• Journal of the Microelectronics and Packaging Society
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• v.15 no.4
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• pp.17-24
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• 2008

Thermal annealing and electromigration test were performed at $150^{\circ}C$ and $150^{\circ}C,\;5{\times}10^4\;A/cm^2$ conditions, respectively, in order to compare the growth kinetics of intermetallic compound(IMC) in Cu pillar bump. The quantitative interfacial adhesion energy with annealing was measured by using four-point bending strength test in order to assess the effect of IMC growth on the mechanical reliability of Cu pillar bump. Only $Cu_6Sn_5$ was observed in the Cu pillar/Sn interface after reflow. However, $Cu_3Sn$ formed and grew at Cu pillar/$Cu_6Sn_5$ interface with increasing annealing and stressing time. The growth kinetics of total($Cu_6Sn_5+Cu_3Sn$) IMC changed when all Sn phases in Cu pillar bump were exhausted. The complete consumption time of Sn phase in electromigration condition was faster than that in annealing condition. The quantitative interfacial adhesion energy after 24h at $180^{\circ}C$ was $0.28J/m^2$ while it was $3.37J/m^2$ before annealing. Therefore, the growth of IMC seem to strongly affect the mechanical reliability of Cu pillar bump.

• Nuclear Engineering and Technology
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• v.25 no.1
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• pp.71-79
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• 1993

Positron annihilation characteristics and microhardness of 25% cold worked and isochronally annealed hafnium specimens were measured to study recovery and recrystallization stages of hafnium specimens. The annihilation lifetime of positrons in hafnium has been measured for the distinct cases of annihilation in the annealed lattice and annihilation after trapping at lattice defects generated by cold deformation at room temperature. The annihilation lifetime in the annealed lattice was 187 $\pm$3.7 psec, whereas it was 217 $\pm$ 4.2 psec for positrons trapped at deformation-induced defects (mostly dislocations). The changes in Doppler broadening and hardness showed similar trend in the recrystallization range, however, the measured value of Doppler broadening variation were quite sensitive to changes in the recovery region in which the variation in hardness value was completely insensitive. Recovery of cold worked hafnium initiated at about 623 K and recrystallization occurred at around 1023 K.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.1
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• pp.562-567
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• 2021

To develop an antibacterial tempered glass for applications to various building facilities and household products, the antibacterial activity of domestic materials was investigated, and a tempered glass sample was produced with silver, copper, and zinc, having an antibacterial activity of 99% or more at a specific concentration. The measured antibacterial activity of the samples, in which silver, copper, and zinc were dispersed in ethylene glycol + glycerol, was more than 99%. Measurements of the thickness of the coated metal material by washing using a surface analyzer showed that the thickness decreased by less than 1% in various types of detergents, including water, but only approximately 10% in the alkaline detergents. To check the human safety of the samples, a cytotoxicity test was performed through an MTT assay; the samples showed no cytotoxicity. Finally, a Live/Dead kit or film adhesion method showed that the antibacterial activity of the prototype was more than 99%. Therefore, the high-functional antibacterial effect of tempered glass was developed using domestic materials and may be used in various products in the future.

• Journal of the Korean Chemical Society
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• v.28 no.1
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• pp.41-46
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• 1984

To preconcentrate trace elements, microgram amounts of 5 heavy metals (Cu, Co, Ni, Zn and Cd) were precipitated with 8-hydroxyquinoline (oxine) and metal oxinates were extracted with stearic acid. And then each of the molten stearic acid extract with stearic acid. And then each of the molten stearic acid extract was poured into a glass ring and cooled for specimen preparation. The obtained specimens were analyzed by X-ray fluorescene spectrometry. And then conditions of precipitation formation and extraction, reproducibility, sensitivity and detection limit were observed. The relative standard deviation of specimen preparation was 1.0~5.7% and the detection limit was 5~$50{\mu}g$/100ml. The proposed preconcentration procedure exhibited a considerable inhancement and simplicity in preparing specimens.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 1991.04a
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• pp.133-138
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• 1991

일반적으로 고무를 비롯한 점탄성재료는 형상 및 크기를 적절히 조절함으로 써 한 방향 이상으로의 원하는 스프링상수를 얻을 수 있으며, 금속에 비하여 내부 마찰에 의한 에너지 발산이 매우 크기 때문에 강제 진동시의 진폭저감 및 충격에 따른 자유진동의 감쇠에 널리 이용되고 있다. 이와 같은 진동감쇠 에 점탄성재료를 효과적으로 사용하기 위해서는 복소탄성계수 즉, 탄성계수 와 손실계수를 정확하게 알아내는 것이 필요하다. 점탄성재료의 복소탄성계 수는 주파수, 온도 및 변형률등에 따라 변하므로 이와 같은 사용조건의 함수 로 구해야 한다. 복소탄성계수를 실험적으로 구하는 방법은 여러가지가 있으 며 실험의 용이성과 관심대상에 따라 적절한 방법을 선택하게 된다. 본 연구 에서는 주파수변화에 따른 복소탄성계수를 임피던스법으로 집중질량 모형을 이용하여 구하려고 할 때, 실험데이타로부터 보다 정확한 결과를 얻기 위하 여 적절한 시편의 크기를 결정하는 방법을 제시하고자 한다. 이를 위해서 시 편내의 파동전달효과와 포아송비와 관련된 양단제한효과 그리고 정하중시 압축변형에 대한 시편의 좌굴등을 고려하여 이론적으로 해석하였으며 실험 적으로도 검증하였다.

• Proceedings of the Korean Vacuum Society Conference
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• 1995.06a
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• pp.48-49
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• 1995

전자소자의 축소화에 따라 electromigration은 점차 반도체 디바이스의 주요 결함 원 인으로 부각되고 있다. 본 실험은 현재 배선 재료로 널리 사용되고 있는 Al-1%Si 금속박막 배선의 electromigration에 대한 온도 및 배선길이 의존성에 관하여 연구하였다. ppLCC(pplastic Leaded Chipp Carrier) ppackage된 ppSG(8000$\AA$)/SiO2(1000$\AA$)/Al-1%Si(7000 $\AA$)/SiO2(5000$\AA$)/pp-typpe Si(100)의 보호막처리된 시편과 Al-1%Si/SiO2(5000$\AA$)/pp-typpe Si(100)의 보호막처리되지 않은 시편등을 standard pphotolithograpphy 공정을 이용하여 각각 제작하였다. 선폭 3$mu extrm{m}$, 길이 100, 400, 800, 1600$\mu\textrm{m}$의 등의 Al-1%Si 박막배선구조를 사용하 였다. 가속화실험을 위해 인가된 D.C 전류밀도는 4.5$\times$106A/cm2이었고 실온에서 10$0^{\circ}C$까지 의 분위기 온도에서 electromigration를 실행하였다. 박막배선길이에 따른 MTF(Mean Time-to-Failure)는 임계길이 이상에서 포화되는 경향을 보이며 임계길이는 Al-1%Si 박막 배선에서 분위기온도에 따라 길이 400$\mu\textrm{m}$과 800$\mu\textrm{m}$범위에서 나타났다. 각 시편에서 electromigration에 대한 활성화에너지도 MTF의 특성과 유사하게 임계길이 이상에서 포화 되는 특성을 타나내었다.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2003.11a
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• pp.196-201
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• 2003

Decontamination means every method that can drop the level of the radioactivities from the materials contaminated with them to the allowable one. In this paper, one of the decontamination methods, the electro-decontamination was described with lots of experiments. Two test specimens contaminated with alpha ray and beta ray respectively were used to compare the decontamination factors between two rays and many experiments were performed in every electrolyte with SUS and Carbon steel test specimens. Sulphuric acid, phosphoric acid, nitric acid, citric acid and oxalic acid were used as the electrolyte. Decontamination Factors (DF) could be compared and analyzed with different electrolyte, current intensities and time.

• Proceedings of the Materials Research Society of Korea Conference
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• 2009.11a
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• pp.30.1-30.1
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• 2009

정보화가 급속히 진전됨에 따라 보다 많은 양의 정보를 전송, 처리, 저장하게 되면서 이를 위해 대용량, 고속, 비휘발성의 특징을 갖는 차세대 메모리의 개발이 절실히 요구되고있다. 이 중 저항 변화 메모리(ReRAM)는 일반적으로 TiO2, Al2O3, NiO2, HfO2, ZrO2 등의 전이금속산화물을 이용한 MIM 구조로서 적당한 전기 신호를 가하면 저항이 높아서 전도되지 않는 상태(Offstate)에서 저항이 낮아져 전도가 가능한 상태(On state)로 바뀌는 메모리 특성을가진다. ReRAM은 비휘발성 메모리이며 종래의 비휘발성 기억소자인 Flash memory 보다 access time 이105 배 이상 빠르고, 5V 이하의 낮은 전압에서도 동작이 가능하다. 또한 구조가 간단하여 공정 단순화가 가능하고 소자의 집적화도 쉽다는 점 등 많은 장점들이 있어서 Flash memory를 대체할 수 있는 유력한 후보로 여겨지고 있다. 본연구에서는 DC-magnetron Sputtering 방법으로 전이금속 박막을 증착하고, Dry furnace로 산화시켜 전이금속산화물 박막을 제작한 후 저항변화 특성을 연구하였다. 두 개의 전이금속산화물 박막을 dual-layer로 형성시켜 저항변화특성을 관찰하였으며 또한, 전이금속산화물 박막의 조성을 달리 하여 저항변화를 관찰 하였다. 전이금속산화물 박막의 전기적 특성을 알아보기 위해 Si(100) wafer 위에 Pt를 이용 MIM 형태로 capacitor 시편을 제작 하여, probe station으로 I-V 측정을 하였고 조성 및 표면 분석을 위해서는 AES와 AFM을, 미세구조를 분석을 위해서는 TEM과 SEM 을 사용하였다.

• Conservation Science in Museum
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• v.29
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• pp.111-132
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• 2023

Terahertz radiation cannot pass through metal and therefore reflect and return most signals. Utilizing this property, this study analyzed information on paintings to verify the usage of metal materials on paintings and the scope of their application. First, the study tested specimens of metal-based pigments and synthetic pearl pigments with metallic colors and textures in order to compare basic characteristics of terahertz images, such as signal severance caused by metallic substances, traits reflected in cross-section images, and high degree of reflection. Subsequently, based on the collected information, the study diagnosed various types of paintings including Korean traditional paintings and oil paintings using the terahertz imaging technique to confirm the usage of metal-based pigments in the inner layers of paintings and their scope of application. The terahertz imaging technique could has the potential to provide scientific evidence for previously-undiscovered information and art-historical records about various types of paintings that used metalbased pigments, thereby rendering significant utility for the conservation and authentication of paintings.

• Composites Research
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• v.23 no.4
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• pp.21-27
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• 2010

In most engineering structures, fracture often takes place due to fatigue. Therefore, many studies about the effect of the various mode-mixities on fatigue characteristics have been performed. However, most of the former studies only address metal/metal interfaces or delamination of composite. In this study, the fatigue characteristics of composite/metal interfaces are investigated. The fatigue tests were performed using single leg bending(SLB)specimens that comprise composite and steel bonded to each other using co-cure bonding method. This paper focuses on fatigue characteristics depending on different mode ratios$(G_{II}/G_T$. The overall results obtained in this study show that the crack propagation rate increases with the mode II loading component.