4.9) of BSA, the foamate volume was maximum, but enrichment ratio was minimum, resulting in the maximum recovery rate. When the pH deviated from the isoelectric point, the foamate volume decreased and the enrichment ratio increased. The enrichment ratio increased, while the foamate volume decreased drastically as the temperature was elevated above $20^{\circ}C$, resulting in the decrease in recovery rate. As the gas flow rate increased, the enrichment ratio decreased and the foamate volume increased. When $(NH_4)_2SO_4$ was added, the enrichment ratio decreased, but the maximum foamate was obtained at ionic strength 7. The concentration to form the surface excess of ovlbumin, which has lower surface hydrophobicity than BSA, was 200 times higher than that of BSA. This fact indicates the possibility of selective foam separation by hydrophobicity difference of proteins.

• Resources Recycling
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• v.27 no.1
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• pp.45-54
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• 2018

This study aimed to investigate the effects of mechanical factors such as agitation speed and air rate in fly ash flotation. Specifically, we used thermal power plant fly ash with unburned carbon content of 3.4 to 3.7%. The effect of pH, agitation speed, collector dosage, and frother dosage - the key factors of froth flotation - showed unburned carbon recovery and unburned carbon content of 63% and 34%, respectively, when the dosage of safflower oil used as collector was 800 g/ton, pH was 7, agitation speed was 1,200 rpm, and frother dosage was 400 g/ton. The SEM/EDS analysis of fly ash in that case indicated that the spherical fly ash particles lowered the unburned carbon content as they floated with the air bubbles without being dissolved in the unburned carbon or settled in the ore solution. The other experiment of changing the mechanical factors such as agitation speed and air rate resulted in unburned carbon recovery and unburned carbon content of 74% and 67%, respectively, at air rate of 8 L/min and agitation speed of 900 rpm. The recovery and unburned carbon content increased as the low agitation speed and additional air injection decreased the strength of the eddy current in the ore solution and consequently prevented the floating of fine fly ash particles with unburned carbon. In addition, the recovery rate and unburned carbon increased further to 80% and 70%, respectively, showing the best performance when the agitation speed and air rate were lowered to 800 rpm and 6 L/min, respectively.