• Title/Summary/Keyword: 기울기계수

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Benzothiazole Substituted Benzocrown Ether-Based Potassium Ion-Selective Membrane Electrodes (벤조티아졸기를 갖는 벤조크라운에테르를 전극물질로 사용한 $K^+$ 이온선택성 막전극)

  • Hong, Uk Sun;Kwon, Hye Kyong;Cha, Geun Sig;Nam, Hakhyun;Chang, Seung Hyun;Chung, Kwang Bo
    • Journal of the Korean Chemical Society
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    • v.39 no.9
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    • pp.698-704
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    • 1995
  • The ion-selective membrane fabricated with 33 wt% PVC, 66 wt% o-NPOE and 1 wt% 4'-benzothiazolylbenzo-15-crown-5 (TB15C5) as a neutral carrier exhibited an enhanced selectivity to potassium ion over sodium ion compared to those prepared with other 15-crown-5 or 18-crown-6 derivatives. The potentiometric properties (response slope, selectivity, detection limits and lifetime) of TB15C5-based ISE membranes along with those based on valinomycin, benzo-15-crown-5 (B15C5), 4'-aminobenzo-15-crouwn-5 (AB15C5), benzo-18-crown-6 (B18C6), dibenzo-18-crown-6 (DB18C6) and bis[(benzo-15-crown-5)-4'-ylmethyl]pimelate (PI-Ⅱ) ionophores were carefully examined under the same experimental conditions. The enhanced selectivity of TB15C5-based membrane to potassium is explained in terms of the effect of the benzothiazol functional group and the distribution coefficients of metal ions.

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Forecast of the Daily Inflow with Artificial Neural Network using Wavelet Transform at Chungju Dam (웨이블렛 변환을 적용한 인공신경망에 의한 충주댐 일유입량 예측)

  • Ryu, Yongjun;Shin, Ju-Young;Nam, Woosung;Heo, Jun-Haeng
    • Journal of Korea Water Resources Association
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    • v.45 no.12
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    • pp.1321-1330
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    • 2012
  • In this study, the daily inflow at the basin of Chungju dam is predicted using wavelet-artificial neural network for nonlinear model. Time series generally consists of a linear combination of trend, periodicity and stochastic component. However, when framing time series model through these data, trend and periodicity component have to be removed. Wavelet transform which is denoising technique is applied to remove nonlinear dynamic noise such as trend and periodicity included in hydrometeorological data and simple noise that arises in the measurement process. The wavelet-artificial neural network (WANN) using data applied wavelet transform as input variable and the artificial neural network (ANN) using only raw data are compared. As a results, coefficient of determination and the slope through linear regression show that WANN is higher than ANN by 0.031 and 0.0115 respectively. And RMSE and RRMSE of WANN are smaller than those of ANN by 37.388 and 0.099 respectively. Therefore, WANN model applied in this study shows more accurate results than ANN and application of denoising technique through wavelet transforms is expected that more accurate predictions than the use of raw data with noise.

A Monte Carlo Study of Secondary Electron Production from Gold Nanoparticle in Kilovoltage and Megavoltage X-rays (몬테칼로 기법을 이용한 금 나노입자에서의 2차 전자 발생 평가)

  • Hwang, Chul-Hwan;Kang, Se-Sik;Kim, Jung-Hoon
    • Journal of the Korean Society of Radiology
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    • v.10 no.3
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    • pp.153-159
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    • 2016
  • This study investigated relationship between secondary electrons produced from single gold nanoparticle as a result of its interaction with radiation and particle size and incidence energy, provided basic data related to the dose enhancement effect based on gold nanoparticles. Monte Carlo simulation was applied by using MCNPX MC code, 50, 100, 150 kV and 6, 15 MV x-ray energy was used. In a water phantom, single gold nanoparticles that are 30, 50, 70, 90, and 110 nm in diameter were placed and the tally volume was designated at every 10 nm. Difference in electrons produced from gold nanoparticles was normalized based on absence of nanoparticle. When the X ray energy decreased and the diameter of gold particles increased, more electrons were produced. When the energy was lower, in the linear formula related to nanoparticle size and electron production, the gradient was higher. And, in comparison to the MV X-ray, at kV X-ray, significantly more electrons were produced. This study can be used as data to understand the dose enhancement effect based on gold nanoparticles, and further research related to various materials that dose enhancement including gold nanoparticles needs to be conducted.

Isotherm, Kinetic, Thermodynamic and Competitive for Adsorption of Brilliant Green and Quinoline Yellow Dyes by Activated Carbon (활성탄에 의한 Brilliant Green과 Quinoline Yellow 염료의 흡착에 대한 등온선, 동력학, 열역학 및 경쟁흡착)

  • Lee, Jong Jib
    • Korean Chemical Engineering Research
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    • v.59 no.4
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    • pp.565-573
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    • 2021
  • Isotherms, kinetics and thermodynamic properties for adsorption of Brilliant Green(BG), Quinoline Yellow(QY) dyes by activated carbon were carried out using variables such as dose of adsorbent, pH, initial concentration, contact time, temperature and competitive. BG showed the highest adsorption rate of 92.4% at pH 11, and QY was adsorbed at 90.9% at pH 3. BG was in good agreement with the Freundlich isothermal model, and QY was well matched with Langmuir model. The separation coefficients of isotherm model indicated that these dyes could be effectively treated by activated carbon. Estimated adsorption energy by Temkin isotherm model indicated that the adsorption of BG and QY by activated carbon is a physical adsorption. The kinetic experimental results showed that the pseudo second order model had a better fit than the pseudo first order model with a smaller in the equilibrium adsorption amount. It was confirmed that surface diffusion was a rate controlling step by the intraparticle diffusion model. The activation energy and enthalpy change of the adsorption process indicated that the adsorption process was a relatively easy endothermic reaction. The entropy change indicated that the disorder of the adsorption system increased as the adsorption of BG and QY dyes to activated carbon proceeded. Gibbs free energy was found that the adsorption reaction became more spontaneous with increasing temperature. As a result of competitive adsorption of the mixed solution, it was found that QY was disturbed by BG and the adsorption reduced.

Analysis of solute transport in rivers using a stochastic storage model (확률론적 저장대모형을 이용한 하천에서의 물질혼합거동 해석)

  • Kim, Byunguk;Seo, Il Won;Kwon, Siyoon;Jung, Sung Hyun;Yun, Se Hun
    • Journal of Korea Water Resources Association
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    • v.54 no.5
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    • pp.335-345
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    • 2021
  • The one-dimensional solute transport models have been developed for recent decades to predict behavior and fate of solutes in rivers. Transient storage model (TSM) is the most popular model because of its simple conceptualization to consider the complexity of natural rivers. However, the TSM is highly dependent on its parameters which cannot be directly measured. In addition, the TSM interprets the late-time behavior of concentration curves in the shape of an exponential function, which has been evaluated as not suitable for actual solute behavior in natural rivers. In this study, we suggested a stochastic approach to the solute transport analysis. We delineated the model development and model application to a natural river, and compared the results of the proposed model to those of the TSM. To validate the proposed model, a tracer test was carried out in the 4.85 km reach of Gam Creek, one of the first-order tributaries of Nakdong River, South Korea. As a result of comparing the power-law slope of the tail of breakthrough curves, the simulation results from the stochastic storage model yielded the average error rate of 0.24, which is more accurate than the 14.03 and 1.87 from advection-dispersion model and TSM, respectively. This study demonstrated the appropriateness of the power-law residence time distribution to the hyporheic zone of the Gam Creek.

Current status of fish fauna and Zacco platypus population in the Cheonggyecheon stream (청계천의 어류상 및 피라미(Zacco platypus) 개체군 현황)

  • Wang, Ju Hyoun;Choi, Won Sub;Choi, Jun Kil;Lee, Hwang Goo
    • Korean Journal of Environmental Biology
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    • v.39 no.1
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    • pp.68-80
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    • 2021
  • This study aimed to present the current status of exotic fish species, invasive species, and dominant species inhabiting the Cheonggyecheon stream. We conducted three samplings from April to October 2019. A total of 2,045 individuals from 27 species belonging to nine fish families were collected. There were five Korean endemic species (18.5%) including Coreoleuciscus splendidus, Sarcocheilichthys nigripinnis morii, Squalidus gracilis majimae, Zacco koreanus, and Odontobutis interrupta in the Cheonggyecheon stream. The dominant species was Zacco platypus (62.4%) and the subdominant species was Z. koreanus (9.8%). The length-weight analysis of the dominant species Z. platypus population showed a regression coefficient b of 3.3434 and a condition factor(k) of 0.0026, with a positive slope. The growth state of the Z. platypus population was identified as being in a very favorable condition. The Cheonggyecheon stream is considered to be an appropriate habitat for the Z. platypus population. Since the restoration, The Cheonggyecheon stream has had continuous problems due to the introduction of exotic species and invasive species and in this study, exotic species, Gyrinocheilus aymonier var.(gold type), and invasive species, Coreoleuciscus splendidus, which have not previously been reported in the Cheonggyecheon stream, appeared. Therefore, it is deemed necessary to prepare continuous publicity and management measures to prevent exotic species and invasive species from inhabiting the Cheonggyecheon stream.

Analysis of a Comparability Test between LX Detergent Cleaning Solution and OC Detergent Cleaning Solution Using OC Sensor PLEDIA (OC Sensor PLEDIA를 이용한 LX Detergent Cleaning Solution과 OC Detergent Cleaning Solution의 동등성 평가)

  • Cha, Kyung Jae
    • Korean Journal of Clinical Laboratory Science
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    • v.53 no.1
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    • pp.19-31
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    • 2021
  • This study aimed at comparing the performance of imported LX detergent cleaning solution (LX-CS) and the self-manufactured OC cleaning solution (OC-CS), based on functional and quantitative analysis. The functional analysis was carried out using apparent diffusion coefficient (ADC) values. For quantitative analysis, precision, linearity, and carry-over rates were measured with commercial control materials according to the Clinical and Laboratory Standards Institute (CLSI) guidelines. Using OC-Sensor PLEDIA (Eiken Chemical, Japan), the ADC value of all cuvettes satisfied the acceptance criteria. For quantitative analysis, precision was less than 5.0% for the two products, and carry-over rates were less than ±1.00%. The linearity slopes and r2 values were 1.0017 and 0.9982 in the LX-CS, and 0.9924 and 0.9996 in the OC-CS, respectively. The correlation coefficient (r) was found to be 0.9997. Also, the percent difference in correlation with 40 artificial-stool specimens was less than 10% and the p-value was less than 0.1. The result of standard deviation ratio (D: ±1 SD ratio) was similar for both products. In conclusion, the functional and quantitative analyses of the two products were compared and showed similar results. In the future, the self-manufactured OC-CS will be able to provide a much more stable and faster supply than the imported LX-CS.

Line-Segment Feature Analysis Algorithm for Handwritten-Digits Data Reduction (필기체 숫자 데이터 차원 감소를 위한 선분 특징 분석 알고리즘)

  • Kim, Chang-Min;Lee, Woo-Beom
    • KIPS Transactions on Software and Data Engineering
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    • v.10 no.4
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    • pp.125-132
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    • 2021
  • As the layers of artificial neural network deepens, and the dimension of data used as an input increases, there is a problem of high arithmetic operation requiring a lot of arithmetic operation at a high speed in the learning and recognition of the neural network (NN). Thus, this study proposes a data dimensionality reduction method to reduce the dimension of the input data in the NN. The proposed Line-segment Feature Analysis (LFA) algorithm applies a gradient-based edge detection algorithm using median filters to analyze the line-segment features of the objects existing in an image. Concerning the extracted edge image, the eigenvalues corresponding to eight kinds of line-segment are calculated, using 3×3 or 5×5-sized detection filters consisting of the coefficient values, including [0, 1, 2, 4, 8, 16, 32, 64, and 128]. Two one-dimensional 256-sized data are produced, accumulating the same response values from the eigenvalue calculated with each detection filter, and the two data elements are added up. Two LFA256 data are merged to produce 512-sized LAF512 data. For the performance evaluation of the proposed LFA algorithm to reduce the data dimension for the recognition of handwritten numbers, as a result of a comparative experiment, using the PCA technique and AlexNet model, LFA256 and LFA512 showed a recognition performance respectively of 98.7% and 99%.

Changes in the Chlorophyll of Garlic Chives (Allium tuberosum) Resulting fromFertilizer and Drought Stress (비료와 가뭄 스트레스에 의한 부추의 엽록소 변화)

  • Huh, Man Kyu;Lee, Byeongryong
    • Journal of Life Science
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    • v.32 no.10
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    • pp.743-748
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    • 2022
  • The garlic chive (Allium tuberosum Rotter) is a prominent herb species in Asia and other nations of the world. Garlic chives is a favorite vegetable and used to garnish noodles in Korea. The effects of various doses of N, P, and K fertilizers and drought stress on the chlorophyll content in the leaves of garlic chives were investigated. The evaluations showed that chlorophyll a content was 0.386 at 10 mg/l N fertilizer and 0.584 at 50 mg/l N fertilizer. The treatment group showed a significant difference with regard to the contents of chlorophylls a and b and total chlorophyll at the 5% level (p<0.05). Pearson's correlation coefficient (Pearson's r) for chlorophylls a and b and total chlorophyll were 0.940, 0.966, and 0.971, respectively. The highest content of chlorophylls a and b and total chlorophyll in the leaves was recorded at 40 mg/l P fertilizer, while the values corresponding to 50 mg/l P fertilizer were lower than those for 40 mg/l P fertilizer. The content of total chlorophyll evaluated at 10 mg/l K fertilizer was 0.312 and that at 50 mg/l was 0.589. The simple linear regression showed the relationship between chlorophyll efficiency aand moisture. The slope factors of the dark-level fluorescence yield (Fo), the maximum fluorescence yield (Fm), the quenched state (Fv), and the maximal PSII quantum yield (Fv/Fm) for chlorophyll-efficient indicators were -0.931, 0.972, 972, and 0.950, respectively. NPK fertilizers and drought stress affected the chlorophyll content and efficiency of A. tuberosum.

Dynamic Behavior Characteristics of Group Piles with Relative Density in Sandy Soil (건조 모래지반의 상대밀도에 따른 무리말뚝의 동적거동특성)

  • Heungtae Kim;Hongsig Kang;Kusik Jeong;Kwangkuk Ahn
    • Journal of the Korean GEO-environmental Society
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    • v.24 no.9
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    • pp.33-40
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    • 2023
  • The lateral load which is applied to the pile foundation supporting the superstructure during an earthquake is divided into the inertia force of the upper structure and the kinematic force of the ground. The inertia force and the kinematic force could cause failure to the pile foundation through different complex mechanisms. So it is necessary to predict and evaluate interaction of the ground-pile-structure properly for the seismic design of the foundation. The interaction is affected by the lateral behavior of the structure, the length of the pile, the boundary conditions of the head, and the relative density of the ground. Confining pressure and ground stiffness change accordingly when the relative density changes, and it results that the coefficient of subgrade reaction varies depending on each system. Horizontal bearing behavior and capacity of the pile foundation vary depending on lateral load condition and relative density of the sandy soil. Therefore, the 1g shaking table tests were conducted to confirm the effect of the relative density of the dried sandy soil to dynamic behavior of the group pile supporting the superstructure. The result shows that, as the relative density increases, maximum acceleration of the superstructure and the pile cap increases and decreases respectively, and the slope of the p-y curve of the pile decreases.