• Title/Summary/Keyword: 기공형태

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Preparation of Mesoporous Molecular Sieve by the Reaction of Na2SiO3 and H2SiF6 in the Presence of an Aqueous Nonionic Surfactant Solution (비이온성 계면활성제 수용액에서 Na2SiO3와 H2SiF6의 반응을 통한 메조포러스 실리카의 제조)

  • Kim, Jin-Yeong;Kwon, Oh-Yun
    • Applied Chemistry for Engineering
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    • v.29 no.1
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    • pp.122-126
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    • 2018
  • Mesoporous molecular sieves were prepared by the reaction of $Na_2SiO_3$ and $H_2SiF_6$ using nonionic micelle templates in an aqueous solution. Well-crystalline mesoporous molecular sieves were obtained after several seconds at atmospheric conditions. Powder samples exhibited d-spacing of 3.8-5.1 nm with the sharpness of the d00l peak, showing well-crystalline mesoporous molecular sieves, pore size distributions of 2.5-3.1 nm and large specific surface areas of $290-1,018m^2/g$, depending on types of surfactants. SEM images of samples showed well-divided spherical particles with an uniform size of ${\sim}0.5{\mu}m$ and TEM images demonstrated uniform pores with a worm hole shape.

The Synthesis and Mechanical Property of Calcium Silicate Hydrates Using the Amorphous Silicates (비정질 규산원료를 이용한 칼슘실리케이트 수화물 합성과 역학적 특성)

  • 엄태선;최연묵;최상흘
    • Journal of the Korean Ceramic Society
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    • v.34 no.1
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    • pp.45-55
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    • 1997
  • Various kinds of amorphous silicates were used as raw materials to synthesize building materials based on calcium silicate hydrates. Relationships between the reactivities of silicates and castabilities of the building materials were investigated. In addition, effects of the reactivities of silicates on the mechanical properties of casted specimens were studied by analyzing microstructures and hydrates produced. As the reactivity of silicate increase, the press castability increases and the crystal size of hydrate and pore size also increase. For the mechanical properties, the flexural strength increases with decreasing crystal size and densifing microstructure. The compressive strength is greatly dependent on the den-sification of microstructure rather than crystal size of hydrate. Based on the results, diatomous ma-terials are desirable due to high reactivity and formation of densified microstructure. Slag and fly ash may be partially used as raw materials with amorphous silicates to manufacture building materials based on calcium silicate hydrates.

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A Study on the tooth size and shape of the permanent Incisor teeth (영구치 절치의 크기와 형태에 관한 연구)

  • Lee, Tae-Jung;Shin, Jong-Woo
    • Journal of Technologic Dentistry
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    • v.15 no.1
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    • pp.89-94
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    • 1993
  • The tooth size and shape of the permanent incisor teeth have been studied and analyzed about the mean size, S.D, S.E, etcs and percentage from stone model of 100 Korean male and 74 Korean female. The results were as follows. 1. The crown length of permanent incisor teeth were longer in males than in females statistical differences of males and female were not found. 2. the mesio-distal diameters of permanent incisor teeth were larger in males than in females and statistical differences of males and females were found in mandibular lateral incisor and the bigest were max. central incisor, 2nd max. lateral incisor, 3rd man. lateral incisor and the smallest were man. central incisor. 3. The square form in max. central incisor was the greatest percentage and the tapering form in max. lateral incisor and man, incisor was the greatest percentage but tapering form and ovoid form and other shape were found in max. lateral at the same ratio. 4. Concerning the labial developmental groove "midium" was the greatest percentage in the max. central incisor and "low" was the greatest percentage in the man incisor. Concerning the incisal line, straight line was the greatest percentage in the max, incisor and man, incisor and concerning the lingual tubercle "none" was the greatest percentage in the max. incisor. 5. In comparison between left side and right side of incisor, the ratio of same shape ware 22.4%-36.2% but similar or dissimilar cases were more frequently found.

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Micromechanical Model for the Consolidation Behavior in SiC-Ti Metal Matrix Composites (SiC-Ti금속기 복합재료의 강화거동에 관한 미시역학적 모델)

  • 김준완;김태원
    • Composites Research
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    • v.16 no.3
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    • pp.1-8
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    • 2003
  • Densification occurs by the inelastic flow of the matrix materials during the consolidation processes at high temperature for MMCs, and the results depend on many process conditions such as applied pressure, temperature and volume fraction of fiber and matrix materials. This is particularly important in titanium matrix composites since material failure may occur by either the applied conditions or microstructural parameters through the processes, and thus a generic model based on micro-mechanical approaches enabling the evolution of density over time to be predicted has been developed. The mode developed is then implemented into FEM so that practical process simulation has been carried out. Further the experimental investigation of the consolidation behavior of SiC/Ti-6Al-4V composites using vacuum hot pressing has been performed, and the results obtained are compared with the model predictions.

Effect of Wind Velocity on Photosynthesis, Sap Flux, and Damage of Leaves in Apple Trees (풍속이 사과나무의 광합성 특성과 수액이동 및 엽손상에 미치는 영향)

  • Yim, Ji Hye;Choi, Young Min;Choi, Dong Geun
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.16 no.2
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    • pp.131-136
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    • 2014
  • This study was carried out to determine the effects of wind speed on physiological responses in 'Fuji' apple (Malus pumila Miller). Two levels of wind blowing (3 and $5m{\cdot}s^{-1}$) were produced by large electric fans. Photosynthetic rate was reduced by one-way wind blowing treatment at $5m{\cdot}s^{-1}$, compared to the mild wind control, and this reduction was more obvious with stronger wind and increasing duration of wind application. The reduction in photosynthesis by the wind treatments was correlated with that in the proportion of opened stomates and stomatal conductance. The one-way wind treatment at $5m{\cdot}s^{-1}$ caused a leaf browning and leaf fall, and this negative effect became more serious with increasing time of exposure to the wind treatments. The sap flux through stem increased in all wind treatments compared to the natural mild wind.

Synthetic Characteristics of Porous Polymeric Catalyst Support (다공성 고분자촉매 담체의 제조 특성)

  • Kang, Hee-Suk;Lee, Han-Soo;Chung, Hongsuk;Ahn, Do-Hee;Son, Soon-Hwan;Chung, Yang Geun;Song, Myung-Jae
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.715-725
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    • 1996
  • This study represents the synthetic characteristics of styrene-DVB copolymer which is used as a catalyst support for the removal of tritium in CANDU. To evaluate the effect of solvent on the styrene-DVB polymeric support, the solvating power dependent on various kinds and composition of solvents was calculated. In order to synthesize the macroreticular type polymer bead, the following conditions are needed; solvating power should be higher than 1 for 20% of crosslinkage and higher than 3 for 40% of crosslinkage. Stabilization of organic monomers at about $40^{\circ}C$ for more than 2 hours is prerequisite. Removal of solvent prior to drying is preferred for the post-treatment of the bead. The polymer particle size was increased by lowering concentration of surfactant and stirring speed.

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Association between mandibular occlusal morphology and occlusal curvature (교합면의 해부학적 형태와 교합만곡의 연관성에 대한 연구)

  • Nam, Shin-Eun;Lee, Heekyung
    • Journal of Technologic Dentistry
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    • v.38 no.3
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    • pp.217-224
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    • 2016
  • Purpose: This study aimed to generate 3-D occlusal curvatures and evaluate the relationship between the occlusal curvatures and mandibular occlusal morphology factors. Methods: Mandibular dental casts from 25 young adult Korean were scanned as a virtual dental models with a 3-D scanner(Scanner S600, Zirkonzahn, Italy). The curve of Spee, curve of Wilson, and Monson's sphere were generated by fitting a circle/sphere to the cusp tips using a least-squares method. The mandibular mesiodistal cusp inclination, buccolingual cusp inclination, and tooth wear parameters were measured on the prepared virtual models using RapidForm2004(INUS technology INC, Seoul, Korea). Wilcoxon signed-rank test was performed to test side difference, and Spearman's rank correlation coefficients were investigated to verify the correlation between occlusal curvatures and correlated factors (a=0.05). Results: The mean radii of curve of Spee were $83.09{\pm}33.94$ in the left side and $79.00{\pm}28.12mm$ in the right side. The mean radii of curve of Wilson were $66.82{\pm}15.87mm$ in the mesial side and $47.87{\pm}9.40mm$ in the distal side with significantly difference between mesiodistal sides(p<0.001). The mean radius of Monson's sphere was $121.85{\pm}47.11mm$. Most of the cusp inclination parameters showed negative correlation for the radius of Monson' sphere(p<0.05). Especially, the buccolingual cusp inclinations in mesial side of molar showed high correlation coefficients among the factors(p<0.05). Conclusion: The radius of Monson's sphere was greater than the classical 4-inch values, and the buccolingual cusp inclinations in mesial side of molar can be considered as one of the main factors correlating with the radius of Monson's sphere.

Preparation and Characterization of PSF Membranes by Phosphoric Acid and 2-Butoxyethanol (인산 및 2-부톡시에탄올 첨가에 의한 PSF 고분자 분리막의 제조 및 특성)

  • Kim, Nowon
    • Membrane Journal
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    • v.22 no.3
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    • pp.178-190
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    • 2012
  • Flat sheet membranes were prepared with polysulfone (PSF) by an immersion precipitation phase inversion method. Membranes were prepared with PSF/N-methylpyrrolidone (NMP)/polyvinylpyrrolidone (PVP)/phosphoric acid casting solution and water coagulant. By using the successive process of the vapor-induced phase inversion (VIPS) followed by the nonsolvent-induced phase inversion (NIPS), the effect of phosphoric acid addition to casting solution on morphology and permeability of membrane was studied. The mean pore size, the porosity, and the water flux of membranes were increased by the addition of small amount of phosphoric acid. Furthermore, the morphology of the prepared membranes were changed from a dense sponge-like structure to highly enhanced asymmetric structure. PSF/NMP/PVP/phosphoric acid/2-butoxyethanol (BE) casting solution were prepared and cast the successive VIPS-NIPS process with same experimental condition. Due to the addition of BE to casting solution, the mean pore size and almost 0.1 ${\mu}m$ and the water flux increased about 10 to 12 $L/cm^2{\cdot}min{\cdot}bar$.

Synthesis of Mesoporous TiO2 Thin Films with Polypyrrole Nanoparticles by Ultrasonic-induced Polymerization (초음파 중합에 의한 polypyrrole 나노입자를 함유하는 메조포러스 TiO2 박막의 합성)

  • Jang, Kwang-Suk;Cho, Sung-Ho;Song, Myung-Geun;Kim, Jong-Duk
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.777-782
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    • 2008
  • Using ultrasonic-induced polymerization of pyrrole, mesoporous $TiO_2$ thin film with polypyrrole nanoparticles was prepared. Polypyrrole nanoparticles were ultrasonically synthesized in the mother solution of mesoporous $TiO_2$ before spin-coating. The polypyrrole particles were well dispersed in the solution. After spin-coating and calcinations process, the nanocomposite films have well-organized pore channels without pore-collapse, and polypyrrole nanoparticles are well dispersed in mesoporous $TiO_2$ matrix. The pore size and light absorbance of the mesoporous nanocomposite thin films were controlled by using different template materials, and by using different amount of pyrrole monomer, respectively.

Microstructure and annealing effect on fracture behavior in the dental glass-infiltrated alumina (치아용 유리침윤 알루미나에서 파괴거동에 미치는 미세구조 및 어닐링 효과)

  • 정종원;최성철
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.4
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    • pp.330-336
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    • 2000
  • Effects of microstructure and indentation stress on fracture behavior of glass-infiltrated alumina composite for dental restorative application were investigated by the Hertzian and Vickers indentation method. Indentation stress-strain curve of glass-infiltrated alumina has showed the quasi-plastic behavior - deviation from linearity at high stress and the classical Hertzian cone crack, which could be confirmed the subsurface damage micrographs using bonded-interface specimen technique. The indentation stress-strain curves for the starting preforms are strongly dependent on porosity and microstructure of the preforms. On the other hand, the curves for the infiltrated composites are relatively insensitive to these factors. The failure of composite is originated at quasi-plastic deformation region. Damage and fracture behavior due to Hertzian stress field is theoretically examined, so that the indentation stress field plays a great role in material degradation. After Hertzian indentation annealing processing changes fracture behavior of alumina composite, so that stress field in material is healed through annealing.

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