• 대한치과기공학회지
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• 제11권1호
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• pp.83-88
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• 1989

This investigation was performed to evaluate the effect of four different preteatment techniques on the bond strength of porcelain to non-precious metal alloy. Samples of total of 40 were divided into 4 groups according to the 4 variables which included the 50$\mu$alumina oxide air abrasion, method, the as retention bead method, the L-retention bead method, the Etching method. The completed metal-porcelain samples were compressed in Instron loading machine until gross fracture occured to examine the effect of the complex variables on the bond strength of porcelain to non precious metal alloy. The result obtained were as follows : 1. The difference of bond strength according to four different pretreatment techniques was statistically significant(p<0.01). 2. The difference of bond strength between the ss-retention bead method and the L-retention bead method was not significant statistically(p>0.05) 3. The difference of bond strength between the retention bead method and the etching method was statistically significant(p<0.01). 4. The difference of bond strength between the retention bead method and the 50$\mu$alumina oxide air abrasion method was statistically significant(p<0.01). 5. The difference of bond strength between the etching method and the 50$\mu$alumina oxide air abrasion method was statistically significant(p<0.01).

• 대한치과기공학회지
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• 제35권4호
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• pp.353-358
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• 2013

Purpose: This study was observation shear bonding strength by compositional change and firing step of a Ni-Cr alloy for porcelain fused metal crown. The aim of study was to suggest the material for firing step of Ni71-Cr14 alloy to development of alloy for porcelain fused to metal crown. Methods: The test was on the two kinds of Ni-Cr alloy specimens. The surfaces of two alloys were analyzed by EDX in order to observe oxide characteristic. And the shear test was performed by MTS. Results: The surface property and oxide characteristic analysis of oxide layer, weight percentage of Element O within $Ni_{71}Cr_{14}$ alloy measured 23.32wt%, and $Ni_{59}Cr_{24}$ alloy was measured 23.03wt%. And the maximum shear bonding strength was measured 58.02MPa between $Ni_{59}Cr_{24}$ alloy and vintage halo(H4 group). Conclusion: The surface property and oxide characteristic three kind of Ni-Cr alloy was similar. and shear bonding strength showed the highest bonding strength in H4 specimens.

• 한국분말재료학회지
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• 제7권3호
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• pp.143-148
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• 2000

NiAl alloy powders were prepared by mechanical alloying method and bulk specimens were produced using hot isostatic pressing techniques. This study focused on the transformation behavior and properties of Ni-Al mechanically alloyed powders and bulk alloys. Transformation behavior was investigated by differential scanning calorimeter (DSC), XRD and TEM. Particle size distribution and microstructures of mechanically alloyed powders were studied by particle size analyzer and scanning electron microscope (SEM). After 10 hours milling, XRB peak broadening appeared at the alloyed powders with compositions of Ni-36at%Al to 40at%Al. The NiAl and $Ni_3Al$ intermetallic compounds were formed after water quenching of solution treated powders and bulk samples at $1200^{\circ}C$, but the martensite phase was observed after liquid nitrogen quenching of solution treated powders. However, the formation of $Ni_3Al$ intermetallic compounds were not restricted by fast quenching into liquid nitrogen. It is considered to be caused by fast diffusion of atoms for the formation of stable $\beta$(NiAl) phase and $Ni_3Al$ due to nano sized grains during quenching. Amounts of martensite phase increased as the composition of aluminium component decreased in the Ni-Al alloy, which resulted in the increasing damping properties.

• 한국분말재료학회지
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• 제11권3호
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• pp.247-252
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• 2004

Recently, it has been found that mechanical alloying (MA) facilitates the nanocomposites formation of metal-metal oxide systems through solid-state reduction during ball milling. In this work, we studied the MA effect of Fe$_{3}$O$_{4}$-M (M = Al, Ti) systems, where pure metals are used as reducing agents. It is found that composite powders in which $Al_{2}$O$_{3}$ and TiO$_{2}$ are dispersed in $\alpha$-Fe matrix with nano-sized grains are obtained by mechanical alloying of Fe$_{3}$O$_{4}$ with Al and Ti for 25 and 75 hours, respectively. It is suggested that the large negative heat associated with the chemical reduction of magnetite by aluminum is responsible for the shorter MA time for composite powder formation in Fe$_{3}$O$_{4}$-Al system. X-ray diffraction results show that the reduction of magnetite by Al and Ti if a relatively simple reaction, involving one intermediate phase of FeAl$_{2}$O$_{4}$ or Fe$_{3}$Ti$_{3}$O$_{10}$. The average grain size of $\alpha$-Fe in Fe-TiO$_{2}$ composite powders is in the range of 30 nm. From magnetic measurement, we can also obtain indirect information about the details of the solid-state reduction process during MA.

• 오토저널
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• 제17권3호
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• pp.11-18
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• 1995

본 논문에서는 주철 라이너를 삽입한 알루미늄 블럭 엔진 개발과정에서 주조 불량이 발생하였을때, 냉각계에 일어나는 제반 현상을 분석하고, 이를 해결해 나가는 과정을 기술하였다. 이를 위하여 주철 블럭과 알루미늄 블럭을 장착한 엔진의 피스톤 온도와 블럭의 열유속, 열정산을 측정하였다. 측정한 결과는 다음과 같다. 1. 알루미늄 블럭 제작시 주철 라이너와 알루미늄 블럭 사이에 공기층이 크거나, 용탕 충진이 불완전한 주조 불량이 발생하면 열접촉 저항이 커져 엔진 열전달 경로에 큰 영향을 준다. 2. 알루미늄 블럭 제작시 주조 불량이 발생하면 피스톤에서 라이너로의 전열량이 줄어듦에 따라 냉각수로의 전열량은 감소하는데, 6,000rpm, 전부하에서 알루미늄 블럭의 출력 대비 냉각수로의 방열량의 비는 38.3%이고, 주철 블럭은 44.1%이다. 3. 알루미늄 블럭 제작시 주조 불량이 발생하면, 피스톤 온도가 15-20.deg.C 정도 상승하여 피스톤 손상을 유발시킬 수 있다. 4. 알루미늄 블럭의 주조가 완벽하게 되어 주철 라이너와 알루미늄 몸체 사이에서의 열접촉저항이 없어지면, 스토로크 방향에 따른 금속면 온도 분포가 균일하게 된다. 5. 실린더 라이너의 주조상태 개선없이 오일젯을 사용한 결과 피스톤의 온도를 만족할 만한 수준으로 감소시켰다. 6. 6000rpm, 전부하에서 오일젯 적용시 출력 대비 냉각수로의 방열량의 비가 38.3%에서 36.2%로 감소하고, 출력대비 오일로의 방열량의 비는 9.6%에서 11.2%로 증가한다. 7. 오일젯 작용시 오일 펌프의 용량 증대와 오일 쿨러의 장착이 필수적이다.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2015년도 춘계학술대회 논문집
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• pp.139-140
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• 2015

주석(Sn)은 뛰어난 유연성을 나타내기 때문에 접촉저항을 감소시킬 목적으로 전자부품과 전자기기의 도선과 단자를 피복하는데 사용된다. 하지만 특정한 조건에서 시간경과와 함께 위스커라는 침상결정이 발생하여 회로 단락을 초래하는 것이 문제이다. 위스커는 직선형, 굴곡형, 곡선형의 형태로 성장하며 직경은 $1{\mu}m$, 길이는 수백 ${\mu}m$에서부터 수 mm에 이른다. 발생 초기단계에서 성장이 정지된 작은 덩어리도 위스커와 함께 관찰된다. 주석도금 피막에서 발생하는 위스커는 1940년대 미국의 전화교환기 단락원인으로 널리 알려지게 되었다. 이러한 위스커를 억제하는 방법으로 주석-납 도금이 개발되었다. 주석-납 도금피막에서는 작은 덩어리가 다수 발생하는 반면에 위스커는 발생하지 않는다. 하지만 2006년 7월에 시행된 RoHS(Restriction of the use of certain Hazardous Substances) 지령에서 수은, 카드뮴, 6가 크롬 및 납은 유해물질로 지정되어 사용이 엄격히 규제되고 있다. 주석 도금피막의 위스커가 발생하고, 성장하는 원인으로 도금피막 내부의 압축응력과 전위, 산화피막, 도금피막-기판계면에서 발생하는 금속간화합물 주변의 변형을 들 수 있다. 본고에서는 도금하여 얻은 주석피막 표면에 형성된 위스커를 중심으로 증착피막과 주석도금 피막을 용융 응고하여 형성된 합금의 경시변화를 비교하고, 작은 덩어리와 위스커의 발생 및 성장 기구에 관하여 기술하였다.

• Journal of Welding and Joining
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• 제30권3호
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• pp.38-43
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• 2012

In this study, active metal brazing methods for $ZrO_2$ and Ti alloy were discussed. To get a successful metal-ceramic bonding, various factors (melting temperature, corrosion, sag resistance, thermal expansion coefficient etc. of base materilas and filler metal) should be considered. Moreover, in order to clarify bonding between the metal and ceramic, the mechanism of the interfacial structure of the joints should be identified. The driving force for the formation of metal and ceramic interfaces is the reduction of the free energy which occurs when their contact becomes complete. Interfacial bonding depends on the material combinations and the bonding processes. This study describes the bonding between ceramic and metal in an active metal brazing.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2006년도 하계학술발표대회 논문집
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• pp.346-351
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• 2006

When metallic alloys are reacted to hydrogen, heat transfer of storage tank effects hydrogen storage rate and capacity. If pulsating heat pipe are used to improve heat transfer efficiency, production of hydrogen storage tank can be more simple and economical. Experiment of heat pipe was conducted by varying working fluids and heat flux. According to supply heat flux, test indicate that R-22 and R-l42b were found lower temperature difference between evaporator and condenser than R-134a and Ethanol. Thermal resistances of R-22 and R-142b were also lower than others. Using R-142b as a working fluid, heat pipe type hydrogen storage tank is tested in absorption and desorption processes.

• 열처리공학회지
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• 제34권3호
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• pp.116-121
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• 2021

This study was carried out to investigate the effect of transformation induced martensite on the tensile properties of Fe-20Mn-12Cr-3Ni-3Si alloy. α' and ε-martensite were formed by cold rolling, and these martensite were formed with according to the specific direction, surface relief and partially intersection. With an increasing degree of cold rolling, amount of α'-martensite was slowly increased, whereas amount of ε-martensite was rapidly increased. Volume fraction of ε-martensite formed by cold working was large than α'-martensite. Tensile strength was rapidly increase and elongation was rapidly decreased with an increasing of degree of cold rolling. This means that tensile strengh and elongation was greatly influenced by the volume fraction of ε-martensite formed by cold rolling then α'-martensite.

• 한국재료학회지
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• 제29권3호
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• pp.160-166
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• 2019

This study investigates the effect of thermo-mechanical treatment on the damping capacity of the Fe-20Mn-12Cr-3Ni-3Si alloy with deformation induced martensite transformation. Dislocation, ${\alpha}^{\prime}$ and ${\varepsilon}-martensite$ are formed, and the grain size is refined by deformation and thermo-mechanical treatment. With an increasing number cycles in the thermo-mechanical treatment, the volume fraction of ${\varepsilon}-martensite$ increases and then decreases, whereas dislocation and ${\alpha}^{\prime}-martensite$ increases, and the grain size is refined. In thermo-mechanical treated specimens with five cycles, more than 10 % of the volume fraction of ${\varepsilon}-martensite$ and less than 3 % of the volume fraction of ${\alpha}^{\prime}-martensite$ are attained. Damping capacity decreases by thermo-mechanical treatment and with an increasing number of cycles of thermo-mechanical treatment, and this result shows an opposite tendency for general metal with deformation induced martensite transformation. The damping capacity of the thermo-mechanical treated damping alloy with deformation induced martensite transformation greatly affect the formation of dislocation, grain refining and ${\alpha}^{\prime}-martensite$ and then ${\varepsilon}-martensite$ formation by thermo-mechanical treatment.